Evaluation of a calix[4]-bis-crown-6 ionophore-based supported liquid membrane system for selective 137Cs transport from acidic solutions

Journal of Membrane Science

Volumn 310, Issue 1-2, 2008, Pages 229-236

  Raut, D R ^a   Mohapatra, P K ^a   Ansari, S A ^a   Manchanda, V K ^a  

^a BHABHA ATOMIC RESEARCH CENTRE   (India)

Author keywords

Calix crown; Cesium; High level waste; Supported liquid membrane

Indexed keywords

CALIX-CROWN; HIGH LEVEL WASTE; SUPPORTED LIQUID MEMBRANE;

CESIUM; CONCENTRATION (PROCESS); NITRATES; SOLUTIONS;

LIQUID MEMBRANES;

2 NITROPHENYLOCTYL ETHER; CALIX[4]BIS 2,3 NAPHTHO CROWN 6; CESIUM 137; CROWN COMPOUND; DODECANE; ETHER DERIVATIVE; IONOPHORE; LIGAND; METAL; NITRATE; NITRO DERIVATIVE; POLITEF; UNCLASSIFIED DRUG; URANIUM; WATER;

CESIUM; CONCENTRATION (PROCESS); LIQUID MEMBRANES; NITRATES; SOLUTIONS;

ACIDITY; AQUEOUS SOLUTION; ARTICLE; CONCENTRATION (PARAMETERS); DISSOLUTION; EXTRACTION; IRRADIATION; LIQUID MEMBRANE; MEMBRANE TRANSPORT; PRIORITY JOURNAL; RADIOACTIVE WASTE; RADIOACTIVE WASTE PROCESSING; SEPARATION TECHNIQUE; STOICHIOMETRY; TRANSPORT KINETICS;

EID: 38649093014     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2007.10.044     Document Type: Article

References (28)

1. IAEA Technical Data Series No. 356, IAEA, 1993.
2. 3 solutions-a technology review and assessment. Sep. Sci. Technol. 22 (1987) 191
3. Ungaro R., Casnati A., Ugozzoli F., Pochini A., Dozol J.-F., Hill C., and Rouquette H. 1,3-Dialkoxycalix[4]arenecrowns-6 in 1,3-alternate configuration: cesium-selective ligands that exploit cation-arene interactions. Angew. Chem. Int. Ed. Engl. 33 (1994) 1506
4. Talanov V.S., Talanov G.G., Gorbunova M.G., and Bartsch R.A. Novel cesium-selective, 1.3-alternate calix[4]arene-bis(crown-6-ethers) with proton-ionisable groups for enhanced extraction efficiency. J. Chem. Soc., Perkin Trans. 2 (2002) 209
5. Ungaro R., Casnati A., Ugozzoli F., Pochini A., Dozol J.F., Hill C., and Rouquette H. Angew. Chem. Int. Ed. Engl. 33 (1994) 1506
6. Bonnesen P.V., Delmau L.H., and Moyer B.A. A robust alkaline-side CSEX solvent suitable for removing cesium from savanna river high level waste. Solv. Extr. Ion Exch. 18 (2000) 1079
7. Ungaro R., Casnati A., Ugozzoli F., Pochini A., Dozol J.-F., Hill C., and Rouquette H. 1.3-Dialkoxycalix[4]arenecrown-6 in 1,3-alternate conformation: cesium-selective ligands that exploit cation-arene interactions. Angew. Chem. Int. Ed. Engl. 33 (1994) 1506
8. Sachleben R.A., Bonnesen P.V., Descazeaud T., Haverlock T.J., Urvoas A., and Moyer B.A. Surveying the extraction of cesium nitrate by 1,3-alternate calix[4]arene crown-6 ethers in 1,2-dichloroethane. Solv. Extr. Ion Exch. 17 (1999) 1445
9. Moyer B.A., Bazelaire E., Bonnesen P.V., Custelcean R., Delmau L.H., Ditto M.E., Engle N.L., Gorbunova M.G., Haverlock T.J., Levitskaia T.G., Bartsch R.A., Surowiec M.A., and Zhou H. Special INASAT Bulletin on Separation Science & Technology in Nuclear Industry (2006), Perfect Press, Mumbai pp.32-44
10. Leonard R.A., Conner C., Liberatore M.W., Sedlet J., Aase S.B., Vandegrift G.F., Delmau L.H., Bonnesen P.V., and Moyer B.A. Development of a solvent extraction process for cesium removal from SRS tank waste. Sep. Sci. Technol. 36 (2001) 743
11. Mohapatra P.K., Ansari S.A., Sarkar A., Bhattacharyya A., and Manchanda V.K. Evaluation of calix-crown ionophores for selective separation of radio-cesium from acidic nuclear waste solution. Anal. Chim. Acta 571 (2006) 308
12. Sriram S., Mohapatra P.K., Pandey A.K., Manchanda V.K., and Badheka L.P. Facilitated transport of americium(III) from nitric acid media using dimethyldibutyl-tetradecyl-1,3-malonamide. J. Membr. Sci. 177 (2000) 163
13. Mohapatra P.K., Lakshmi D.S., Mohan D., and Manchanda V.K. Selective transport of cesium using a supported liquid membrane containing di-t-butyl benzo 18 crown-6 as the carrier. J. Membr. Sci. 232 (2004) 133
14. Asfari Z., Bressot C., Vicens J., Hill C., Dozol J.-F., Rouquette H., Eymard S., Lamare V., and Tournois B. Doubly crowned calix[4]arenas in the 1,3-alternate conformation as cesium selective carriers in supported liquid membranes. Anal. Chem. 67 (1995) 3133
15. Ansari S.A., Mohapatra P.K., Prabhu D.R., and Manchanda V.K. Transport of americium(III) through a supported liquid membrane containing N,N,N′-N′-tetraoctyl-3-oxapentane diamide (TODGA) in n-dodecane as the carrier. J. Membr. Sci. 282 (2006) 133
16. Shailesh S., Pathak P.N., Mohapatra P.K., and Manchanda V.K. Transport studies of uranium across a supported liquid membrane containing N,N-di(2-ethylhexyl) isobutyramide (D2EHIBA) as the carrier. J. Membr. Sci. 272 (2006) 143
17. Thuery P., Nierlich M., Lamare V., Dozol J.-F., Asfari Z., and Vicens J. Bis(crownether) and azobenzo crown derivatives of calix[4]arene. A review of structural information from crystallographic and modeling studies. J. Incl. Phenom. Macrocycl. Chem. 36 (2000) 375
18. Danesi P.R. Separation of metal species by supported liquid membranes. Sep. Sci. Technol. 19 (1985) 857
19. Robinson R.A., and Stokes R.H. Electrolyte Solutions. 2nd ed. (1965), Butterworth, London pp. 314
20. Dozol J.F., Simon N., Lamare V., Rouquette H., Eymard S., Tournois B., De Marc D., and Macias R.M. A solution for cesium removal from high-salinity acidic or alkaline liquid waste: the crown calix[4]arenas. Sep. Sci. Technol. 34 (1999) 877
21. Wang W.J., Lin J., Wang A., Zheng P., Wang M., and Wang B. Thermodynamics and coordination characteristics of the hydronium-uranium(VI)-dicyclohexano-24-crown-8 extraction complex. Inorg. Chim. Acta 149 (1988) 151
22. Mohapatra P.K., and Manchanda V.K. Liquid membrane based separations of actinides and fission products. Ind. J. Chem. 42A (2003) 2925
23. Duhart A., Dozol J.F., Rouquette H., and Deratani A. Selective removal of cesium from model nuclear waste solutions using a solid membrane composed of an unsymmetrical calix[4]arenebiscrown-6 bonded to an immobilized polysiloxane backbone. J. Membr. Sci. 185 (2001) 145
24. Rawat N., Mohapatra P.K., Lakshmi D.S., Bhattacharyya A., and Manchanda V.K. Selective transport of strontium from nitric acid medium using a flatsheet membrane containing a macrocyclic carrier. J. Membr. Sci. 275 (2006) 82
25. Danesi P.R., Reichley-Yinger L., and Rickert P. Life time of supported liquid membranes: the influence of interfacial properties, chemical composition and water transport on the long term stability of the membranes. J. Membr. Sci. 31 (1987) 117
26. Mohapatra P.K., Lakshmi D.S., Mohan D., and Manchanda V.K. Uranium transport using a PTFE flat-sheet membrane containing aliquat 336 in toluene as the carrier. Sep. Purif. Technol. 51 (2006) 24
27. Kemperman A.J.B., Bargeman D., Van Den Boomgaard T., and Strathmann H. Stability of supported liquid membranes: state of the art. Sep. Sci. Technol. 31 (1996) 2733
28. A. Bhattacharyya, P.K. Mohapatra, S.A. Ansari, D.R. Raut, V.K. Manchanda, Separation of trivalent actinides and lanthanides using hollow fibre supported liquid membrane containing cyanex-301 as the carrier, J. Membr. Sci. (communicated).