1-[(E)-2-arylethenyl]-2,2-diphenylcyclopropanes: Kinetics and mechanism of rearrangement to cyclopentenes

Helvetica Chimica Acta

Volumn 94, Issue 8, 2011, Pages 1359-1388

  Mulzer, Johann ^a   Huisgen, Rolf ^b   Arion, Vladimir ^c   Sustmann, Reiner ^d  

^a INSTITUT FÜR ORGANISCHE CHEMIE   (Austria)

^b UNIVERSITY OF MUNICH   (Germany)

^c UNIVERSITY OF VIENNA   (Austria)

^d UNIVERSITY OF DUISBURG ESSEN   (Germany)

Author keywords

Cyclopentenes; Cyclopropanes, 1 (E) 2 arylethenyl 2,2 diphenyl ; Kinetics; Rearrangement reactions; X Ray crystallography

Indexed keywords

CHARGE SEPARATIONS; CYCLOPENTENES; CYCLOPROPANES, 1-[(E)-2-ARYLETHENYL]-2,2-DIPHENYL-; DECALIN; DIRADICALS; FIVE-MEMBERED RINGS; KINETIC MEASUREMENT; KINETICS AND MECHANISM; LINEAR RELATION; QUANTUM-CHEMICAL CALCULATION; REARRANGEMENT REACTIONS; RING OPENING; SOLVENT DEPENDENCE; THERMAL REARRANGEMENT; TRANSITION STRUCTURES; VINYLCYCLOPROPANE;

CONFORMATIONS; ISOMERS; ORGANIC SOLVENTS; PROPANE; QUANTUM CHEMISTRY; X RAY CRYSTALLOGRAPHY;

KINETICS;

1[ 2 ARYLETHENYL] 2,2 DIPHENYLCYCLOPROPANE; 3,4,4 TRIPHENYLCYCLOPENTENE; ALCOHOL; BENZENE; BUTANOL; CYCLOHEXANE; CYCLOPENTENE DERIVATIVE; CYCLOPROPANE DERIVATIVE; DECALIN; DIMETHYL SULFOXIDE; DIOXANE; N,N DIMETHYLFORMAMIDE; SOLVENT; UNCLASSIFIED DRUG; VINYLCYCLOPROPANE;

ALLYLIC REARRANGEMENT; ARTICLE; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CONFORMATIONAL TRANSITION; ISOMERISM; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTUM MECHANICS; RACEMIZATION; RING OPENING; THERMAL ANALYSIS; WITTIG REACTION; X RAY CRYSTALLOGRAPHY;

EID: 80051913675     PISSN: 0018019X     EISSN: 15222675     Source Type: Journal    
DOI: 10.1002/hlca.201100135     Document Type: Article

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