Kinetics of the thermal isomerizations of gaseous vinylcyclopropane and vinylcyclobutane

Journal of Physical Chemistry A

Volumn 101, Issue 22, 1997, Pages 4097-4102

  Lewis, David K ^a,c   Charney, Donald J ^a   Kalra, Bansi L ^a,d   Plate, Ann Marie ^a   Woodard, M Heather ^a   Cianciosi, Steven J ^b   Baldwin, John E ^b  

^a Center for Language and Brain   (United States)

^b SYRACUSE UNIVERSITY   (United States)

^c The Holleran Center for Community Action and Public Policy   (United States)

^d HOLLINS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000058612     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9639556     Document Type: Article

References (38)

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14. Wellman, R. E.; Walters, W. R. J. Am. Chem. Soc. 1957, 79, 1542-1546. For the conversion of methylcyclobutane to ethene plus propylene, the activation parameters are 15.4 and 61.2 kcal/mol (Das, M. N.; Walters, W. D. Z. Phys. Chem. (Frankfurt/Main) 1958, 15, 22-33).
15. Wellman, R. E.; Walters, W. R. J. Am. Chem. Soc. 1957, 79, 1542-1546. For the conversion of methylcyclobutane to ethene plus propylene, the activation parameters are 15.4 and 61.2 kcal/mol (Das, M. N.; Walters, W. D. Z. Phys. Chem. (Frankfurt/Main) 1958, 15, 22-33).
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18. Lewis, D. K.; Brandt, B.; Crockford, L.; Glenar, D. A.; Rauscher, G.; Rodriguez, J.; Baldwin, J. E. J. Am. Chem. Soc. 1993, 115, 11728-11734. The fit between model and data was best when it was assumed that there was no retention of cyclohexene stereochemistry in ethene molecules formed via vinylcyclobutane; the complete loss of stereochemistry in the vinylcyclobutane → ethene + 1,3-butadiene reaction has now been demonstrated experimentally (Lewis, D. K.; Hutchinson, A.; Lever, S. J.; Spaulding, E. L.; Bonacorsi, S. J., Jr.; Baldwin, J. E. Isr. J. Chem. 1996, 36, 233-238).
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33. o for hydrogenation for cyclopentene, 26.94 ± 0.13 kcal/mol (Alliger, N. L.; Dodziuk, H.; Rogers, D. W.; Naik, S. N. Tetrahedron 1982, 38, 1593-1597) and 26.8 ± 0.2 kcal/mol (Roth, W. R.; Lennartz, H.-W. Chem. Ber. 1980, 113, 1806-1817).
34. o for hydrogenation for cyclopentene, 26.94 ± 0.13 kcal/mol (Alliger, N. L.; Dodziuk, H.; Rogers, D. W.; Naik, S. N. Tetrahedron 1982, 38, 1593-1597) and 26.8 ± 0.2 kcal/mol (Roth, W. R.; Lennartz, H.-W. Chem. Ber. 1980, 113, 1806-1817).
35. o values for phenyl vs vinyl derivatives (Luo, Y.-R.; Holmes, J. L. J. Phys. Chem. 1992, 96, 9568-9571).
36. o values for phenyl vs vinyl derivatives (Luo, Y.-R.; Holmes, J. L. J. Phys. Chem. 1992, 96, 9568-9571).
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