Direct observation of a hydroperoxide surface intermediate upon visible light-driven water oxidation at an Ir oxide nanocluster catalyst by rapid-scan FT-IR spectroscopy

Journal of the American Chemical Society

Volumn 133, Issue 33, 2011, Pages 12976-12979

  Sivasankar, Narayanappa ^a,b   Weare, Walter W ^a,c   Frei, Heinz ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b Liquid Light Inc   (United States)

^c NORTH CAROLINA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATTENUATED TOTAL REFLECTION MODES; FTIR SPECTROSCOPY; HYDROPEROXIDES; INFRARED BANDS; MULTI-ELECTRON; NANOCLUSTER CATALYST; OXYGEN EVOLUTION; PULSE RESPONSE; RU(BPY); SPECTRAL ASSIGNMENTS; SURFACE INTERMEDIATES; UNDER PULSED EXCITATIONS; VIBRATIONAL MODES; VISIBLE LIGHT; WATER OXIDATION;

CATALYSTS; IRIDIUM; NANOCLUSTERS; OXIDATION;

REACTION INTERMEDIATES;

HYDROPEROXIDE; IRIDIUM COMPLEX; IRIDIUM OXIDE; OXIDE; UNCLASSIFIED DRUG; WATER;

ARTICLE; CATALYST; COLLOID; FOURIER TRANSFORM MASS SPECTROMETRY; KINETICS; LIGHT; NANOANALYSIS; OXIDATION; SURFACE PROPERTY;

CATALYSIS; HYDROGEN PEROXIDE; IRIDIUM; LIGHT; NANOSTRUCTURES; OXIDATION-REDUCTION; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; WATER;

EID: 80051779146     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja205300a     Document Type: Article

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