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Volumn 128, Issue 33, 2006, Pages 10668-10669

Visible light-driven water oxidation by Ir oxide clusters coupled to single Cr centers in mesoporous silica

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM DERIVATIVE; IRIDIUM COMPLEX; IRIDIUM OXIDE; METAL OXIDE; SILICON DIOXIDE; UNCLASSIFIED DRUG; WATER;

EID: 33747753197     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0625632     Document Type: Article
Times cited : (97)

References (34)
  • 11
    • 0344896573 scopus 로고    scopus 로고
    • Oxidation of a dinuclear Mn complex by a coupled light-driven charge-separation unit has been demonstrated, but the system has not yet been shown to evolve oxygen: Hammarström, L. Curr. Opin. Chem. Biol. 2003, 7, 666-673.
    • (2003) Curr. Opin. Chem. Biol. , vol.7 , pp. 666-673
    • Hammarström, L.1
  • 18
    • 0001502219 scopus 로고    scopus 로고
    • Incorporation of Al (Al/Si = 0.02) into the framework of MCM-41 increased the thermal stability and served to prevent leaching of Cr into the aqueous solution: Weckhuysen, B. M.; Wachs, I. E.; Schoonheydt, R. A. Chem. Rev. 1996, 96, 3327-3349.
    • (1996) Chem. Rev. , vol.96 , pp. 3327-3349
    • Weckhuysen, B.M.1    Wachs, I.E.2    Schoonheydt, R.A.3
  • 23
    • 33747797839 scopus 로고    scopus 로고
    • note
    • Supporting Information.
  • 32
    • 33747806765 scopus 로고    scopus 로고
    • note
    • Further spectroscopic studies are in progress to determine the detailed structure of the active Cr centers, including whether Cr centers separated from the Ir oxide cluster by Si-O linkages are active as charge-transfer chromophores by virtue of hole hopping.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.