Pr-doped ceria nanoparticles as intermediate temperature ionic conductors

International Journal of Hydrogen Energy

Volumn 36, Issue 17, 2011, Pages 10981-10990

  Ruiz De Larramendi, Idoia ^a   Ortiz Vitoriano, Nagore ^a   Acebedo, Begoña ^a   Jimenez De Aberasturi, Dorleta ^a   Gil De Muro, Izaskun ^a   Arango, Ana ^b   Rodríguez Castellón, Enrique ^b   Ruiz De Larramendi, Jose Ignacio ^a   Rojo, Teofilo ^a,c  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^b UNIVERSITY OF MÁLAGA   (Spain)

^c CIC ENERGIGUNE   (Spain)

Author keywords

Ceria; Fluorite; Ionic conductor; SOFC electrolyte

Indexed keywords

A-THERMAL; BULK CONDUCTIVITIES; DILATOMETRIC MEASUREMENTS; DOUBLE PEROVSKITES; ELECTROCHEMICAL BEHAVIORS; ELECTROCHEMICAL PERFORMANCE; ELECTROLYTE MATERIAL; FURTHER DEVELOPMENT; INTERMEDIATE TEMPERATURES; IONIC CONDUCTOR; MATERIAL PROPERTY; NANO-STRUCTURED; NANOSTRUCTURED ELECTROLYTES; NEW ELECTROLYTES; POLYOL-MEDIATED SYNTHESIS; PR-DOPED CERIA; SOFC ELECTROLYTE; THERMOMECHANICAL PROPERTIES; WELL-CRYSTALLIZED NANOPARTICLES;

CERIUM COMPOUNDS; ELECTROCHEMICAL PROPERTIES; IONIC CONDUCTION; IONIC CONDUCTIVITY; ORE SINTER; PARTICLE SIZE; PEROVSKITE; SOLID ELECTROLYTES; SOLID OXIDE FUEL CELLS (SOFC); THERMAL EXPANSION;

NANOPARTICLES;

EID: 80051580672     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.05.177     Document Type: Article

References (58)

1. M. Roco Government nanotechnology funding: an International outlook JOM-J Minerals Metals Mater 54 2002 22 23 (Pubitemid 35236569)
2. H. Gleiter Nanostructured materials Adv Mater 4 1992 474 481
3. J.V. Stark, D.G. Park, I. Lagadic, and K.J. Klabunde Nanoscale metal oxide particles/clusters as chemical reagents. Unique surface chemistry on magnesium oxide as shown by enhanced adsorption of acid gases (sulfur dioxide and carbon dioxide) and pressure dependence Chem Mater 8 1996 1904 1912 (Pubitemid 126475379)
4. J.V. Stark, and K.J. Klabunde Nanoscale metal oxide particles/clusters as chemical reagents. adsorption of hydrogen halides, nitric oxide, and sulfur trioxide on magnesium oxide nanocrystals and compared with microcrystals Chem Mater 8 1996 1913 1918 (Pubitemid 126475380)
5. Y. Sun, and Y. Xia Shape-controlled synthesis of gold and silver nanoparticles Science 298 2002 2176 2179 (Pubitemid 35471239)
6. O.B. Koper, I. Lagadic, A. Volodin, and K.J. Klabunde Alkaline earth oxide nanoparticles obtained by aerogel methods. Characterization and rational for unexpectedly high surface chemical reactivities Chem Mater 9 1997 2468 2480 (Pubitemid 127471859)
7. B. Kang, and G. Ceder Battery materials for ultrafast charging and discharging Nature 458 2009 190 193
8. M. Das, D. Mishra, P. Dhak, S. Gupta, T.K. Maiti, and A. Basak Biofunctionalized, phosphonate-grafted, ultrasmall iron oxide nanoparticles for combined targeted cancer therapy and multimodal imaging Small 5 2009 2883 2893
9. B.C.H. Steele, and A. Heinzel Materials for fuel-cell technologies Nature 414 2001 345 352 (Pubitemid 33097817)
10. S. Obara ower generation efficiency of an SOFC-PEFC combined system with time shift utilization of SOFC exhaust heat Int J Hydrogen Energy 35 2010 757 767
11. A. Tarancón Strategies for lowering solid oxide fuel cells operating temperature Energies 2 2009 1130 1150
12. 1.9 for low temperature solid oxide fuel cells based on composite electrolyte Int J Hydrogen Energy 35 2010 731 737
13. Y. Patcharavorachot, W. Paengjuntuek, S. Assabumrungrat, and A. Arpornwichanop Performance evaluation of combined solid oxide fuel cells with different electrolytes Int J Hydrogen Energy 35 2010 4301 4310
14. A.J. McEvoy Thin SOFC electrolytes and their interfaces-a near-term research strategy Solid State Ionics 132 2000 159 165
15. X.J. Chen, K.A. Khor, S.H. Chan, and L.G. Yu Influence of microstructure on the ionic conductivity of yttria-stabilized zirconia electrolyte Mater Sci Eng A A335 2002 246 252 (Pubitemid 34915628)
16. A.N. Vlasov, and M.V. Perfil'ev Aging of zirconium dioxide-based solid electrolytes Solid State Ionics 25 1987 245 253 (Pubitemid 18564270)
17. 7 (YZ) pyrochlore based materials: the influence of bismuth Mater Chem Phys 92 2005 303 309 (Pubitemid 40538691)
18. 2.85 for IT-SOFCs Int J Hydrogen Energy 35 2010 294 300
19. Y. Higuchi, M. Sugawara, K. Onishi, M. Sakamoto, and S. Nakayama Oxide ionic conductivities of apatite-type lanthanum silicates and germanates and their possibilities as an electrolyte of lower temperature operating SOFC Ceramics Int 36 2010 955 959
20. 2-d ceramics Electrochim Acta 52 2006 2001 2008
21. 1.9 Adv Mater 22 2010 1659 1662
22. S. Piñol, M. Najib, D.M. Bastidas, A. Calleja, X.G. Capdevila, and M. Segarra Microstructure-conductivity relationship in Gd- and Sm-doped ceria-based electrolytes prepared by the acrylamide sol-gel-related method J Solid State Electrochem 8 2004 650 654 (Pubitemid 39099202)
23. M. Nauer, C. Fikos, and B.C.H. Steele An evaluation of Ce-Pr oxides and Ce-Pr-Nb oxides mixed conductors for cathodes of solid oxide fuel cells: structure, thermal expansion and electrical conductivity J Eur Ceram Soc 14 1994 493 499
24. 3 ECS Trans 25 2009 2799 2806
25. M.G. Bellino, D.G. Lamas, and N.E. Walsöe de Reca Enhanced ionic conductivity in nanostructured, heavily doped ceria ceramics Adv Funct Mater 16 2006 107 113 (Pubitemid 43076321)
26. J. Rodríguez-Carvajal Recent advances in magnetic structure determination by neutron powder diffraction Physica B 192 1993 55 69
27. 2-d solid solutions Solid State Ionics 116 1999 217 223
28. M.J. Chen, S. Cheng, F.Y. Wang, J.F. Lee, and Y.L. Tai Study of Pr-doped ceria-based electrolytes for ITSOFC ECS Trans 7 2007 2245 2252
29. 4 nanoparticles with controlled sizes J Non-Crystallin Solids 354 2008 5207 5209
30. H. Borchert, Y. Borchert, V.V. Kaichev, I.P. Prosvirin, G.M. Alikina, and A.I. Lukashevich Nanostructured, Gd-doped ceria promoted by Pt or Pd: investigation of the electronic and surface structures and relations to chemical properties J Phys Chem B 109 2005 5728 5738
31. 3 (Ln = Sm, Dy) for the electrode of solid oxide fuel cells Solid State Ionics 100 1997 283 288 (Pubitemid 127399643)
32. R.D. Shannon Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Acta Cryst A 32 1976 751 767
33. A. Tarancon, M. Burriel, J. Santiso, S.J. Skinner, and J.A. Kilner Advances in layered oxide cathodes for intermediate temperature solid oxide fuel cells J Mater Chem 20 2010 3799 3813
34. 5+d as cathode material for doped lanthanum gallate electrolyte IT-SOFCs Fuel Cells 8 2008 351 359
35. N.Q. Minh, and T. Takahashi Science and technology of ceramic fuel cells 1995 Elsevier Amsterdam
36. 3+ on the electrochemical properties of hydrothermally prepared gadolinium-doped ceria ceramics J Alloys Compound 491 2010 106 112
37. 4 (ASm, Sr; BCo, Fe, Ni) samarium oxide system as cathode materials for intermediate temperature-operating solid oxide fuel cell Solid State Ionics 179 2008 1570 1574
38. 5-d oxides as cathodes for intermediate-temperature solid oxide fuel cells J Electrochem Soc 155 2008 B385 B390
39. 5-d (Ln = Pr, Sm, and Gd) as cathode materials for IT-SOFC J Electrochem Soc 156 2009 B682 B689
40. 5+δ perovskite oxides as cathode materials for proton-conducting SOFCs J Alloys Compound 492 2010 291 294
41. 1.9 composites prepared by physical mixing as electrodes of solid oxide fuel cells J Power Sources 195 2010 7187 7195
42. 3-d (0.3 < x < 0.7) J Eur Ceram Soc 26 2006 2827 2832
43. J.F. Moulder, W.F. Stickle, P.E. Sobol, and K.D. Bomben Standard spectra for identification and interpretation of XPS data 1992 Perkin Elmer Eden Prairie, MN
44. 2 catalyst Appl Catal A 217 2001 231 239
45. L. Fan, and K. Fujimoto Reaction mechanism of methanol synthesis from carbon dioxide and hydrogen on ceria-supported palladium catalysts with SMSI effect J Catal 172 1997 238 242
46. 2 prepared by deposition precipitation method Catal Commun 6 2005 796 801
47. 2-based oxides Bull Chem Soc Jpn 72 1999 313 320 (Pubitemid 29091889)
48. 2 prepared by deposition-precipitation method and the catalytic activity for methanol decomposition J Mol Catal A 153 2000 165 168
49. x defective layers Appl Surf Sci 158 2000 164 171
50. 2 catalysts after zinc addition J Catal 210 2002 127 136
51. 2 Appl Surf Sci 161 2000 301 315
52. A. Holmgren, F. Ararnoush, and F. Fridell Influence of pre-treatment on the low-temperature activity of Pt/ceria Appl Catal B 22 1999 49 61 (Pubitemid 29341693)
53. 2 supported on zirconium containing ordered mesoporous silica Catal Lett 129 2009 323 330
54. J.T.S. Irvine, D.C. Sinclair, and A.R. West Electroceramics: characterization by impedance spectroscopy Adv Mater 2 1990 132 138
55. J.R. Macdonald Impedance spectroscopy 1988 Wiley NY
56. 3-d thin films grown by pulsed laser deposition J Power Sources 171 2007 747 753 (Pubitemid 47368946)
57. D.Y. Wang, and A.S. Nowick Dielectric relaxation from a network of charged defects in dilute yttrium oxide-doped ceria solid solutions Solid State Ionics 5 1981 551 555
58. 3 system (0.05 < Gd/Ce < 0.4) prepared by oxalate coprecipitation Solid State Ionics 148 2002 567 573 (Pubitemid 34545688)