Shrinkage and pore structure in preparation of carbon aerogels

Journal of Sol-Gel Science and Technology

Volumn 59, Issue 2, 2011, Pages 371-380

  Feng, Junzong ^a   Feng, Jian ^a   Zhang, Changrui ^a  

^a NATIONAL UNIVERSITY OF DEFENSE TECHNOLOGY   (China)

Author keywords

Carbon aerogels; Linear shrinkage; Pore size; Supercritical drying

Indexed keywords

CARBON; CARBONIZATION; DRYING; MOLAR RATIO; PARTICLE SIZE; PORE SIZE; PORE STRUCTURE; SHRINKAGE; SODIUM CARBONATE; SODIUM COMPOUNDS; THERMAL INSULATING MATERIALS;

CARBON AEROGELS; CARBONIZATION PROCESS; LINEAR SHRINKAGE; LOWER DENSITY; RESORCINOL-FORMALDEHYDE AEROGELS; SUPERCRITICAL DRYING; SURFACE AREA; THERMAL INSULATORS;

AEROGELS;

EID: 80051545575     PISSN: 09280707     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10971-011-2514-8     Document Type: Article

References (43)

1. N Hüsing U Schubert 1998 Aerogels-airy materials: chemistry, structure, and properties Angew Chem Int Ed 37 22 45 10.1002/(SICI)1521- 3773(19980202)37:1/2<22::AID-ANIE22>3.0.CO;2-I
2. X Lu MC Arduini-Schuster J Kuhn 1992 Thermal conductivity of monolithic organic aerogels Science 255 971 972 10.1126/science.255.5047.971 1:CAS:528:DyaK38Xhs1ShsLk%3D (Pubitemid 23603847)
3. J Fricke A Emmerling 1998 Aerogels-recent progress in production techniques and novel applications J Sol-Gel Sci Technol 13 299 303 10.1023/A:1008663908431 1:CAS:528:DyaK1MXpvFejtg%3D%3D
4. BE Yoldas MJ Annen J Bostaph 2000 Chemical engineering of aerogel morphology formed under nonsupercritical conditions for thermal insulation Chem Mater 12 2475 2484 10.1021/cm9903428 1:CAS:528:DC%2BD3cXltFKis7Y%3D
5. AC Pierre GM Pajonk 2002 Chemistry of aerogels and their applications Chem Rev 102 4243 4265 10.1021/cr0101306 1:CAS:528:DC%2BD38XnvFCntLw%3D (Pubitemid 35410371)
6. M Wiener G Reichenauer F Hemberger HP Ebert 2006 Thermal conductivity of CAs as a function of pyrolysis temperature Int J Thermophys 27 1826 1843 10.1007/s10765-006-0086-6 1:CAS:528:DC%2BD28Xht1CqurnM (Pubitemid 44838239)
7. F Hemberger S Weis G Reichenauer HP Ebert 2009 Thermal transport properties of functionally graded CAs Int J Thermophys 30 1357 1371 10.1007/s10765-009-0616-0 1:CAS:528:DC%2BD1MXht1Wqtb7K
8. SS Kistler 1931 Coherent expanded aerogels and jellies Nature 227 741 10.1038/127741a0
9. ND Hegde AV Rao 2006 Effect of processing temperature on gelation and physical properties of low density TEOS based silica aerogels J Sol-Gel Sci Technol 38 55 61 10.1007/s10971-006-5348-z 1:CAS:528:DC%2BD28XktlSjtL4%3D (Pubitemid 43724133)
10. TF Baumann AE Gash SC Chinn AM Sawvel RS Maxwell JH Satcher Jr 2005 Synthesis of high-surface-area alumina aerogels without the use of alkoxide precursors Chem Mater 17 395 401 10.1021/cm048800m 1:CAS:528:DC%2BD2cXhtFChsrvM (Pubitemid 40139714)
11. V Štengl S Bakardjieva J Šubrt L Szatmary 2006 Titania aerogel prepared by low temperature supercritical drying Microporous Mesoporous Mater 91 1 6 10.1016/j.micromeso.2005.10.046
12. CN Chervin BJ Clapsaddle HW Chiu AE Gash JH Satcher Jr SM Kauzlarich 2005 Aerogel synthesis of yttria-stabilized zirconia by a non-alkoxide sol-gel route Chem Mater 17 3345 3351 10.1021/cm0503679 1:CAS:528:DC%2BD2MXksVWjt7g%3D (Pubitemid 41047925)
13. HB Ren L Zhang CW Shang X Wang YT Bi 2010 Synthesis of a low-density tantalum oxide tile-like aerogel monolithic J Sol-Gel Sci Technol 53 307 311 10.1007/s10971-009-2092-1 1:CAS:528:DC%2BC3cXhsFersrY%3D
14. M Krumm CL Pueyo S Polarz 2010 Monolithic zinc oxide aerogels from organometallic sol-gel precursors Chem Mater 22 5129 5136 10.1021/cm1006907 1:CAS:528:DC%2BC3cXhtVCks7%2FP
15. NC Bigall AK Herrmann M Vogel M Rose P Simon W Carrillo-Cabrera D Dorfs S Kaskel N Gaponik A Eychmüller 2009 Hydrogels and aerogels from noble metal nanoparticles Angew Chem Int Ed 48 9731 9734 1:CAS:528:DC%2BD1MXhsFGru77J
16. 2 powders Ceram Int 36 8 2269 2272 10.1016/j.ceramint.2010.07.020 1:CAS:528:DC%2BC3cXht1KgtLzO
17. 2 adsorption behavior of three-dimensional novel Pt-Ru hollow sphere assemblies Microporous Mesoporous Mater 117 1-2 208 212 1:CAS:528:DC%2BD1cXhsVSgsr7I
18. H Wang SY Zheng XD Li 2005 Preparation of three-dimensional ordered macroporous SiCN ceramic using sacrificing template method Microporous Mesoporous Mater 80 1-3 357 362 10.1016/j.micromeso.2005.01.014 1:CAS:528:DC%2BD2MXjtlKhsLs%3D (Pubitemid 40688586)
19. J Wang CR Zhang J Feng 2005 Effects of poly(ethylene glycol) on properties of nanoporous silica film J Inorg Mater 20 2 435 441 1:CAS:528:DC%2BD2MXjtlKqur0%3D (Pubitemid 40597535)
20. N Leventis C Sotiriou-Leventis N Chandrasekaran S Mulik ZJ Larimore HB Lu G Churu JT Mang 2010 Multifunctional polyurea aerogels from isocyanates and water. A structure-property case study Chem Mater 22 6692 6710 10.1021/cm102891d 1:CAS:528:DC%2BC3cXhsFakt7nK
21. MF Bertino JF Hund G Zhang C Sotiriou-Leventis AT Tokuhiro N Leventis 2004 Room temperature synthesis of noble metal clusters in the mesopores of mechanically strong silica-polymer aerogel composites J Sol-Gel Sci Technol 30 43 48 10.1023/B:JSST.0000028178.25991.9e 1:CAS:528:DC%2BD2cXktVGisrg%3D
22. JH Zou JH Liu AS Karakoti A Kumar D Joung Q Li SI Khondaker S Seal L Zhai 2010 Ultralight multiwalled carbon nanotube aerogel ACS Nano 4 12 7293 7302 10.1021/nn102246a 1:CAS:528:DC%2BC3cXhsVGkt7rN
23. MA Worsley PJ Pauzauskie TY Olson J Biener JH Satcher TF Baumann 2010 Synthesis of graphene aerogel with high electrical conductivity J Am Chem Soc 132 14067 14069 10.1021/ja1072299 1:CAS:528:DC%2BC3cXhtF2msr%2FK
24. M Shafaei-Fallah JQ He A Rothenberger MG Kanatzidis 2011 Ion-exchangeable cobalt polysulfide chalcogel J Am Chem Soc 133 1200 1202 10.1021/ja1089028 1:CAS:528:DC%2BC3MXivFCitA%3D%3D
25. M Inagaki 2009 Pores in carbon materials-importance of their control New Carbon Mater 24 3 193 232 10.1016/S1872-5805(08)60048-7 1:CAS:528: DC%2BD1MXhtlanu7zO
26. M Wiener G Reichenauer S Braxmeier F Hemberger HP Ebert 2009 CA-based high-temperature thermal insulation Int J Thermophys 30 1372 1385 10.1007/s10765-009-0595-1 1:CAS:528:DC%2BD1MXht1Wqtb%2FM
27. SA Al-Muhtaseb JA Ritter 2003 Preparation and properties of resorcinol-formaldehyde organic and carbon gels Adv Mater 15 2 101 114 10.1002/adma.200390020 1:CAS:528:DC%2BD3sXhtlCmtbs%3D
28. V Drach M Wiener G Reichenauer H-P Ebert J Fricke 2007 Determination of the anisotropic thermal conductivity of a carbon aerogel-fiber composite by a non-contact thermographic technique Int J Thermophys 28 1542 1562 10.1007/s10765-006-0145-z 1:CAS:528:DC%2BD2sXht1Oktr7N (Pubitemid 350084914)
29. J Yang S Li Y Luo L Yan F Wang 2011 Compressive properties and fracture behavior of ceramic fiber-reinforced carbon aerogel under quasi-static and dynamic loading Carbon 49 1542 1549 10.1016/j.carbon.2010.12.021 1:CAS:528:DC%2BC3MXhsFOhurg%3D
30. X Lu O Nilsson J Fricke 1993 Thermal and electrical conductivity of monolithic CAs J Appl Phys 73 2 581 584 10.1063/1.353367
31. RW Pekala 1989 Organic aerogels from the polycondensation of resorcinol with formaldehyde J Mater Sci 24 3221 3227 10.1007/BF01139044 1:CAS:528:DyaK3cXotF2k (Pubitemid 20600977)
32. AI Cooper MJ Rosseinsky 2009 Improving pore performance Nat Chem 1 26 27 10.1038/nchem.157 1:CAS:528:DC%2BD1MXktlSlsbc%3D
33. G Qin W Wei S Guo 2003 Semi-continuous drying of RF gels with supercritical acetone Carbon 41 851 853 10.1016/S0008-6223(03)00016-2 1:CAS:528:DC%2BD3sXit12jtLk%3D
34. R Saliger V Bock R Petricevic T Tillotson S Geis J Fricke 1997 Carbon aerogels from dilute catalysis of resorcinol with formaldehyde J Non-Cryst Solids 221 144 150 10.1016/S0022-3093(97)00411-0 1:CAS:528:DyaK2sXotVyitb4%3D (Pubitemid 127433536)
35. C Lin JA Ritter 2000 Carbonization and activation of sol-gel derived carbon xerogels Carbon 38 849 861 10.1016/S0008-6223(99)00189-X 1:CAS:528:DC%2BD3cXjtFyqtrk%3D
36. C Lin JA Ritter 1997 Effect of synthesis pH on the structure of carbon xerogels Carbon 35 1271 1278 10.1016/S0008-6223(97)00069-9 1:CAS:528: DyaK2sXntVOltrw%3D (Pubitemid 127393485)
37. N Job R Pirard J Marien JP Pirard 2004 Porous carbon xerogels with texture tailored by pH control during sol-gel process Carbon 42 619 628 10.1016/j.carbon.2003.12.072 1:CAS:528:DC%2BD2cXhtVKitrw%3D
38. KL Murray NA Seaton MA Day 1999 An adsorption-based method for the characterization of pore networks containing both mesopores and macropores Langmuir 15 6728 6737 10.1021/la990159t 1:CAS:528:DyaK1MXksFGitbY%3D
39. RW Pekala 1993 Structure of organic aerogels. 1. Morphology and scaling Macromolecules 26 5487 5493 10.1021/ma00072a029 1:CAS:528:DyaK3sXls1Wntr8%3D
40. N Job A Thery R Pirard J Marien L Kocon JN Rouzaud, et al. 2005 Carbon aerogels, cryogels and xerogels: influence of the drying method on the textural properties of porous carbon materials Carbon 43 2481 2494 10.1016/j.carbon.2005. 04.031 1:CAS:528:DC%2BD2MXntVGgt7k%3D (Pubitemid 41085053)
41. RW Fu TF Baumann S Cronin G Dresselhaus MS Dresselhaus JH Satcher Jr 2005 Formation of graphitic structures in cobalt- and nickel-doped carbon aerogels Langmuir 21 2647 2651 10.1021/la047344d 1:CAS:528:DC%2BD2MXhsVOqsrg%3D (Pubitemid 40448919)
42. AH Lu WC Li EL Salabas B Spliethoff F Schüth 2006 Low temperature catalytic pyrolysis for the synthesis of high surface area, nanostructured graphitic carbon Chem Mater 18 2086 2094 10.1021/cm060135p 1:CAS:528: DC%2BD28XislOgsbo%3D
43. N Job F Panariello J Marien M Crine JP Pirard A Leonard 2006 Synthesis optimization of organic xerogels produced from convective air-drying of resorcinol-formaldehyde gels J Non-Cryst Solids 352 24 34 10.1016/j.jnoncrysol. 2005.11.024 1:CAS:528:DC%2BD2MXhtlCmsL3L (Pubitemid 41828419)