Palladium-mediated olefination of 2-(tert-butyldimethylsilyl)pyridine by sp3 C-H activation

Synthesis

Volumn , Issue 16, 2011, Pages 2590-2594

  Wang, Cong ^a   Ge, Haibo ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

olefination; palladium; pyridine

Indexed keywords

ALLYLSILANES; C-H ACTIVATION; OLEFINATION; TERT-BUTYLDIMETHYLSILYL;

ACTIVATION ANALYSIS; CHEMICAL REACTIONS;

PYRIDINE;

1,2 DICHLOROETHANE; 2 (TERT BUTYLDIMETHYLSILYL)PYRIDINE DERIVATIVE; ACRYLIC ACID DERIVATIVE; BENZONITRILE(DICHLORO)PALLADIUM; BENZYL 4 [TERT BUTYL(METHYL)PYRIDIN 2 YLSILYL]BUT 2 ENOATE; BUTYL 4 [TERT BUTYL(METHYL)PYRIDIN 2 YLSILYL]BUT 2 ENOATE; COPPER ACETATE; ETHYL 4 [TERT BUTYL(METHYL)PYRIDIN 2 YLSILYL]BUT 2 ENOATE; METHYL 2 [2 [TERT BUTYL(METHYL)PYRIDIN 2 YLSILYL]ETHYL]ACRYLATE; METHYL 4 [TERT BUTYL(METHYL)PYRIDIN 2 YLSILYL] 3 METHYLBUT 2 ENOATE; METHYL 4 [TERT BUTYL(METHYL)PYRIDIN 2 YLSILYL]BUT 2 ENOATE; PALLADIUM ACETATE; PALLADIUM CHLORIDE; PALLADIUM COMPLEX; POTASSIUM CARBONATE; POTASSIUM DIHYDROGEN PHOSPHATE; PYRIDINE DERIVATIVE; SODIUM CARBONATE; SOLVENT; TERT BUTYL 2 [2 [TERT BUTYL(METHYL)PYRIDIN 2 YLSILYL]ETHYL]ACRYLATE; TERT BUTYL 4 [TERT BUTYL(METHYL)PYRIDIN 2 YLSILYL]BUT 2 ENOATE; TERT BUTYLACRYLATE; TETRAHYDROFURAN; TOLUENE; UNCLASSIFIED DRUG;

ALKENYLATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; HECK REACTION; OLEFINATION; REACTION TEMPERATURE; REACTION TIME; TEMPERATURE;

EID: 80051528418     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0030-1260075     Document Type: Article

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