In-cloud multiphase behaviour of acetone in the troposphere: Gas uptake, Henry's law equilibrium and aqueous phase photooxidation

Chemosphere

Volumn 81, Issue 3, 2010, Pages 312-320

  Poulain, Laurent ^a   Katrib, Yasmine ^b   Isikli, Estelle ^b   Liu, Yao ^a   Wortham, Henri ^a   Mirabel, Philippe ^b   Calvé, Stéphane Le ^b   Monod, Anne ^a  

^a AIX MARSEILLE UNIVERSITY   (France)

^b UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

Acetone; Aqueous phase reactivity; Hydroxyl radical; Oxidation mechanism; Water solubility

Indexed keywords

ACETIC ACID; ATMOSPHERIC CHEMISTRY; DROPS; FORMALDEHYDE; OXIDATION; PH; PHOTOOXIDATION; TROPOSPHERE;

AQUEOUS-PHASE REACTIVITY; ATMOSPHERIC IMPLICATIONS; GAS-PHASE REACTIVITY; HYDROXYL RADICALS; MASS ACCOMMODATION COEFFICIENT; OXIDATION MECHANISMS; TROPOSPHERIC CHEMISTRY; WATER SOLUBILITIES;

ACETONE;

ACETIC ACID; ACETONE; FORMALDEHYDE; FORMIC ACID; HYDROPEROXIDE; HYDROXYACETONE; KETONE DERIVATIVE; METHYLGLYOXAL; PERACETIC ACID; UNCLASSIFIED DRUG; WATER;

ACETIC ACID; ACETONE; ATMOSPHERIC CHEMISTRY; CLOUD DROPLET; GAS PHASE REACTION; HYDROXYL RADICAL; MASS SPECTROMETRY; PH; PHOTOOXIDATION; TROPOSPHERE;

ARTICLE; GAS TRANSPORT; HENRY LAW; MASS SPECTROMETRY; MATHEMATICAL PARAMETERS; PH; PHASE TRANSITION; PHOTOOXIDATION; TROPOSPHERE;

EID: 79960975284     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2010.07.032     Document Type: Article

References (67)

1. Altieri K.E., Seitzinger S.P., Carlton A.G., Turpin B.J., Klein G.C., Marshall A.G. Oligomers formed through in-cloud methylglyoxal reactions: chemical composition, properties, and mechanisms investigated by ultra-high resolution FT-ICR mass spectrometry. Atmos. Environ. 2008, 42:1476-1490.
2. 3 with 2-methyl-3-buten-2-ol. Atmos. Environ. 1999, 33:2893-2905.
3. Atkinson R. Gas-phase tropospheric chemistry of organic-compounds. J. Phys. Chem. Ref. Data 1994, R1.
4. Baker B., Guenther A., Greenberg J., Fall R. Canopy level fluxes of 2-methyl-3-buten-2-ol, acetone, and methanol by a portable relaxed eddy accumulation system. Environ. Sci. Technol. 2001, 35:1701-1708.
5. Benkelberg H.J., Hamm S., Warneck P. Henry's law coefficients for aqueous solutions of acetone, acetaldehyde and acetonitrile, and equilibrium constants for the addition compounds of acetone and acetaldehyde with bisulfite. J. Atmos. Chem. 1995, 20:17-34.
6. Betterton E.A. The partitioning of ketones between the gas and aqueous phases. Atmos. Environ. A - Gen. 1991, 25:1473-1477.
7. Betterton E.A., Hoffmann M.R. Henry's law constants of some environmentally important aldehydes. Environ. Sci. Technol. 1988, 22:1415-1418.
8. 2. Anal. Biochem. 1984, 142:207-209.
9. Burnett M.G. Determination of partition coefficients at infinite dilution by gas chromatographic analysis of the vapor above dilute solutions. Anal. Chem. 1963, 35:1567-1570.
10. Buttery R.G., Ling J.L., Guadagni D.G. Volatilities of aldehydes, ketones, and esters in dilute water solution. J. Agric. Food Chem. 1969, 17:385-389.
11. Custódio D., Guimarães C.S., Varandas L., Arbilla G. Pattern of volatile aldehydes and aromatic hydrocarbons in the largest urban rainforest in the Americas. Chemosphere 2010, 79:1064-1069.
12. Dievart P., Allou L., Louis F., Le Calvé S. Tropospheric multiphase chemistry of 2, 5-and 2, 6-dimethylphenols: determination of the mass accommodation coefficients and the Henry's law constants. Phys. Chem. Chem. Phys. 2006, 8:1714-1723.
13. El Haddad I., Liu Y., Nieto-Gligorovski L., Michaud V., Temime-Roussel B., Quivet E., Marchand N., Sellegri K., Monod A. In-cloud processes of methacrolein under simulated conditions - Part 2: formation of secondary organic aerosol. Atmos. Chem. Phys. 2009, 9:5107-5117.
14. Ervens B., Gligorovski S., Herrmann H. Temperature-dependent rate constants for hydroxyl radical reactions with organic compounds in aqueous phase. Phys. Chem. Chem. Phys. 2003, 5:1811-1824.
15. Facchini M.C., Decesari S., Mircea M., Fuzzi S., Loglio G. Surface tension of atmospheric wet aerosol and cloud/fog droplets in relation to their organic carbon content and chemical composition. Atmos. Environ. 2000, 34:4853-4857.
16. Fall R., Custer T.G., Kato S., Bierbaum V.M. New directions: the biogenic acetone-HCN connection. Atmos. Environ. 2001, 35:1713-1714.
17. Feigenbrugel V., Le Calvé S., Mirabel P. Temperature dependence of Henry's law constants of metolachlor and diazinon. Chemosphere 2004, 57:319-327.
18. Feigenbrugel V., Le Calvé S., Mirabel P., Louis F. Henry's law constant measurements for phenol, o-, m-, and p-creso as a function of temperature. Atmos. Environ. 2004, 38:5577-5588.
19. 2 and several organic hydroperoxides for field campaigns. Atmos. Res. 2005, 74:525-545.
20. x to increase ecosystem effects. Environ. Sci. Technol. 1987, 21:519-524.
21. Gautier C., Le Calve S., Mirabel P. Henry's law constants measurements of alachlor and dichlorvos between 283 and 298 K. Atmos. Environ. 2003, 37:2347-2353.
22. Grosjean D., Wright B. Carbonyls in urban fog, ice fog, cloudwater and rainwater. Atmos. Environ. 1983, 17:2093-2096.
23. Guillard C., Charton N., Pichat P. Degradation mechanism of t-butyl methyl ether (MTBE) in atmospheric droplets. Chemosphere 2003, 53:469-477.
24. Hallquist M., Wenger J.C., Baltensperger U., Rudich Y., Simpson D., Claeys M., Dommen J., Donahue N.M., George C., Goldstein A.H., Hamilton J.F., Herrmann H., Hoffmann T., Iinuma Y., Jang M., Jenkin M.E., Jimenez J.L., Kiendler-Scharr A., Maenhaut W., McFiggans G., Mentel T.F., Monod A., Prevot A.S.H., Seinfeld J.H., Surratt J.D., Szmigielski R., Wildt J. The formation, properties and impact of secondary organic aerosol: current and emerging issues. Atmos. Chem. Phys. 2009, 9:5155-5236.
25. Hoff J.T., Mackay E., Gillham R., Shiu W.Y. Partitioning of organic chemicals at the air-water interface in environmental systems. Environ. Sci. Technol. 1993, 27:2174-2180.
26. Holzinger R., Carsten W., Hansel A., Jordan A., Lindinger W., Scharffe D.H., Schade G., Crutzen P.J. Biomass burning as a source of formaldehyde, acetaldehyde, methanol, acetone, acetonitrile, and hydrogen cyanide. Geophys. Res. Lett. 1999, 26:1161-1164.
27. Houdier S., Perrier S., Defrancq E., Legrand M. A new fluorescent probe for sensitive detection of carbonyl compounds: sensitivity improvement and application to environmental water samples. Anal. Chim. Acta 2000, 412:221-233.
28. Jacob D.J., Field B.D., Jin E.M., Bey I., Li Q., Logan J.A., Yantosca R.M. Atmospheric budget of acetone. J. Geophys. Res. 2002, 107. (ACH5-1: ACH5-19).
29. Janini G.M., Qaddora L.A. Determination of activity-coefficients of oxygenated hydrocarbons by liquid-liquid chromatography. J. Liq. Chromatogr. 1986, 9:39-53.
30. Janson R., de Serves C. Acetone and monoterpene emissions from the boreal forest in northern Europe. Atmos. Environ. 2001, 35:4629-4637.
31. Kalberer M., Paulsen D., Sax M., Steinbacher M., Dommen J., Prevot A.S.H., Fisseha R., Weingartner E., Frankevich V., Zenobi R., Baltensperger U. Identification of polymers as major components of atmospheric organic aerosols. Science 2004, 303:1659-1662.
32. Kolb C.E., Worsnop D.R., Zahniser M.S., Davidovits P., Hanson D.R., Ravishankara A.R., Keyser L.F., Leu M.T., Williams L.R., Molina M.J., Tolbert M.A. Laboratory studies of atmospheric heterogeneous chemistry. Advances in Physical Chemistry Series 1995, 771. World Scientific, Singapore. J.R.E. Backer (Ed.).
33. Lo J.-H.A., Lee W.-M.G. Effect of surfactant film on solubility of hydrophobic organic compounds in fog droplets. Chemosphere 1996, 33:1391-1408.
34. Magi L., Schweitzer F., Pallares C., Cherif S., Mirabel P., George C. Investigation of the uptake rate of ozone and methyl hydroperoxide by water surfaces. J. Phys. Chem. A 1997, 101:4943-4949.
35. McElroy W.J., Waygood S.J. Oxidation of formaldehyde by the hydroxyl radical in aqueous-solution. J. Chem. Soc. Faraday Trans. 1991, 87:1513-1521.
36. Mitani M.M., Keller A.A., Bunton C.A., Rinker R.G., Sandall O.C. Kinetics and products of reactions of MTBE with ozone and ozone/hydrogen peroxide in water. J. Hazard. Mater. 2002, 89:197-212.
37. Monod A., Poulain L., Grubert S., Voisin D., Wortham H. Kinetics of OH-initiated oxidation of oxygenated organic compounds in the aqueous phase: new rate constants, structure-activity relationships and atmospheric implications. Atmos. Environ. 2005, 39:7667-7688.
38. Monod A., Chevallier E., Jolibois R.D., Doussin J.F., Picquet-Varrault B., Carlier P. Photooxidation of methylhydroperoxide and ethylhydroperoxide in the aqueous phase under simulated cloud droplet conditions. Atmos. Environ. 2007, 41:2412-2426.
39. Reid R.C., Praunsnitz J.M., Poling B.E. The Properties of Gazes and Liquids 1987, McGraw-Hill, New York, USA. fourth ed.
40. Rosado-Reyes C.M., Francisco J.S. Atmospheric oxidation pathways of propane and its by-products: acetone, acetaldehyde, and propionaldehyde. J. Geophys. Res. - Atmos. 2007, 112:D14310.
41. Russell G.A. Deuterium-isotope effects in the autoxidation of aralkyl hydrocarbons. Mechanism of the interaction of peroxy radicals. J. Am. Chem. Soc. 1957, 79:3871-3877.
42. Schaffer D.L., Daubert T.E. Gas-liquid chromatographic determination of solution properties of oxygenated compounds in water. Anal. Chem. 2002, 41:1585-1589.
43. Schuchmann M.N., Von Sonntag C. The rapid hydratation of the acetyl radical. A pulse radiolysis study of acetaldehyde in aqueous solution. J. Am. Chem. Soc. 1988, 110:5698-5701.
44. Schweitzer F., Magi L., Mirabel P., George C. Uptake rate measurements of methanesulfonic acid and glyoxal by aqueous droplets. J. Phys. Chem. A 1998, 102:593-600.
45. Singh H.B., Hanst P.L. Peroxyacetyl nitrate (PAN) in the unpolluted atmosphere - an important reservoir for nitrogen-oxides. Geophys. Res. Lett. 1981, 8:941-944.
46. Singh H.B., O'Hara D., Herlth D., Sachse W., Blake D.R., Bradshaw J.D., Kanakidou M., Crutzen P.J. Acetone in the atmosphere: distribution, sources, and sinks. J. Geophys. Res. - Atmos. 1994, 99:1805-1819.
47. Singh H.B., Kanakidou M., Crutzen P.J., Jacob D.J. High concentrations and photochemical fate of oxygenated hydrocarbons in the global troposphere. Nature 1995, 378:50-54.
48. Singh H., Chen Y., Tabazadeh A., Fukui Y., Bey I., Yantosca R., Jacob D., Arnold F., Wohlfrom K., Atlas E., Flocke F., Blake D.R., Blake N., Heikes B., Snow J., Talbot R., Gregory G., Sachse G., Vay S., Kondo Y. Distribution and fate of selected oxygenated organic species in the troposphere and lower stratosphere over the Atlantic. J. Geophys. Res. - Atmos. 2000, 105:3795-3805.
49. Singh T.S., Gejji S.P., Rao B.S.M., Mohan H., Mittal J.P. Radiation chemical oxidation of aniline derivatives. J. Chem. Soc. Perk. Trans. 2001, 2:1205-1211.
50. Snider J.R., Dawson G.A. Tropospheric light alcohols, carbonyls and acetonitrile; concentrations in the southwestern United States and Henry's law data. J. Geophys. Res. - Atmos. 1985, 90:3797-3805.
51. Spaulding R.S., Schade G.W., Goldstein A.H., Charles M.J. Characterisation of secondary atmospheric photooxidation products: evidence for biogenic and anthropogenic sources. J. Geophys. Res. - Atmos. 2003, 108. (ACH7-1: ACH7-17).
52. 2 and speciation of organic exhaust emission. Atmos. Environ. 1998, 32:999-1009.
53. Staudinger J., Roberts P.V. A critical review of Henry's law constants for environmental applications. Crit. Rev. Environ. Sci. Technol. 1996, 26:205-297.
54. 2 process. Environ. Sci. Technol. 1999, 33:870-873.
55. Stefan M.I., Hoy A.R., Bolton J.R. Kinetics and mechanism of the degradation and mineralization of acetone in dilute aqueous solution sensitized by the UV photolysis of hydrogen peroxide. Environ. Sci. Technol. 1996, 30:2382-2390.
56. Strekowski R.S., George C. Measurement of Henry's law constants for acetone, 2-butanone, 2,3-butanedione, and isobutyraldehyde using a horizontal flow reactor. J. Chem. Eng. Data 2005, 50:804-810.
57. Valsaraj K.T., Thoma G.J., Reible D.D., Thibodeaux L.J. On the enrichment of hydrophobic organic compounds in fog droplets. Atmos. Environ. 1993, 27A:203-210.
58. van Pinxteren D., Plewka A., Hofmann D., Müller K., Kramberger H., Svrcina B., Bächmann K., Jaeschke W., Mertes S., Collet J.L., Herrmann H. Schmucke hill cap cloud and valley stations aerosol characterisation during FEBUKO (II): organic compounds. Atmos. Environ. 2005, 39:4305-4320.
59. Vitenberg A.G., Loffe B.V., Dimitrova Z.S., Butaeva I.L. Determination of gas-liquid partition coefficients by means of gas chromatographic analysis. J. Chromatogr. A 1975, 112:319-327.
60. Von Sonntag C., Schuchmann H.-P. Peroxyl Radicals in Aqueous Solution 1997, John Wiley & Sons Ltd., Chichester, England.
61. Warneck P. Multi-phase chemistry of C-2 and C-3 organic compounds in the marine atmosphere. J. Atmos. Chem. 2005, 51:119-159.
62. Wisthaler A., Jensen N.R., Winterhalter R., Lindinger W., Hjorth J. Measurements of acetone and other gas phase product yields from the OH-initiated oxidation of terpenes by proton-transfer-reaction mass spectrometry (PTR-MS)*1. Atmos. Environ. 2001, 35:6181-6191.
63. 2 on aqueous surfaces. J. Phys. Chem. 1989, 93:1159-1172.
64. 2: a study on the γ-radiolysis and pulse radiolysis of acetone in oxygenated aqueous solutions. Z. Naturforsch. 1986, 41b:1015-1022.
65. Zellner R., Herrmann H. Free radical chemistry of the aqueous atmospheric phase. Spectroscopy in Environmental Science 1995, 381-451. John Wiley & Sons. R.E. Hester, R.J.H. Clark (Eds.).
66. Zhou X., Mopper K. Apparent partition coefficients of 15 carbonyl compounds between air and seawater and between air and freshwater; implications for air-sea exchange. Environ. Sci. Technol. 1990, 24:1864-1869.
67. Zhou X., Mopper K. Photochemical production of low-molecular-weight carbonyl compounds in seawater and microlayer and their air-sea exchange. Mar. Chem. 1997, 56:201-213.