Photochemical production of low-molecular-weight carbonyl compounds in seawater and surface microlayer and their air-sea exchange

Marine Chemistry

Volumn 56, Issue 3-4, 1997, Pages 201-213

  Zhou, Xianliang ^a,c   Mopper, Kenneth ^b  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

^b WASHINGTON STATE UNIVERSITY   (United States)

^c WADSWORTH CENTER   (United States)

Author keywords

air sea exchange; carbonyl; photoproduction; seawater; surface microlayer

Indexed keywords

AIR-WATER EXCHANGES; CARBONYL; ORGANIC COMPOUNDS; PHOTOCHEMISTRY;

EID: 0031104877     PISSN: 03044203     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0304-4203(96)00076-X     Document Type: Article

References (32)

1. Bell, R.P. and Avans, P.G., 1966. Kinetics of the dehydration of methylene glycol in aqueous solution. Proc. R. Soc. London, Ser. A, 291: 297-321.
2. Blanchard, D.C., 1964. Sea-to-air transport of surface active material. Science, 146: 396-397.
3. Carlson, D.J., 1982. Surface microlayer phenolic enrichments indicate sea surface slicks. Nature (London), 296: 426-429.
4. Carlson, D.J., 1983. Dissolved organic materials in surface microlayers: Temporal and spatial variability and relation to sea state. Limnol. Oceanogr., 28: 415-431.
5. 2O) across the ocean-atmosphere interface. J. Atmos. Chem., 6: 83-94.
6. Eberhardt, M.A. and Sieburth, J.McN., 1985. A colorimetric procedure for the determination of aldehydes in seawater and in cultures of methylotrophic bacteria. Mar. Chem., 17: 199-212.
7. Eisenriech, S.J., Elzerman, A.W. and Armstrong, D.E., 1978. Enrichment of micronutrients, heavy metals, and chlorinated hydrocarbons in wind-generated lake foam. Environ. Sci. Technol., 12: 413-417.
8. 2 production in surface microlayer and surface-water samples: Influence of UV and visible radiation. Mar. Ecol. Prog. Ser., 77: 21-26.
9. Garrett, W.D., 1965. Collection of slick-forming materials from the sea surface. Limnol. Oceanogr., 10: 602-604.
10. Garrett, W.D., 1967. Stabilization of air bubbles at the air-sea interface by surface-active material. Deep-Sea Res., 14: 661-672.
11. Hardy, J.T., 1982. The sea surface microlayer: Biology, chemistry and anthropogenic enrichment. Prog. Oceanogr., 11: 307-328.
12. Hardy, J.T., Apts, C.W., Crecelius, E.A. and Fellingham, G.W., 1985. The sea-surface microlayer: Fate and residence times of atmospheric metals. Limnol. Oceanogr., 30: 93-101.
13. Hoover, T.E. and Berkshire, D.C., 1969. Effects of hydration on carbon dioxide exchange across an air-water interface. J. Geophys. Res., 74: 456-464.
14. Johnson, B.D., Zhou, X., Parrish, C.C., Wangersky, P.J. and Kerman, B.R., 1989. Fractionation of particulate matter, the trace metals Cu, Cd, and Zn, and lipids in foam and water below Niagara Falls. J. Great Lakes Res., 15: 189-196.
15. Kieber, D.J. and Mopper, K., 1987. Photochemical formation of glyoxylic and pyruvic acids in seawater. Mar. Chem., 21: 135-149.
16. Kieber, R.J. and Mopper, K., 1990. Determination of picomolar concentrations of carbonyl compounds in natural waters, including seawater, by liquid chromatography. Environ. Sci. Technol., 24: 1477-1481.
17. Kieber, D.J., McDaniel, J.A. and Mopper, K., 1989. Photochemical source of biological substrates in seawater: Implications for carbon cycling. Nature (London), 341: 637-639.
18. Kieber, R.J., Zhou, X. and Mopper, K., 1990. Formation of carbonyl compounds from UV-induced photodegradation of humic substances in natural waters: Fate of riverine carbon in the sea. Limnol. Oceanogr., 35: 1503-1515.
19. Liss, P.S., 1975. Chemistry of the sea-surface microlayer. In: J.P. Riley and G. Skirrow (Editors), Chemical Oceanography. Academic Press, London, 2nd ed.
20. Liss, P.S. and Slater, P.G., 1974. Flux of gases across the air-sea interface. Nature (London), 247: 181-185.
21. Mopper, K. and Kieber, D.J., 1991. Distribution and biological turnover of dissolved organic compounds in the water column of the Black Sea. Deep-Sea Res., 38: 1021-1047.
22. Mopper, K. and Stahovec, W.L., 1986. Photochemical production of low molecular weight organic carbonyl compounds in seawater. Mar. Chem., 19: 305-321.
23. Mopper, K., Zhou, X., Kieber, R.J., Kieber, D.J., Sikorski, R.J. and Jones, R.D., 1991. Role of photochemical degradation in the cycling of oceanic dissolved organic carbon. Nature (London), 353: 60-62.
24. Schautman, M.A. and Morgan, J.J., 1993. Effects of aqueous chemistry on the binding of polycyclic aromatic hydrocarbons by dissolved humic materials. Environ. Sci. Technol., 27: 961-969.
25. Schecker, H. and Schultz, G., 1969. Untersuchungen hydrationskinetik von formaldehyde in wassriger losung. Z. Phys. Chem., Neue Folge, 65: 221-224.
26. Thompson, A.M., 1980. Wet and dry removal of tropospheric formaldehyde at a coastal site. Tellus, 32: 376-383.
27. Thompson, A.M. and Zafiriou, O.C., 1983. Air-sea fluxes of transient atmospheric species. J. Geophys. Res., 88C: 6696-6708.
28. Van Vleet, E. and Williams, P.M., 1983. Surface potential and film pressure measurements in seawater systems. Limnol. Oceanogr., 28: 401-414.
29. Zafiriou, O.C., Alford, J., Herrera, M., Peltzer, E.T., Gagosian, R.B. and Liu, S.C., 1980. Formaldehyde in remote marine air and rain: Flux measurements and estimates. Geophys. Res. Lett., 7: 341-344.
30. Zhou, X. and Lee, Y.-N., 1994. Henry's Law solubilities of some multiple-oxygenated carbonyl compounds. J. Phys. Chem., submitted.
31. Zhou, X. and Mopper, K., 1990. Apparent partition coefficients of 15 carbonyl compounds between air and seawater and between air and freshwater: Implications for air-sea exchange. Environ. Sci. Technol., 24: 1864-1869.
32. Zhou, X. and Mopper, K., 1993. Carbonyl compounds in the lower marine troposphere over the Caribbean Sea and Bahamas, J. Geophys. Res., 98C: 2385-2392.