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0032556663
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0013299605
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This C(O)-P(O) bond cleavage was demonstrated to play a pivotal role in the catalytic decarbonylation and metathesis reactions of α- ketophosphonates
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H. Nakazawa Y. Matsuoka I. Nakagawa K. Miyoshi Organometallics 1992 11 1385
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66149106621
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A related aryl-P(O) bond cleavage has been recently observed upon coordination of secondary phosphine oxide-oxazoline ligands at iridium under basic conditions:
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T. Mizuta N. Tanaka Y. Iwakuni K. Kubo K. Miyoshi Organometallics 2009 28 2808
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P. Gualco T. P. Lin M. Sircoglou M. Mercy S. Ladeira G. Bouhadir L. M. Perez A. Amgoune L. Maron F. P. Gabbaï D. Bourissou Angew. Chem., Int. Ed. 2009 48 9892
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For computational studies of C-P bond cleavage/formation at transition metals, see:
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M. Gagliardo G. Rodríguez H. H. Dam M. Lutz A. L. Spek R. W. A. Havenith P. Coppo L. De Cola F. Hartl G. P. M. van Klink G. van Koten Inorg. Chem. 2006 45 2143
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40
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P,P+,P-pincer complex featuring a central cationic phosphenium moiety, see:
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