Graphene actuators: Quantum-mechanical and electrostatic double-layer effects

Journal of the American Chemical Society

Volumn 133, Issue 28, 2011, Pages 10858-10863

  Rogers, Geoffrey W ^a   Liu, Jefferson Z ^a  

^a MONASH UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

AB INITIO; ACTUATION MECHANISM; ATOMIC CHARGE; CARBON MATERIAL; DOUBLE LAYERS; ELECTROCHEMICAL ACTUATION; ELECTROCHEMICAL STRAIN; FIRST-PRINCIPLES; LIQUID ELECTROLYTES; NANO ELECTROMECHANICAL SYSTEMS; QUANTUM MECHANICAL;

ACTUATORS; CALCULATIONS; ELECTRIC POTENTIAL; ELECTROSTATIC ACTUATORS; ELECTROSTATICS; MONOLAYERS;

GRAPHENE;

CARBON; GRAPHENE;

ARTICLE; CONTROLLED STUDY; COUPLING FACTOR; COVALENT BOND; ELECTRIC POTENTIAL; ELECTROSTATIC DOUBLE LAYER POTENTIAL; MATHEMATICAL MODEL; NANOELECTROMECHANICAL SYSTEM; QUANTUM MECHANICS; STATIC ELECTRICITY;

EID: 79960248336     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja201887r     Document Type: Article

References (34)

1. Baughman, R.; Cui, C.; Zakhidov, A.; Iqbal, Z.; Barisci, J.; Spinks, G.; Wallace, G.; Mazzoldi, A.; DeRossi, D.; Rinzler, A.; Jaschinski, O.; Roth, S.; Kertesz, M. Science 1999, 284, 1340
2. Madden, J.; Barisci, J.; Anquetil, P.; Spinks, G.; Wallace, G.; Baughman, R.; Hunter, I. Adv. Mater. 2006, 18, 870
3. Hughes, M.; Spinks, G. Adv. Mater. 2005, 17, 443
4. Barisci, J.; Wallace, G.; MacFarlane, D.; Baughman, R. Electrochem. Commun. 2004, 6, 22
5. Novoselov, K.; Geim, A.; Morozov, S.; Jiang, D.; Zhang, Y.; Dubonos, S.; Grigorieva, I.; Firsov, A. Science 2004, 306, 666
6. Geim, A.; Novoselov, K. Nat. Mater. 2007, 6, 183
7. Castro Neto, A.; Guinea, F.; Peres, N.; Novoselov, K.; Geim, A. Rev. Mod. Phys. 2009, 81, 109
8. Geim, A. Science 2009, 324, 1530
9. Bunch, J.; van der Zande, A.; Verbridge, S.; Frank, I.; Tanenbaum, D.; Parpia, J.; Craighead, H.; McEuen, P. Science 2007, 315, 490
10. Park, S.; An, J.; Suk, J.; Ruoff, R. Small 2010, 6, 210
11. Xie, X.; Qu, L.; Zhou, C.; Li, Y.; Zhu, J.; Bai, H.; Shi, G.; Dai, L. ACS Nano 2010, 4, 6050
12. Sun, G.; Kürti, J.; Kertesz, M.; Baughman, R. J. Am. Chem. Soc. 2002, 124, 15076
13. Sun, G.; Kertesz, M.; Kürti, J.; Baughman, R. Phys. Rev. B 2003, 68, 125411
14. Verissimo-Alves, M.; Koiller, B.; Chacham, H.; Capaz, R. Phys. Rev. B 2003, 67, 161401
15. Pastewka, L.; Koskinen, P.; Elsässer, C.; Moseler, M. Phys. Rev. B 2009, 80, 155428
16. Boda, D.; Henderson, D.; Chan, K. J. Chem. Phys. 1999, 110, 5346
17. Schmickler, W. Chem. Rev. 1996, 96, 3177
18. Armand, M.; Endres, F.; MacFarlance, D.; Ohno, H.; Scrosati, B. Nat. Mater. 2009, 8, 621
19. Kornyshev, A. J. Phys. Chem. B 2007, 111, 5545
20. Galiǹski, M.; Lewandowski, A.; Stȩpniak, I. Electrochim. Acta 2006, 51, 5567
21. Kresse, G.; Furthmüller, J. Phys. Rev. B 1996, 54, 169
22. Kresse, G.; Joubert, D. Phys. Rev. B 1999, 59, 1758
23. Manz, T.; Sholl, D. J. Chem. Theory Comput. 2010, 6, 2455
24. Charge apportionment methods other than these four were investigated also, but were found to be significantly less reliable.
25. Tang, W.; Sanville, E.; Henkelman, G. J. Phys.: Condens. Matter 2009, 21, 084204
26. Bultinck, P.; Van Alsenoy, C.; Ayers, P.; Carbó-Dorca, R. J. Chem. Phys. 2007, 126, 144111
27. Hirshfeld, F. Theor. Chim. Acta 1977, 44, 129
28. Lillestolen, T.; Wheatley, R. J. Chem. Phys. 2009, 131, 144101
29. There remains debate as to the true charge transfers in graphite intercalation compounds. We adopt those values that have been used most recently in other actuation studies.
30. Preil, M.; Fischer, J.; DiCenzo, S.; Wertheim, G. Phys. Rev. B 1984, 30, 3536
31. Fischer, J.; Kim, H.; Cajipe, V. Phys. Rev. B 1987, 36, 4449
32. Riemenschneider, J.; Opitz, S.; Sinapius, N.; Monner, H. J. Intell. Mater. Syst. Struct. 2009, 20, 245
33. Sato, N. Electrochemistry at Metal and Semiconductor Electrodes; Elsevier: Amsterdam, 1998; p 119.
34. Suppiger, D.; Busato, S.; Ermanni, P. Carbon 2008, 46, 1085