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4 gave (R)- N -benzyl- N -(α-methylbenzyl)amine; subsequent deprotonation with BuLi in THF generated a pink solution of lithium (R)- N -benzyl- N -(α-methylbenzyl) amide 3.
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4 gave (R)- N -benzyl- N -(α-methylbenzyl)amine; subsequent deprotonation with BuLi in THF generated a pink solution of lithium (R)- N -benzyl- N -(α-methylbenzyl) amide 3.
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12
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0028196580
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For selected applications of our aminohydroxylation procedure, see
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79956131251
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Treatment of diol 7 with TFA-promoted lactonization to give 8 as the major product. The absolute configuration within lactone 8 has previously been unambiguously established by conversion to methyl d -3- epi -daunosaminide hydrochloride; see ref 12.
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Treatment of diol 7 with TFA-promoted lactonization to give 8 as the major product. The absolute configuration within lactone 8 has previously been unambiguously established by conversion to methyl d -3- epi -daunosaminide hydrochloride; see ref 12.
-
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27
-
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79956103281
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Crystallographic data (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication number CCDC 814127.
-
Crystallographic data (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication number CCDC 814127.
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Crystallographic data (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication number CCDC 805287.
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Crystallographic data (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication number CCDC 805287.
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30
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79956143718
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Crystallographic data (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication number CCDC 805286.
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Crystallographic data (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication number CCDC 805286.
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31
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4/TMEDA complex in a range of cyclic systems, with generally poor diastereodivergency between the two dihydroxylation protocols being noted, see
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79956083171
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The sample of lactol 14 was contaminated with tetraol 15 alongside other unidentifiable species.
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The sample of lactol 14 was contaminated with tetraol 15 alongside other unidentifiable species.
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37
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0030782344
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