Determination of steroids adulterated in liquid herbal medicines using QuEChERS sample preparation and high-performance liquid chromatography

Journal of Pharmaceutical and Biomedical Analysis

Volumn 55, Issue 5, 2011, Pages 1175-1178

  Klinsunthorn, Nantana ^a,b   Petsom, Amorn ^a   Nhujak, Thumnoon ^a  

^a CHULALONGKORN UNIVERSITY   (Thailand)

^b MINISTRY OF PUBLIC HEALTH   (Thailand)

Author keywords

Dispersive solid phase extraction; Herbal medicines; HPLC; QuEChERS; Steroids

Indexed keywords

BECLOMETASONE; BETAMETHASONE; CORTISONE ACETATE; DEXAMETHASONE; FLUDROCORTISONE ACETATE; HYDROCORTISONE; METHYLPREDNISOLONE; PREDNISOLONE; STEROID; TRIAMCINOLONE;

ACCURACY; ARTICLE; DRUG DETERMINATION; DRUG ISOLATION; HERBAL MEDICINE; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; PRIORITY JOURNAL;

ADSORPTION; CALIBRATION; CHEMISTRY TECHNIQUES, ANALYTICAL; CHEMISTRY, PHARMACEUTICAL; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; DRUG CONTAMINATION; PLANT PREPARATIONS; POWDERS; REPRODUCIBILITY OF RESULTS; SOLID PHASE EXTRACTION; SOLVENTS; STEROIDS; TIME FACTORS;

EID: 79956088561     PISSN: 07317085     EISSN: 1873264X     Source Type: Journal    
DOI: 10.1016/j.jpba.2011.03.046     Document Type: Article

References (20)

1. Lau A.-J., Holmes M.J., Wood S.-O., Koh H.-L. Analysis of adulterants in a traditional herbal medicinal product using liquid chromatography-mass spectrometry-mass spectrometry. J. Pharm. Biomed. Anal. 2003, 31:401-406.
2. Bogusz M.J., Hassan H., Al-Enazi E., Ibrahim Z., Al-Tufail M. Application of LC-ESI-MS-MS for detection of synthetic adulterants in herbal remedies. J. Pharm. Biomed. Anal. 2006, 41:554-564.
3. Thai Drug Control Division, Ministry of Public Health, Thailand, Requirements for Registration of Traditional Drug Formula, 2004, p. 147-149 (in Thai).
4. Sweetman S.C. Martindale: The Complete Drug Reference 2007, Pharmaceutical Press, London. 35th ed.
5. Ku Y.-R., Wen K.-C., Ho L.-K., Chang Y.-S. Solid-phase extraction and high performance liquid chromatographic determination of steroids adulterated in traditional Chinese medicines. J. Food Drug Anal. 1999, 7:123-130.
6. Gonzalo-Lumbrears R., Muñuz-Valencia R., Santos-Montes A., Izquierdo-Hornillos R. Liquid chromatographic method development for steroids determination (corticoids and anabolics) application to animal feed samples. J. Chromatogr. A 2007, 1156:321-330.
7. Gagliardi L., Orsi D.D., Rosaria M., Giudice D., Gatta F., Porra R., Chimenti P., Tonelli D. Development of a tandem thin-layer chromatography-high-performance liquid chromatography method for the identification and determination of corticosteroids in cosmetic products. Anal. Chim. Acta 2002, 457:187-198.
8. Andersen J.H., Hansen L.G., Pedersen M. Optimization of solid phase extraction clean up and validation of quantitative determination of corticosteroids in urine by liquid chromatography-tandem mass spectrometry. Anal. Chim. Acta 2008, 617:216-224.
9. Saito K., Yagi K., Ishizaki A., Kataoka H. Determination of anabolic steroids in human urine by automated in-tube solid-phase microextraction coupled with liquid chromatography-mass spectrometry. J. Pharm. Biomed. Anal. 2010, 53:727-733.
10. Anastassiades M., Lehotay S.J., Stajnbaher D. Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) approach for the determination of pesticide residues. WTQA 2002 Proc. 2003, 231-241.
11. Lehotay S.J, de Kok A., Hiemstra M., van Bodegraven P. Validation of a fast and easy method for the determination of residues from 229 pesticides in fruits and vegetables using gas and liquid chromatography and mass spectrometric detection. J. AOAC Int. 2005, 88:595-614.
12. Banerjee K., Oulkar D.P., Dasgupta S., Patil S.B., Patil S.H., Savant R., Adsule P.G. Validation and uncertainty analysis of a multi-residue method for pesticides in grapes using ethyl acetate extraction and liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 2007, 1173:98-109.
13. Gilbert-López B., García-Reyes J.F., Lozano A., Fernández-Alba A.R., Molina-Díaz A. Large-scale pesticide testing in olives by liquid chromatography-electrospray tandem mass spectrometry using two sample preparation methods based on matrix solid-phase dispersion and QuEChERS. J. Chromatogr. A 2010, 1217:6022-6035.
14. Cieślik E., Sadowska-Rociek A., Ruiz J.M.M., Surma-Zadora M. Evaluation of QuEChERS method for the determination of organochlorine pesticide residues in selected groups of fruits. Food Chem. 2011, 125:773-778.
15. Frenich A.G., Martinez Vidal J.L., Pastor-Montoro E., Romero-Gonzalez R. High-throughput determination of pesticide residues in food commodities by use of ultra-performance liquid chromatography-tandem mass spectrometry. Anal. Bioanal. Chem. 2008, 390:947-959.
16. Chung S.W.C., Chan B.T.P. Validation and use of a fast sample preparation method and liquid chromatography-tandem mass spectrometry in analysis of ultra-trace levels of 98 organophosphorus pesticide and carbamate residues in a total diet study involving diversified food types. J. Chromatogr. A 2010, 1217:4815-4824.
17. Wilkowska A., Biziuk M. Determination of pesticide residues in food matrices using the QuEChERS methodology. Food Chem. 2011, 125:803-812.
18. Horwitz W., Albert R. The Horwitz ratio (HorRat): a useful index of method performance with respect to precision. J. AOAC Int. 2006, 89:1095-1109.
19. Taverniers I., de Loose M., van Bockstaele E. Trends in quality in the analytical laboratory: II analytical method validation and quality assurance. Trends Anal. Chem. 2004, 23:535-552.
20. Peeler J.T., Horwitz W., Albert R. Precision parameters of standard methods of analysis of dairy products. J. AOAC Int. 1989, 72:784-806.