Electrochemical monitoring of the fluorescence emission of tetrazine and bodipy dyes using total internal reflection fluorescence microscopy coupled to electrochemistry

ACS Applied Materials and Interfaces

Volumn 3, Issue 3, 2011, Pages 690-696

  Miomandre, F ^a   Lepicier E ^a   Munteanu, S ^a   Galangau, O ^a   Audibert, J F ^a   Meallet Renault R ^a   Audebert, P ^a   Pansu, R B ^a  

^a Ecole Normale Superieure de Cachan   (France)

Author keywords

bora diaza indacene (Bodipy); electrochemistry; fluorescence; tetrazine; TIRF microscopy

Indexed keywords

BORA-DIAZA-INDACENE (BODIPY); DIFFUSION LAYERS; ELECTROCHEMICAL MONITORING; ELECTRODE POTENTIALS; EMISSION INTENSITY; EMISSIVE STATE; FLUORESCENCE EMISSION; FLUORESCENCE PROPERTIES; FLUORESCENCE SIGNALS; ORGANIC DYE; REDOX CONVERSION; SENSITIVE TECHNIQUES; SWITCH-ON; TETRAZINES; TIME RESOLUTION; TIRF MICROSCOPY; TOTAL INTERNAL REFLECTION FLUORESCENCE MICROSCOPY;

CHRONOAMPEROMETRY; CYCLIC VOLTAMMETRY; ELECTROCHEMICAL PROPERTIES; ELECTROLYSIS; ELECTROLYTIC ANALYSIS; ELECTROLYTIC CELLS; FLUORESCENCE MICROSCOPY; REFRACTIVE INDEX;

FLUORESCENCE;

FLUORESCENT DYE;

ARTICLE; CHEMISTRY; ELECTROCHEMISTRY; EQUIPMENT; EQUIPMENT DESIGN; FLUORESCENCE MICROSCOPY; INSTRUMENTATION;

ELECTROCHEMISTRY; EQUIPMENT DESIGN; EQUIPMENT FAILURE ANALYSIS; FLUORESCENT DYES; MICROSCOPY, FLUORESCENCE;

EID: 79955945219     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/am100980u     Document Type: Article

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27. This is reasonable since the fluorescence is measured in a fixed volume close to the electrode surface, theoretically equal to the electrode area x the penetration depth (A 1×d). Thus the electrogenerated species concentration in this volume should be proportional to the injected charge.