One-pot synthesis of Ni(II) and Fe(III) complexes: In situ formation of 2-pyridinemethanol from 2-pyridinecarboxaldehyde

Inorganic Chemistry Communications

Volumn 14, Issue 6, 2011, Pages 877-881

  Sun, Ji Ping ^a   Li, Li Cun ^b   Zheng, Xiang Jun ^a  

^a BEIJING NORMAL UNIVERSITY   (China)

^b NANKAI UNIVERSITY   (China)

Author keywords

Crystal structure; In situ ligand synthesis; Magnetism; Supramolecule

Indexed keywords

EID: 79955789027     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.03.016     Document Type: Article

References (28)

1. Z.G. Han, Y.Z. Gao, X.L. Zhai, H.H. Song, A copper-organic complex from hydrothermal reaction involving in situ aromatic nucleophilic substitution of ligand, Inorg. Chem. Commun. 10 (2007) 1079-1082.
2. (a) W.B. Lin, O.R. Evans, R.G. Xiong, Z.Y. Wang, Supramolecular engineering of chiral and acentric 2D networks. Synthesis, structures, and second-order nonlinear optical properties of bis(nicotinato)zinc and bis{3-[2-(4-pyridyl)ethenyl]benzoato}cadmium, J. Am. Chem. Soc. 120 (1998) 13272-13273;
3. (b) W.B. Lin, Z.Y. Wang, L. Ma, A novel octupolar metal-organic NLO material based on a chiral 2D coordination network, J. Am. Chem. Soc. 121 (1999) 11249-11250.
4. L. Han, X.H. Bu, Q.C. Zhang, P.Y. Feng, Solvothermal in situ ligand synthesis through disulfide cleavage: 3D (3,4)-connected and 2D square-grid-type coordination polymers, Inorg. Chem. 45 (2006) 5736-5738.
5. (a) F. Luo, J.M. Zheng, M. Kurmoo, One-pot synthesis of Schiff-base-containing Ni-8 clusters: solvothermal synthesis, structure, and magnetic properties, Inorg. Chem. 46 (2007) 8448-8450;
6. (b) F. Luo, M.B. Luo, Solvothermal in situ synthesis of (Schiff-base)-containing dinuclear cobalt compound, Inorg. Chem. Commun. 13 (2010) 319-321.
7. (a) R.G. Xiong, X. Xue, H. Zhao, X.Z. You, B.F. Abrahams, Z.L. Xue, Novel, acentric metal-organic coordination polymers from hydrothermal reactions involving in situ ligand synthesis, Angew. Chem. Int. Ed. 41 (2002) 3800-3803;
8. (b) Z. Li, M. Li, X.P. Zhou, T. Wu, D. Li, S.W. Ng, Metal-directed supramolecular architectures: from mononuclear to 3D frameworks based on in situ tetrazole ligand synthesis, Cryst. Growth Des. 7 (2007) 1992-1998.
9. (a) C.M. Liu, S. Gao, H.Z. Kou, Dehydrogenative coupling of phenanthroline under hydrothermal conditions: crystal structure of a novel layered vanadate complex constructed of 4,8,10-net sheets: [(2,2′-biphen) Co]V3O8.5, Chem. Commun. 17 (2001) 1670-1671;
10. (b) O.R. Evans, W.B. Lin, Synthesis of zinc oxalate coordination polymers via unprecedented oxidative coupling of methanol to oxalic acid, Cryst. Growth Des. 1 (2001) 9-11.
11. 4(mtp)] (Hophen=2-hydroxy-1,10′- phenanthroline, mtp=2-methyl-terephthalate acid), J. Mol. Struct. 734 (2005) 171-176.
12. (a) J.Y. Lu, A.M. Babb, A simultaneous reduction, substitution, and self-assembly reaction under hydrothermal conditions afforded the first diiodopyridine copper(I) coordination polymer, Inorg. Chem. 41 (2002) 1339-1341;
13. 4+ cubic clusters into three-dimensional photoluminescent souper-lattice, J. Am. Chem. Soc. 124 (2002) 9688-9689;
14. 2OS donor set: coordination chemistry with nickel(II) ions and aerial oxidation to the sulfinate complex, Chem. Eur. J. 6 (2000) 2193-2199.
15. -1): 3415s, 3326s, 2363m, 1605s, 1568w, 1479w, 1435m, 1283m, 1069s, 1048s, 792m.
16. -1): 3430s, 1634s, 1604w, 1475m, 1438m, 1287m, 1065vs, 1047vs, 766s, 685m, 548m, 419m.
17. 2, FW=469.74, Monoclinic, space group C2/m with a=16.0017(17) Å, b=7.4896(8) Å, c=7.6478(8) Å, α=β=90.00° γ=108.651 (2)° V=868.43(16) Å3, Z=2, F(000)=468, GOF=1.055, R1=0.0334 [I>2σ(I)], wR2=0.0783 [all data 1058], 5.62° ≤2θ≤55.12° and largest diff. peak and hole of 0.363 and -0.316 e.A-3, respectively.
18. (a) J. Lawrence, E.C. Yang, R. Edwards, M.M. Olmstead, C. Ramsey, N.S. Dalal, P.K. Gantzel, S. Hill, D.N. Hendrickson, Disorder and intermolecular interactions in a family of tetranuclear Ni(II) complexes probed by high-frequency electron paramagnetic resonance, Inorg. Chem. 47 (2008) 1965-1974;
19. (b) S.G. Telfer, N.D. Parker, R. Kuroda, T. Harada, J. Lefebvre, D.B. Leznoff, Helicates, boxes, and polymers from simple pyridine-alcohol ligands: the impact of the identity of the transition metal ion, Inorg. Chem. 47 (2008) 209-218;
20. (c) M.L. Tong, S.L. Zheng, J.X. Shi, Y.X. Tong, H.K. Lee, X.M. Chen, Synthesis, crystal structures and properties of six cubane-like transition metal complexes of di-2-pyridyl ketone in gem-diol form, Dalton Trans. (2002) 1727-1734;
21. (d) E.C. Yang, W. Wernsdorfer, L.N. Zakharov, Y. Karaki, A. Yamaguchi, R.M. Isidro, G.D. Lu, S.A. Wilson, A.L. Rheingold, H. Ishimoto, D.N. Hendrickson, Fast magnetization tunneling in tetranickel(II) single-molecule magnets, Inorg. Chem. 45 (2006) 529-546;
22. 4+ cubane complexes, Inorg. Chem. 34 (1995) 4167-4177;
23. 2)], Inorg. Chem. 39 (2000) 5515-5519;
24. II complexes of a pentadentate phenol-containing Schiff base with (O, N, O, N, O)-donor atoms, Eur. J. Inorg. Chem. (2003) 863-875;
25. ∩O (X=S, Se or N) donor atoms, Eur. J. Inorg. Chem. (2003) 3167-3178;
26. 4}. Crystal structures and magnetic properties, Polyhedron 18 (1999) 909-914.
27. C.A. Christmas, H.L. Tsai, L. Pardi, J.M. Kesselman, P.K. Gantzel, R.K. Chadha, D. Gatteschi, D.F. Harvey, D.N. Hendrickson, Hexanuclear ferric complexes possessing different degrees of spin frustration, J. Am. Chem. Soc. 115 (1993) 12483-12490. (Pubitemid 24078349)
28. S.M. Gorun, S.J. Lippard, Magnetostructural correlations in magnetically coupled (μ-oxo)diiron(III) complexes, Inorg. Chem. 30 (1991) 1625-1630.