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Due to the moderate enantiomeric purity of 7i, the camphanic ester derivative was obtained as a mixture of the 1S, 4R, 1'S, 6'S, 9'Ss-10b major and 1S, 4R, 1'R, 6'R, 9'R-10b' minor diastereoisomers, which were separated via preparative HPLC. Only the minor diastereoisomer 10b' crystallized, and its X-ray structure was determined Scheme 5
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Due to the moderate enantiomeric purity of 7i, the camphanic ester derivative was obtained as a mixture of the (1S, 4R, 1'S, 6'S, 9'S)-10b (major) and (1S, 4R, 1'R, 6'R, 9'R)-10b' (minor) diastereoisomers, which were separated via preparative HPLC. Only the minor diastereoisomer 10b' crystallized, and its X-ray structure was determined (Scheme 5).
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