Synthesis of oleic acid based esters as potential basestock for biolubricant production

Turkish Journal of Engineering and Environmental Sciences

Volumn 35, Issue 2, 2011, Pages 115-123

  Salih, Nadia ^a   Salimon, Jumat ^a   Yousif, Emad ^b  

^a UNIVERSITI KEBANGSAAN MALAYSIA   (Malaysia)

^b AL NAHRAIN UNIVERSITY   (Iraq)

Author keywords

Biolubricants; Oleic acid based esters; Pour point

Indexed keywords

BASE STOCK; BIOBASED; BIOLUBRICANTS; ESTER DERIVATIVES; FLASH POINTS; FTIR; INDUSTRIAL MATERIALS; OXIRANE RING; POUR POINT; POUR POINTS; TRIESTERS;

ESTERIFICATION; OLEIC ACID; SURFACE ACTIVE AGENTS; UNSATURATED FATTY ACIDS;

ESTERS;

ESTER; LOW TEMPERATURE; LUBRICANT; TEMPERATURE EFFECT; VISCOSITY;

EID: 79955566184     PISSN: 13000160     EISSN: 13036157     Source Type: Journal    
DOI: 10.3906/muh-1005-42     Document Type: Article

References (22)

1. Altin, R., Çetinkaya, S. and Yücesu, H.S., "The Potential of Using Plant Oil Fuels as Fuel for Diesel Engines", Energy Conversion and Management, 42, 529-538, 2001.
2. Aramaki, K. and Khalid H.M., "Effect of Addition and Molecular Size of Triglyceride Oils on Phase Behavior and Surfactant Self-Assemblies", Journal of Oleo Science, 53, 557-563, 2004.
3. ASTM Standard D5949: Standard Test Method for Pour Point of Petroleum (Automatic Pressure Pulsing Method). ASTM, West Conshohocken, PA (USA).
4. ASTM Standard D 56-79: Standard Test Method for Flash Point of Liquids with a Viscosity Less Than, 45 Saybolt Universal Seconds (SUS) at 37.8 °C (That Don't Contain Suspended Solids and Don't Tend to Form a Surface Film Under Test).
5. Adhvaryu, A., Erhan, S.Z., Liu, Z.S. and Perez, J.M., "Oxidation Kinetic Studies of Oils Derived from Unmodified and Genetically Modified Vegetables Using Pressurized Differential Scanning Calorimetry and Nuclear Magnetic Resonance Spectroscopy", Thermochimica Acta, 364, 87-97, 2000.
6. Adhvaryu, A. and Erhan, S.Z., "Epoxidized Soybean Oil as a Potential Source of High-Temperature Lubricants", Industrial Crops and Products, 15, 247-254, 2002.
7. Adhvaryu, A., Erhan, S.Z. and Perez, J.M., "Tribological Studies of Thermally and Chemically Modified Vegetable Oils for Use as Environmentally Friendly Lubricants", Wear, 257, 359-367, 2004.
8. Adhvaryu, A., Liu, Z. and Erhan, S.Z., "Synthesis of Novel Alkoxylated Triacylglycerols and Their Lubricant Base Oil Properties", Industrial Crops and Products, 21, 113-119, 2005.
9. Chi, L., "The Production of Methyl Esters from Vegetable Oil/ Fatty Acid Mixtures", M.Sc Thesis, Graduate Department of Chemical Engineering and Applied Chemistry, University of Toronto, Canada, 1999.
10. Campanella, A. and Baltanás, M.A., "Degradation of the Oxirane Ring of Epoxidized Plant Oils in a Liquid-Liquid-Solid Heterogeneous Reaction System", Chemical Engineering and Processing, 46, 210-22, 2007.
11. Campanella, A., Rustoy, E., Baldessari, A. and Baltanás, M.A., "Lubricants from Chemically Modified Plant Oils", Bioresource Technology, 101, 245-254, 2010.
12. Carlsson A.S., "Plant Oils as Feedstock Alternatives to Petroleum - A Short Survey of Potential Oil Crop Platforms", Biochimie, 91, 665-670, 2009.
13. Caro, P.S., Mouloungui, Z. and Gaset A., "Synthesis of Derivatives of Alkylamino Alkyloxy Propanol Structures by N-Alkylation, Acylation, and Nitration: Application as Fuel Additives", Journal of the American Chemical Society, 74, 241-247, 1997.
14. Crocco, G.L., Shum, W.F., Zajacek, J.G., Kesling, H.S. and Haven, S., "Epoxidation Process", U.S. Patent 5,166,372, 1992.
15. Findley, T.W., Swern, D. and Scanlan, J.T., "Epoxidation of Unsaturated Fatty Materials with Peracetic Acid in Glacial Acetic Acid Solution", Journal of the American Chemical Society, 67, 412-414, 1945.
16. Knothe, G., and Carlson, K.D., "Synthesis, Mass Spectrometry and Nuclear Magnetic Resonance Characterization of Di-Guerbet Esters", Journal of the American Chemical Society, 75, 1861-1866, 1998.
17. Knothe, G., Dunn, R.O., Shockley, M.W. and Bagby, M.O., "Synthesis and Characterization of Some Long-Chain Diesters with Branched or Bulky Moieties", Journal of the American Chemical Society, 77, 865-871, 2000.
18. Knothe, G., "Characterization of Esters of Fatty Acids and Dicarboxylic Acids with Guerbet Alcohols", Journal of the American Chemical Society, 78, 537-540, 2001.
19. Salimon, J. and Salih, N., "Improved Low Temperature Properties of 2-Ethylhexyl-9(10)-Hydroxy-10(9)-Acyloxystearate derivatives", European Journal of Scientific Research, 31, 583-591, 2009.
20. Scala, J.L. and Wool, R.P., "Effect of FA Composition on Epoxidation Kinetics of TAG", Journal of the American Chemical Society, 79,373-378, 2002.
21. Schmits, W.R. and Wallace, J.G., "Epoxidation of Methyl Oleate with Hydrogen Peroxide", Journal of the American Chemical Society, 31, 363-365, 1954.
22. Sliverstien, R.M., Bassler, G. and Morrill, T., Spectrometric Identification of Organic Compounds, 7th edn. John Wiley & Sons, New York, NY (USA), 2005.