Kinetic modeling studies of heterogeneously catalyzed biodiesel synthesis reactions

Industrial and Engineering Chemistry Research

Volumn 50, Issue 9, 2011, Pages 4818-4830

  Kapil, Ankur ^a   Wilson, Karen ^b   Lee, Adam F ^b   Sadhukhan, Jhuma ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b CARDIFF UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

BIODIESEL SYNTHESIS; BULK CONCENTRATION; CATALYST SURFACES; ELEMENTARY REACTION; EXPERIMENTAL DATA; HYDROTALCITE CATALYSTS; KINETIC MODELING; LANGMUIR-HINSHELWOOD-HOUGEN-WATSON; METHANOL ADSORPTION; MULTI-SCALE SIMULATION; QUASI STEADY STATE CONDITIONS; RATE DETERMINING STEP; RATE EXPRESSION; RATE LIMITING; REACTION MECHANISM; SURFACE SPECIES; TRANSESTERIFICATION REACTION;

ADSORPTION; BIODIESEL; CATALYSIS; CATALYSTS; METHANOL; RATE CONSTANTS; SYNTHESIS (CHEMICAL); SYNTHETIC FUELS;

SURFACE REACTIONS;

EID: 79955530388     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie101403f     Document Type: Article

References (29)

1. Narasimharao, K.; Lee, A.; Wilson, K. Catalysts in production of biodiesel: A review J. Biobased Mater. Bioenergy 2007, 1 (1) 19-30
2. Dossin, T. F.; Reyniers, M. F.; Berger, R. J.; Marin, G. B. Simulation of heterogeneously MgO-catalyzed transesterification for fine-chemical and biodiesel industrial production Appl. Catal., B 2006, 67 (1-2) 136-148 (Pubitemid 44247576)
3. Crocker, M. In Development of Heterogeneous Catalysts for Bio-diesel Production, Tri-State Catalysis Society Symposium, Lexington, KY, 2006; Lexington, KY, 2006.
4. Ngaosuwan, K.; Lotero, E.; Suwannakarn, K.; Goodwin, J. G. J.; Praserthdam, P. Hydrolysis of triglycerides using solid acid catalysts Ind. Eng. Chem. Res. 2009, 48, 4757-4767
5. 3 solid catalyst Fuel 2009, 88 (4) 625-628
6. 3-Supported alkali and alkali earth metal oxides for transesterification of palm kernel oil and coconut oil Chem. Eng. J. 2009, 145 (3) 468-474
7. de Caland, L. B.; Santos, L. S. S.; de Moura, C. V. R.; de Moura, E. M. Preparation and study of bimetallic compounds efficiency in the synthesis of biodiesel fuel Catal. Lett. 2009, 128 (3-4) 392-400
8. Singh, A. K.; Fernando, S. D. Transesterification of soybean oil using heterogeneous catalysts Energy Fuels 2008, 22 (3) 2067-2069
9. Verziu, M.; Cojocaru, B.; Hu, J. C.; Richards, R.; Ciuculescu, C.; Filip, P.; Parvulescu, V. I. Sunflower and rapeseed oil transesterification to biodiesel over different nanocrystalline MgO catalysts Green Chem. 2008, 10 (4) 373-381 (Pubitemid 351466541)
10. Brito, A.; Borges, M. E.; Otero, N. Zeolite Y as a heterogeneous catalyst in biodiesel fuel production from used vegetable oil Energy Fuels 2007, 21 (6) 3280-3283 (Pubitemid 350267846)
11. Dalai, A. K.; Kulkarni, M. G.; Meher, L. C. Biodiesel productions from vegetable oils using heterogeneous catalysts and their applications as lubricity additives IEEE EIC Clim. Change Conf. 2006, 1/2, 517-524
12. Di Serio, M.; Cozzolino, M.; Giordano, M.; Tesser, R.; Patrono, P.; Santacesaria, E. From homogeneous to heterogeneous catalysts in biodiesel production Ind. Eng. Chem. Res. 2007, 46 (20) 6379-6384 (Pubitemid 47598370)
13. Di Serio, M.; Ledda, M.; Cozzolino, M.; Minutillo, G.; Tesser, R.; Santacesaria, E. Transesterification of soybean oil to biodiesel by using heterogeneous basic catalysts Ind. Eng. Chem. Res. 2006, 45 (9) 3009-3014
14. Cantrell, D. G.; Gillie, L. J.; Lee, A. F.; Wilson, K. Structure-reactivity correlations in MgAl hydrotalcite catalysts for biodiesel synthesis Appl. Catal., A 2005, 287 (2) 183-190
15. Macedo, C. C. S.; Abreu, F. R.; Tavares, A. P.; Alves, M. B.; Zara, L. F.; Rubim, J. C.; Suarez, P. A. Z. New heterogeneous metal-oxides based catalyst for vegetable oil trans-esterification J. Braz. Chem. Soc. 2006, 17 (7) 1291-1296 (Pubitemid 44892847)
16. Dossin, T. F.; Reyniers, M. F.; Marin, G. B. Kinetics of heterogeneously MgO-catalyzed transesterification Appl. Catal., B 2006, 62 (1-2) 35-45 (Pubitemid 41814612)
17. Raimondeau, S.; Vlachos, D. G. Recent developments on multiscale, hierarchical modeling of chemical reactors Chem. Eng. J. 2002, 90, 3
18. Karpov, E. G.; Chaichenets, S.; Liu, W. K.; Qian, D., Mechano-kinetic coupling approach for materials with dynamic internal structure. Philos. Mag. Lett. 90, (7), 471-480.
19. Levchenko, I.; Ostrikov, K.; Khachan, J.; Vladimirov, S. V. Growth of carbon nanocone arrays on a metal catalyst: The effect of carbon flux ionization Phys. Plasmas 2008, 15, 10
20. Majumder, D.; Broadbelt, L. J. A multiscale scheme for modeling catalytic flow reactors AIChE J. 2006, 52 (12) 4214-4228 (Pubitemid 44935213)
21. Vlachos, D. G.; Mhadeshwar, A. B.; Kaisare, N. S. Hierarchical multiscale model-based design of experiments, catalysts, and reactors for fuel processing Comput. Chem. Eng. 2006, 30 (10-12) 1712-1724 (Pubitemid 44292260)
22. Raimondeau, S.; Vlachos, D. G. The role of adsorbate-layer nonuniformities in catalytic reactor design: Multiscale simulations for CO oxidation on Pt Comput. Chem. Eng. 2002, 26 (7-8) 965-980 (Pubitemid 36076774)
23. Reese, J. S.; Raimondeau, S.; Vlachos, D. G. Monte Carlo algorithms for complex surface reaction mechanisms: Efficiency and accuracy J. Comput. Phys. 2001, 173 (1) 302-321 (Pubitemid 33098518)
24. Kapil, A.; Bhat, S. A.; Sadhukhan, J. Multiscale characterization framework for sorption enhanced reaction processes AIChE J. 2008, 54 (4) 1025-1036 (Pubitemid 351529950)
25. Bhat, S. A.; Sharma, R.; Gupta, S. K. Simulation and optimization of the continuous tower process for styrene polymerization J. Appl. Polym. Sci. 2004, 94 (2) 775-788 (Pubitemid 39253086)
26. Xu, M.; Bhat, S.; Smith, R.; Stephens, G.; Sadhukhan, J. Multi-objective optimization of metabolic productivity and thermodynamic performance Comput. Chem. Eng. 2009, 33 (9) 1438-1450
27. Reid, R. C.; Praustnitz, J. M.; Poling, B. E., The Properties of Gases and Liquids, 4 th ed.; MacGraw-Hill: New York, 1987.
28. Haupt, R.; Haupt, S. E. Practical Genetic Algorithms, 2 nd ed.; John Wiley & Sons Inc: New York, 2004; p 253.
29. Kreyszig, E. Advanced Engineering Mathematics, 8 th ed.; John Wiley & Sons, Inc.: New York, 1999.