Mechanistic studies on the water-oxidizing reaction of homogeneous manganese-based catalysts: Isolation and characterization of a suggested catalytic intermediate

Inorganic Chemistry

Volumn 50, Issue 8, 2011, Pages 3425-3430

  Berggren, Gustav ^a,c   Thapper, Anders ^a   Huang, Ping ^a   Eriksson, Lars ^b   Styring, Stenbjörn ^a   Anderlund, Magnus F ^a  

^a UPPSALA UNIVERSITY   (Sweden)

^b STOCKHOLM UNIVERSITY   (Sweden)

^c UNIV GRENOBLE ALPES   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 79955429629     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic102336a     Document Type: Article

References (37)

1. Brudvig, G. W. Coord. Chem. Rev. 2008, 252, 231.
2. Eisenberg, R.; Gray, H. B. Inorg. Chem. 2008, 47, 1697.
3. Dau, H.; Haumann, M. Coord. Chem. Rev. 2008, 252, 273.
4. Cady, C. W.; Crabtree, R. H.; Brudvig, G. W. Coord. Chem. Rev. 2008, 252, 444.
5. Mukhopadhyay, S.; Mandal, S. K.; Bhaduri, S.; Armstrong, W. H. Chem. Rev. 2004, 104, 3981.
6. Poulsen, A. K.; Rompel, A.; McKenzie, C. J. Angew. Chem., Int. Ed. 2005, 44, 6916.
7. Berggren, G.; Thapper, A.; Huang, P.; Kurz, P.; Eriksson, L.; Styring, S.; Anderlund, M. F. Dalton Trans. 2009, 45, 10044.
8. Beckmann, K.; Uchtenhagen, H.; Berggren, G.; Anderlund, M. F.; Thapper, A.; Messinger, J.; Styring, S.; Kurz, P. Energy Environ. Sci. 2008, 1, 668.
9. Styring, S.; Beckmann, K.; Berggren, G.; Uchtenhagen, H.; Anderlund, M. F.; Thapper, A.; Messinger, J.; Kurz, P. In Photosynthesis. Energy from the sun: 14th International Congress on Photosynthesis; Allen, J. F., Gantt, E., Golbeck, J. H., Osmond, B., Eds.; Springer: Dordrecht, The Netherlands, 2008; p 1281.
10. Kurz, P.; Berggren, G.; Anderlund, M. F.; Styring, S. Dalton Trans. 2007, 4258.
11. The structure 20 has been proposed by Poulsen et al.6 although no evidence for the coordination mode of the ligand has been provided.
12. Baffert, C.; Collomb, M. N.; Deronzier, A.; Kjaergaard-Knudsen, S.; Latour, J. M.; Lund, K. H.;McKenzie, C. J.;Mortensen,M.; Nielsen, L.; Thorup, N. Dalton Trans. 2003, 1765.
13. Sheldrick, G. M. Acta Crystallogr., Sect. A 2008, 112.
14. Brennan, S., http://www.ccp14.ac.uk/ccp/ccp14/ftp.
15. Kissel, L.; Pratt, R. H. Acta Crystallogr., Sect. A 1990, 170.
16. Liu, W.; Thorp, H. H. Inorg. Chem. 1993, 32, 4102.
17. Brown, I. D.; Altermatt, D. Acta Crystallogr. 1985, B41, 244.
18. Groni, S.; Hureau, C.; Guillot, R.; Blondin, G.; Blain, G.; Anxolabéhère-Mallart, E. Inorg. Chem. 2008, 47, 11783.
19. Hureau, C.; Sabater, L.; Anxolabéhère-Mallart , E.; Nierlich, M.; Charlot, M. F.; Gonnet, F.; Rivière, E.; Blondin, G. Chem.-Eur. J. 2004, 10, 1998.
20. A Mn2 IV,IV dimer is expected to be EPR inactive.
21. Baldwin, M. J.; Pecoraro, V. L. J. Am. Chem. Soc. 1996, 118, 11325.
22. Hureau, C.; Blondin, G.; Charlot, M. F.; Philouze, C.; Nierlich, M.; Césario, M.; Anxolabéhère-Mallart , E. Inorg. Chem. 2005, 44, 3669.
23. In the proposed mechanism, the complex is oxidized with TBHP or cerium(IV) to reach the Mn2 IV,IV state, but once this species is formed, the choice of oxidant should not be important.
24. Larsen, A. S.;Wang, K.; Lockwood,M. A.; Rice, G. L.;Won, T.-J.; Lovell, S.; Sadílek, M.; Turecek, F.; Mayer, J. M. J. Am. Chem. Soc. 2002, 124, 10112.
25. Dubois, L.; Pécaut, J.; Charlot,M.-F.; Baffert, C.; Collomb,M.-N.; Deronzier, A.; Latour, J.-M. Chem.-Eur. J. 2008, 14, 3013.
26. Caudle, M. T.; Riggs-Gelasco, P.; Gelasco, A. K.; Penner-Hahn, J. E.; Pecoraro, V. L. Inorg. Chem. 1996, 35, 3577.
27. Hiatt, R. R.; Irwin, K. C.; Gould, C. W. J. Org. Chem. 1968, 33, 1430.
28. Hiatt, R. R.; Mill, T.; Mayo, F. R. J. Org. Chem. 1968, 33, 1416.
29. Chandra, S. K.; Chakravorty, A. Inorg. Chem. 1992, 31, 760.
30. Kessissoglou, D. P.; Li, X.; Butler, W. M.; Pecoraro, V. L. Inorg. Chem. 1987, 26, 2487.
31. Chandra, S. K.; Basu, P.; Ray, D.; Pal, S.; Chakravorty, A. Inorg. Chem. 1990, 29, 2423.
32. Smegal, J. A.; Hill, C. L. J. Am. Chem. Soc. 1983, 105, 3515.
33. Limburg, J.; Vrettos, J. S.; Liable-Sands, L. M.; Rheingold, A. L.; Crabtree, R. H.; Brudvig, G. W. Science 1999, 283, 1524.
34. Gao, Y.; Åkermark, T.; Liu, J.; Sun, L.; Åkermark, B. J. Am. Chem. Soc. 2009, 131, 8726.
35. McEvoy, J. P.; Gascon, J. A.; Batista, V. S.; Brudvig, G. W. Photochem. Photobiol. Sci. 2005, 4, 940.
36. Pecoraro, V. L.; Baldwin, M. J.; Caudle, M. T.; Hsieh, W. Y.; Law, N. A. Pure Appl. Chem. 1998, 70, 925.
37. Tagore, R.; Chen, H.; Zhang, H.; Crabtree, R. H.; Brudvig, G. W. Inorg. Chim. Acta 2007, 360, 2983.