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We can not exclude that the geff, 2 signal are part of the EPR spectra of complexes 1 and 3
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eff = 2 signal are part of the EPR spectra of complexes 1 and 3.
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We have assumed that the Mn-Cl bond length is not significantly shortened in solution compared to the X-ray data
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We have assumed that the Mn-Cl bond length is not significantly shortened in solution compared to the X-ray data.
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17744369501
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60849111645
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Difference in the temperature do not significantly change the pattern of the EPR spectra, in the Supporting Information
-
Difference in the temperature do not significantly change the pattern of the EPR spectra. Compare, for instance, the spectrum in Figure 3a with that in Figure S1a in the Supporting Information.
-
Compare, for instance, the spectrum in Figure 3a with that in Figure
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0. In the present case, we consider the Born model theory to evaluate the variation of solvatation energy upon Mn(II)/Mn(III) redox process.
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