메뉴 건너뛰기




Volumn 44, Issue 42, 2005, Pages 6916-6920

Water oxidation catalyzed by a dinuclear Mn complex: A functional model for the oxygen-evolving center of photosystem II

Author keywords

Bioinorganic chemistry; Manganese; N,O ligands; Oxidation; Photosynthesis

Indexed keywords

COMPLEXATION; MASS SPECTROMETRY; OXIDATION; WATER;

EID: 27544457271     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200502114     Document Type: Article
Times cited : (196)

References (27)
  • 6
    • 27544515764 scopus 로고    scopus 로고
    • note
    • 18O-labelling experiments in references [20, 23, 24]. Unfortunately, insufficient detail was provided (in supplementary information) to describe the experimental protocols. Thus, we assume that the gas in the head space over the reactions was analyzed. This method is fundamentally different to MIMS and is not quantitative.
  • 7
    • 27544495371 scopus 로고    scopus 로고
    • note
    • 2 into the system does not invoke this response, rather the surge is recorded, and this immediately decays exponentially.
  • 8
    • 27544471202 scopus 로고    scopus 로고
    • note
    • We are currently designing a new cell so that a continuous supply of TBHP can be added in order to attain a steady state of catalytic activity. Visual inspection of the reactions indicates that the concentrations used in the MIMS experiments are not optimal and the system potentially produces much greater amounts of product.
  • 9
    • 27544498678 scopus 로고    scopus 로고
    • note
    • IV oxidant.
  • 10
    • 27544484317 scopus 로고    scopus 로고
    • note
    • [2] [11] bispicen = N,N′-bis(2-methylpyridyl)ethane-1,2-diamine.
  • 16
    • 0037007237 scopus 로고    scopus 로고
    • Erratum: L. Que, W. B. Tolman, Angew. Chem. 2002, 114, 1900
    • Angew. Chem. Int. Ed. 2002, 41, 1114-1137 Erratum: L. Que, W. B. Tolman, Angew. Chem. 2002, 114, 1900;
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 1114-1137
  • 18
    • 27544439979 scopus 로고    scopus 로고
    • note
    • The reaction is not a catalase-like reaction. If this were the case, both O atoms would be derived from the oxidant.
  • 22
    • 27544470777 scopus 로고    scopus 로고
    • note
    • IV in oxidation reactions. However, participation by the nitrate ion is not normally considered.
  • 23
    • 27544482042 scopus 로고    scopus 로고
    • note
    • - isotopomer by negative-ion ESIMS. Unfortunately, in the presence of such large excess of the unlabeled nitrate, this experiment was beyond the resolution capabilities of our instrument.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.