Effect of sulfur poisoning in high pressure catalytic partial oxidation of methane over Rh-Ce/Al2O3 catalyst

Industrial and Engineering Chemistry Research

Volumn 50, Issue 8, 2011, Pages 4373-4380

  Hong, Jin Ki ^a   Zhang, Lingzhi ^a   Thompson, Mark ^a   Wei, Wei ^a   Liu, Ke ^a  

^a GE GLOBAL RESEARCH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINA FOAMS; CATALYTIC PARTIAL OXIDATION OF METHANE; CATALYTIC PERFORMANCE; CATALYTIC SYSTEM; ENGINEERING CHALLENGES; FEED COMPOSITIONS; HIGH PRESSURE; INJECTION CONDITIONS; OPERATING CONDITION; REACTION MODEL; SHORT CONTACT TIME-CATALYTIC PARTIAL OXIDATION; SULFUR EFFECT; SULFUR LEVELS; SULFUR POISONING; WASHCOATS;

CATALYST ACTIVITY; CATALYTIC OXIDATION; CERIUM; HIGH PRESSURE EFFECTS; INDUSTRIAL APPLICATIONS; INDUSTRY; METHANE; RHODIUM;

SULFUR;

EID: 79954504751     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie102159w     Document Type: Article

References (31)

1. Hickman, D. A.; Schmidt, L. D. Synthesis gas formation by direct oxidation of methane over Pt monoliths J. Catal. 1992, 138, 267
2. Hickman, D. A.; Haupfear, E. A.; Schmidt, L. D. Synthesis gas formation by direct oxidation of methane over Rh monoliths Catal. Lett. 1993, 17, 223
3. Huff, M.; Schmidt, L. D. Production of olefins by oxidative dehydrogenation of propane and butane over monoliths at short contact times J. Catal. 1994, 149, 127
4. Huff, M.; Schmidt, L. D. Oxidative dehydrogenation of isobutane over monoliths at short contact times J. Catal. 1995, 155, 82
5. Witt, P. M.; Schmidt, L. D. Effect of flow rate on the partial oxidation of methane and ethane J. Catal. 1996, 163, 465
6. Tanaka, H.; Kaino, R.; Nakagawa, Y.; Tomishige, K. Comparative study of Rh/MgO modified with Fe, Co or Ni for the catalytic partial oxidation of methane at short contact time. Part II: Catalytic performance and bed temperature profile Appl. Catal., A 2010, 378, 187
7. 2/MgO catalysts for the catalytic partial oxidation of methane at short contact time J. Catal. 2009, 268, 1
8. Nogare, D. D.; Degenstein, N. J.; Horn, R.; Canu, P.; Schmidt, L. D. Modeling spatially resolved data of methane catalytic partial oxidation on Rh Foam Catalyst at different inlet compositions and flowrates J. Catal. 2011, 277, 134
9. Basile, F.; Benito, P.; Fornasari, G.; Monti, M.; Scavetta, E.; Tonelli, D.; Vaccari, A. Novel Rh-based structured catalysts for the catalytic partial oxidation of methane Catal. Today 2010, 157, 183
10. TM process as the SynGas generator Am. Chem. Soc., Div. Fuel Chem. 2003, 48 (2) 791
11. Farrauto, R.; Hwang, S.; Shore, L.; Ruettinger, W.; Lampert, J.; Giroux, T.; Liu, Y.; Ilinich, O. New material needs for hydrocarbon fuel processing: Generating hydrogen for the PEM fuel cell Ann. Rev. Mater. Res. 2003, 33, 1
12. Kang, I.; Bae, J.; Bae, G. Performance comparison of autothermal reforming for liquid hydrocarbons, gasoline and diesel for fuel cell applications J. Power Sources 2006, 163, 538
13. Kang, I.; Bae, J.; Yoon, S.; Yoo, Y. Performance improvement of diesel autothermal reformer by applying ultrasonic injector for effective fuel delivery J. Power Sources 2007, 172, 845
14. Chaniotis, A. K.; Poulikakos, D. Modeling and optimization of catalytic partial oxidation methane reforming for fuel cells J. Power Sources 2005, 142, 184
15. 2/Air Flames, 8th International Conference on Energy for a Clean Environment: Clean Air 2005, Lisbon, Portugal, 2005, pp 1 - 12.
16. Dunstan, T. D.; Jenkins, K. W. The effects of hydrogen substitution on turbulent premixed methane-air kernels using direct numerical simulation Int. J. Hydrogen Energy 2009, 34, 8389
17. Schefer, R. W. Hydrogen enrichment for improved lean flame stability Int. J. Hydrogen Energy 2003, 28, 1131
18. TerMaath, C. Y.; Skolnik, E. G.; Schefer, R. W.; Keller, J. O. Emissions Reduction benefits from hydrogn addition to midsize gas turbine feedstocks Int. J. Hydrogen Energy 2006, 31, 1147
19. 6 over noble metal coated monoliths. Catal. Today 1994, 21.
20. Zerkle, D. K.; Allendorf, M. D.; Wolf, M.; Deutschmann, O. Understanding homogeneous and heterogeneous contributions to the platinum-catalyzed partial oxidation of ethane in a short-contact-time reactor J. Catal. 2000, 196, 18
21. Horn, R.; Williams, K. A.; Degenstein, N. J.; Bitsch-Larsen, A.; Dalle Nogare, D.; Tupy, S. A.; Schmidt, L. D. Methane catalytic partial oxidation on autothermal rh and pt foam catalysts: oxidation and reforming zones, transport effects, and approach to thermodynamic equilibrium J. Catal. 2007, 249, 380
22. Heitnes, K.; Lindberg, S.; Rokstad, O. A.; Holmen, A. Catalytic partial oxidation of methane to synthesis gas Catal. Today 1995, 24, 211
23. Panuccio, G. J.; Schmidt, L. D. Species and temperature profiles in a differential sphere bed reactor for the catalytic partial oxidation of n -octane Appl. Catal., A 2007, 332, 171
24. Horn, R.; Williams, K. A.; Degenstein, N. J.; Schmidt, L. D. Syngas by catalytic partial oxidation of methane on rhodium: mechanistic conclusions from spatially resolved measurements and numerical simulations J. Catal. 2006, 242, 92
25. Bitsch-Larsen, A.; Horn, R.; Schmidt, L. D. Catalytic partial oxidation of methane on rhodium and platinum: Spatial profiles at elevated pressure Appl. Catal., A 2008, 348, 165
26. 2 addition in catalytic partial oxidation of methane on Rh J. Catal. 2009, 265, 117
27. Elbashir, N. O.; Bao, B.; El-Halwagi, M. An Approach to the Design of Advanced Fischer-Tropsch Reactor for Operation in Near-Critical and Supercritical Phase Media. In Proceedings of the 1st Annual Gas Process Symposium; Elsevier: Amsterdam, 2009.
28. Bitsch-Larsen, A.; Degenstein, N. J.; Schmidt, L. D. Effect of Sulfur in Catalytic Partial Oxidation of Methane over Rh-Ce Coated Foam Monoliths Appl. Catal., B 2008, 78, 364
29. Cimino, S.; Torbati, R.; Lisi, L.; Russo, G. Sulphur inhibition on the catalytic partial oxidation of methane over Rh-based monolith catalysts Appl. Catal., A 2009, 360, 43
30. Satterfield, C. N. Heterogeneous Catalysis in Practice; McGraw-Hills Book Company: New York, 1980.
31. Wang, L.; Murata, K.; Inaba, M. Development of novel highly active and sulphur-tolerant catalysts for steam reforming of liquid hydrocarbons to produce hydrogen Appl. Catal., A 2004, 257, 43