Syngas by catalytic partial oxidation of methane on rhodium: Mechanistic conclusions from spatially resolved measurements and numerical simulations

Journal of Catalysis

Volumn 242, Issue 1, 2006, Pages 92-102

  Horn, R ^a   Williams, K A ^a   Degenstein, N J ^a   Schmidt, L D ^a  

^a University of Minnesota   (United States)

Author keywords

Catalytic partial oxidation; Mass spectrometry; Mechanism; Methane; Numerical simulation; Rhodium; Spatial profiles; Syngas

Indexed keywords

ALUMINUM; COMPUTER SIMULATION; CONTRACTS; HEAT TRANSFER; MASS SPECTROMETRY; MATHEMATICAL MODELS; METHANE; OXIDATION; QUARTZ; RHODIUM; STOICHIOMETRY; THERMAL EFFECTS;

CATALYTIC PARTIAL OXIDATION; SPATIAL PROFILES; SYNGAS; SYNGAS STOICHIOMETRY;

CATALYSTS;

EID: 33745992891     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2006.05.008     Document Type: Article

References (44)

1. Ahlbrandt T.S. Int. Geol. Rev. 44 (2002) 1092-1104
2. Wilhelm D.J., Simbeck D.R., Karp A.D., and Dickenson R.L. Fuel Process. Technol. 71 (2001) 139-148
3. Freni S., Calogero G., and Cavallaro S. J. Power Sources 87 (2000) 28-38
4. Hickman D.A., and Schmidt L.D. Science 259 (1993) 343-346
5. Yorck A.P.E., Xiao T., and Green M.L.H. Top. Catal. 22 (2003) 345-358
6. Lyubovsky M., Roychoudhury S., and LaPierre R. Catal. Lett. 99 (2005) 113-117
7. Mallens E.P.J., Hoebink J.H.B.J., and Marin G.B. J. Catal. 167 (1997) 43-56
8. Heitnes Hofstad H., Hoebink J.H.B.J., Holmen A., and Marin G.B. Catal. Today 40 (1998) 157-170
9. Weng W.Z., Chen M.S., Yan Q.G., et al. Catal. Today 63 (2000) 317-326
10. Basini L., Aasberg-Petersen K., Guarinoni A., and Østberg M. Catal. Today 64 (2001) 9-20
11. Au C.T., and Wang H.Y. J. Catal. 167 (1997) 337-345
12. Weng W.Z., Yan Q.G., Luo C.R., et al. Catal. Lett. 74 (2001) 37-43
13. Slaa J.C., Berger R.J., and Marin G.B. Catal. Lett. 43 (1997) 63-70
14. Wang D., Dewaele O., De Groote A.M., and Froment G.F. J. Catal. 159 (1996) 418-426
15. Nakagawa K., Ikenaga N., Kobayashi T., and Suzuki T. J. Catal. 186 (1999) 405-413
16. Buyevskaya O.V., Wolf D., and Baerns M. Catal. Lett. 29 (1994) 249-260
17. Wang H.Y., and Ruckenstein E. J. Phys. Chem. B 103 (1999) 11327-11331
18. Tian Z., Dewaele O., and Marin G.B. Catal. Lett. 57 (1999) 9-17
19. Rabe S., Truong T.-B., and Vogel F. Appl. Catal. A Gen. 292 (2005) 177-188
20. Ruckenstein E., and Wang H.Y. J. Catal. 187 (1999) 151-159
21. Hickman D.A., and Schmidt L.D. AIChE J. 39 (1993) 1164-1177
22. Deutschmann O., and Schmidt L.D. AIChE J. 44 (1998) 2465-2477
23. Goralski C.T., O'Connor R.P., and Schmidt L.D. Chem. Eng. Sci. 55 (2000) 1357-1370
24. Veser G., and Fraunhammer J. Chem. Eng. Sci. 55 (2000) 2271-2286
25. S. Tummala, Ph.D. Thesis, University of Minnesota (2000)
26. Klein E.J., Tummala S., and Schmidt L.D. Stud. Surf. Sci. Catal. 136 (2001) 245-250
27. Wei J., and Iglesia E. J. Catal. 225 (2004) 116-127
28. Deutschmann O., Schwiedernoch R., Maier L.I., and Chatterjee D. Stud. Surf. Sci. Catal. 136 (2001) 251-258
29. Bizzi M., Saracco G., Schwiedernoch R., and Deutschmann O. AIChE J. 50 (2004) 1289-1299
30. Schwiedernoch R., Tischer S., Correa C., and Deutschmann O. Chem. Eng. Sci. 58 (2003) 633-642
31. Williams K.A., Leclerc C.A., and Schmidt L.D. AIChE J. 51 (2005) 247-260
32. Mhadeshwar A.B., and Vlachos D.G. J. Phys. Chem. B 109 (2005) 16819-16835
33. Twigg M.V., and Richardson J.T. Chem. Eng. Res. Des. 80 (2002) 183-189
34. R.J. Kee, F.M. Rupley, J.A. Miller, Chemkin III: A Fortran Package for the Analysis of Gas-Phase Chemical and Plasma Kinetics, 1999
35. R.J. Kee, F.M. Rupley, J.A. Miller, et al., Plug: A Program for the Analysis of Plug-Flow Reactors with Gas-Phase and Surface Chemistry, CHEMKIN Collection, 3.5, Reaction Design, San Diego, CA, 1999
36. Deutschmann O., Tischer C.C.S., Chatterjee D., Kleditzsch S., and Janardhanan V.M. DETCHEM software package. second ed. (2005), Karlsruhe. http://www.detchem.com
37. Fluent 6.2, Computational Fluid Dynamics Software, User's Guide, 2005
38. Richardson J.T., Peng Y., and Remue D. Appl. Catal. A Gen. 204 (2000) 19-32
39. Incropera F.P., and DeWitt D.P. Fundamentals of Heat and Mass Transfer (1996), Wiley, New York
40. Zhao C.Y., Lu T.J., Hodson H.P., and Jackson J.D. Mater. Sci. Eng. A Sruct. A 367 (2004) 123-131
41. Hohn K.L., and Schmidt L.D. Appl. Catal. A Gen. 211 (2001) 53-68
42. Sweeting T.B., Norris D.A., Strom L.A., and Morris J.R. Mater. Res. Soc. Symp. Proc. 368 (1995) 309-314
43. Grunwaldt J.-D., and Baiker A. Catal. Lett. 99 (2005) 5-12
44. Stutz M.J., and Poulikakos D. Chem. Eng. Sci. 60 (2005) 6983-6997