Compositional trends in tourmaline from intragranitic NYF pegmatites of the třebíč pluton, czech republic: An electron microprobe, mössbauer and LA-ICP-MS study

Canadian Mineralogist

Volumn 49, Issue 1, 2011, Pages 359-380

  Novák, Milan ^a   Škoda, Radek ^a   Filip, Jan ^b   Macek, Ivo ^a   Vaculovič, Tomáš ^a  

^a MASARYK UNIVERSITY   (Czech Republic)

^b PALACKÝ UNIVERSITY   (Czech Republic)

Author keywords

Compositional trends; Czech republic; Dravite Schorl Uvite Povondraite; Electron microprobe; LA ICP MS; M ssbauer spectroscopy; Nyf pegmatites; Substitution mechanisms; Tourmaline; T eb pluton

Indexed keywords

COMPOSITIONAL TRENDS; CZECH REPUBLIC; DRAVITE - SCHORL - UVITE - POVONDRAITE; ELECTRON MICROPROBE; LA-ICP-MS; NYF PEGMATITES; SSBAUER SPECTROSCOPIES; SUBSTITUTION MECHANISMS; TOURMALINE;

ALUMINUM; ELECTRONS; GALLIUM; GRANITE; INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY; MANGANESE; MASS SPECTROMETERS; MICA; OXIDE MINERALS; QUARTZ; SCANDIUM; SODIUM; TRACE ELEMENTS;

SILICATE MINERALS;

ELECTRON PROBE ANALYSIS; FLUID COMPOSITION; INDUCTIVELY COUPLED PLASMA METHOD; MORPHOLOGY; MOSSBAUER SPECTROSCOPY; PEGMATITE; TOURMALINE;

CZECH REPUBLIC;

NIOBIA;

EID: 79954474444     PISSN: 00084476     EISSN: None     Source Type: Journal    
DOI: 10.3749/canmin.49.1.359     Document Type: Article

References (70)

1. ABDURIYIM, A., KITAWAKI, H., FURUYA, M. & SCHWARZ, D. (2006): "Paraiba"-type copper-bearing tourmaline from Brazil, Nigeria and Mozambique: chemical fingerprinting by LA-ICP-MS. Gems & Gemol. 42, 4-21.
2. ANDREOZZI, G.B., BOSI, F. & LONGO M. (2008): Linking Mössbauer and structural parameters in elbaite-schorl-dravite tourmalines. Am. Mineral. 93, 658-666.
3. AURISICCHIO, C., DEMARTIN, F., OTTOLINI, L. & PEZZOTTA, R (1999): Homogeneous liddicoatite from Madagascar: a possible reference material? First EMPA, SIMS and SREF data. Eur. J. Mineral. 11, 237-242.
4. BAČÍK, P., UHER, P., SÝKORA, M. & LIPKA, J. (2008): Low-Al tourmalines of the schorl-dravite-povondraite series in redeposited tourmalinites from the Western Carpathians, Slovakia. Can. Mineral. 46, 1117-1129.
5. BLOODAXE, E.S., HUGHES, J.M., DYAR, M.D., GREW, E.S. & GUIDOTTI, C.V (1999): Linking structure and chemistry in the schorl-dravite series. Am. Mineral. 84, 922-928.
6. 2+ over octahedrally coordinated sites of tourmaline. Am. Mineral. 93, 1647-1653.
7. BOSI, F. & LUCCHESI, S. (2007): Crystal chemical relationships in the tourmaline group: structural constraints on chemical variability. Am. Mineral. 92, 1054-1063.
8. BÜTTNER, S.H. & KASEMANN, S.A. (2007): Deformationcontrolled cation diffusion in tourmaline: a microanalytical study on trace elements and boron isotopes. Am. Mineral. 92, 1862-1874.
9. BURIÁNEK, D. & NOVÁK, M. (2007): Compositional evolution and substitutions in disseminated and nodular tourmaline from leucocratic granites: examples from the Bohemian Massif, Czech Republic. Lithos 95, 148-164.
10. BURT, D.M. (1989): Vector representation of tourmaline composition. Am. Mineral. 74, 826-839.
11. CAVARETTA, G. & PUXEDDU, M. (1990): Schorl - dravite - ferridravite tourmalines deposited by hydrothermal magmatic fluids during early evolution of Larderello geothermal field, Italy. Econ. Geol. 85, 1236-1251.
12. ČERNÝ, P. & ERCIT, T.S. (2005): The classification of granitic pegmatites revisited. Can. Mineral. 43, 2005-2026.
13. DEER, W.A., HOWIE, R.A. & ZUSSMAN, J. (1997): Rock-Forming Minerals. 1B. Disilicates and Ring Silicates (2nd ed.). Longman Scientific and Technical, London, U.K.
14. DYAR, M.D., GUIDOTTI, C.V., CORE, D.P., WEARN, K.M., WISE, M.A., FRANCIS, C.A., JOHNSON, K., BRADY, J.B., ROBERTSON, J.D. & CROSS, L.R. (1999): Stable isotope and crystal chemistry of tourmaline across pegmatite - country rock boundaries at Black Mountain and Mount Mica, southwestern Maine, U.S.A. Eur. J. Mineral. 11, 281-294.
15. DYAR, M.D., TAYLOR, M.E., LUTZ, T.M., FRANCIS, C.A., GUIDOTTI, C.V. & WISE, M. (1998): Inclusive chemical characterization of tourmaline: Mössbauer study of Fe valence and site occupancy. Am. Mineral. 83, 848-864.
16. ERCTT, T.S. (2005): REE-enriched granitic pegmatites. In RareElement Geochemistry and Ore Deposits (R.L. Linnen & I.M. Samson, eds.). Geol. Assoc. Can., Short Course Notes 17, 257-296.
17. ERCIT, T.S., GROAT, L.A. & GAULT, R.A. (2003): Granitic pegmatites of the O'Grady Batholith, N.W.T., Canada: a case study of the evolution of the elbaite subtype of rareelement granitic pegmatites. Can. Mineral. 41, 117-137.
18. ERTL, A., HUGHES, J.M., PROWATKE, S., LUDWIG, T., PRASAD, P.S.R., BRANDSTÁTTER, F., KÖRNER, W., SCHUSTER, R., PERTLIK, R & MARSCHALL, H. (2006): Tetrahedrally coordinated boron in tourmalines from the liddicoatite-elbaite series from Madagascar: structure, chemistry, and infrared spectroscopic studies. Am. Mineral. 91, 1847-1856.
19. ERTL, A., HUGHES, J.M., PROWATKE, S., ROSSMAN, G.R., LONDON, D. & FRITZ, E.A. (2003): Mn-rich tourmaline from Austria: structure, chemistry, optical spectra, and relations to synthetic solid solutions. Am. Mineral. 88, 1369-1376.
20. FEDERICO, M., ANDREOZZI, G.B., LUCCHESI, S., GRAZIANI, G. & CÉSAR-MENDES, J. (1998): Compositional variation of tourmaline in the granitic pegmatite dykes of the Cruzeiro mine, Minas Gerais, Brazil. Can. Mineral. 36, 415-431.
21. FOORD, E.E., ČERNÝ, P., JACKSON, L.L., SHERMAN, D.M. & EBY, R.K. (1995): Mineralogical and geochemical evolution of micas from the miarolitic pegmatites of the anorogenic Pikes Peak Batholith. Mineral. Petrol. 55, 1-26.
22. FRIETSCH, R., TUISKU, P., MARTINSSON, O. & PERDAHL, J.-A. (1997): Early Proterozoic Cu-(Au) and Fe ore deposits associated with regional Na-Cl metasomatism in northern Fennoscandia. Ore Geol. Rev. 12, 1-34.
23. GAWEDA, A., PIECZKA, A. & KRACZKA, J. (2002): Tourmalines from the Western Tatra Mountains (W-Carpathians, S-Poland): their characteristics and petrogenetic importance. Eur. J. Mineral. 14, 943-955.
24. HAWTHORNE, F.C. (1996): Structural mechanisms for light-element variations in tourmaline. Can. Mineral. 34, 123-132.
25. HAWTHORNE, F.C. (2002): Bond-valence constraints on the chemical composition of tourmaline. Can. Mineral. 40, 789-797.
26. HAWTHORNE, F.C. & HENRY, D.J. (1999): Classification of the minerals of the tourmaline group. Eur. J. Mineral. 11, 201-215.
27. HENRY, D.J. & DUTROW, B.L. (1996): Metamorphic tourmaline and its petrologic applications. In Boron: Mineralogy, Petrology and Geochemistry (E.S. Grew & L.M. Anovitz, eds.). Rev. Mineral 33, 503-557.
28. HENRY, D.J. & GUIDOTTI, C.V. (1985): Tourmaline as a petrogenetic indicator mineral: an example from the staurolitegrade metapelites of NW Maine. Am. Mineral. 70, 1-15.
29. HENRY, D.J., KIRKLAND, B.L. & KIRKLAND, D.W. (1999): Sector-zoned tourmaline from the cap rock of a salt dome. Eur. J. Mineral. 11, 263-280.
30. HENRY, D., NOVÁK, M., HAWTHORNE, F.C., ERTL, A., DUTROW, B., UHER, P. & PEZZOTTA, R (2011): Nomenclature of the tourmaline supergroup-minerals. Am. Mineral, (in press).
31. HOLUB, F.V., COCHERIE, A. & ROSSI, P. (1997): Radiometric dating of granitic rocks from the Central Bohemian Plutonic Complex (Czech Republic): constraints on the chronology of thermal and tectonic events along the Moldanubian-Barrandian boundary. C.R. Acad. Paris, Earth & Planet. Sci., 325, 19-26.
32. JANOUŠEK, V., BOWES, D.R., ROGERS, G., FARROW, C.M. & JELÍNEK, E. (2000): Modelling diverse processes in the petrogenesis of a composite batholith: the Central Bohemian Pluton, Central European Hercynides. J. Petrol 41, 511-543.
33. JANOUŠEK, V., HOLUB, F.V. & GERDES, A. (2003): K-rich magmatism in the Moldanubian Unit, Bohemian Massif - a complex story featuring variably enriched lithospheric mantle melts and their interaction with the crust. Geolines 16, 48-49.
34. JOLLIFF, B.L., PAPIKE, J.J. & LAUL, J.C. (1987): Mineral recorders of pegmatite internal evolution: REE contents of tourmaline from the Bob Ingersoll pegmatite, South Dakota. Geochim. Cosmochim. Acta 51, 2225-2232.
35. JOLLIFF, B.L, PAPIKE, J.J. & SHEARER, C.K. (1986): Tourmaline as a recorder of pegmatite evolution: Bob Ingersoll pegmatite, Black Hills, South Dakota. Am. Mineral. 71, 472-500.
36. KALT, A., SCHREYER, W., LUDWIG, T., PROWATKE, S., BERNHARDT, H.-J. & ERTL, A. (2001): Complete solid solution between magnesian schorl and lithian excess-boron olenite in a pegmatite from Koralpe (eastern Alps, Austria). Eur. J. Mineral. 13, 1191-1205.
37. KILE, D.E. & FOORD, E.E. (1998): Micas from the Pikes Peak Batholith and its cogenetic granitic pegmatites, Colorado: optical properties, composition, and correlation with pegmatite evolution. Can. Mineral. 36, 463-482.
38. KOTKOVA, J., SCHALTEGGER, U. & LEICHMANN, J. (2003): 338-335 Ma old intrusions in the Bohemian Massif: a relic of the orogen-wide durbachitic magmatism in European Variscides. J. Czech Geol. Soc. 48, 80-81.
39. LONDON, D. (1999): Stability of tourmaline in peraluminous granite systems: the boron cycle from anatexis to hydrothermal aureoles. Eur. J. Mineral 11, 253-262.
40. LONDON, D. (2008): Pegmatites. Can. Mineral, Spec. Publ. 10.
41. LONDON, D., MORGAN, G.B..VI & WOLF, M.B. (1996): Boron in granitic rocks and their contact aureoles. In Boron: Mineralogy, Petrology and Geochemistry (E.S. Grew & L.M. Anovitz, eds.). Rev. Mineral. 33, 299-330.
42. MARTIN, R.F. & DE VITO, C. (2005): The pattern of enrichment in felsic pegmatites ultimately depend on tectonic setting. Can. Mineral. 43, 2027-2048.
43. 2O in rapid emplacement and crystallization of granite pegmatites: resolving the paradox of large crystals in highly undercooled melts. Contrib. Mineral. Petrol. 160, 313-325.
44. NOVÁK, M. (2000): Compositional pathways of tourmaline evolution during primary (magmatic) crystallization in complex (Li) pegmatites of the Moldanubicum, Czech Republic. Mem. Soc. Italiana Scienze Nat., Mus. Civ. Storia Nat., Milano 30, 45-56.
45. NOVÁK, M. (2007): Contamination in granitic pegmatites, examples from the Moldanubicum, Czech Republic. In Granitic Pegmatites: The State of the Art. International Symposium. U. P. Facul. Ciências, Memórias, 8, 9-12.
46. NOVÁK, M. & FILIP, J. (2010): Unusual (Na,Mg)-enriched beryl and its breakdown products (beryl II, bazzite, bavenite) from euxenite-type NYF pegmatite related to the orogenic ultrapotassic Třebíč Pluton, Czech Republic. Can. Mineral. 48, 615-628.
47. NOVÁK, M. & POVONDRA, P. (1995): Elbaite pegmatites in the Moldanubicum: a new subtype of the rare-element class. Mineral. Petrol. 55, 159-176.
48. NOVÁK, M., POVONDRA, P. & SELWAY, J.B. (2004): Schorl-oxyschorl to dravite-oxy-dravite tourmaline from granitic pegmatites; examples from the Moldanubicum, Czech Republic. Eur. J. Mineral. 16, 323-333.
49. NOVÁK, M., SELWAY, J.B., ČERNÝ, P., HAWTHORNE, F.C. & OTTOLINI, L. (1999): Tourmaline of the elbaite-dravite series from an elbaite-subtype pegmatite at Bližná, southern Bohemia, Czech Republic. Eur. J. Mineral., 11, 557-568.
50. NOVÁK, M., SELWAY, J.B. & ŠKODA, R. (2003): Tourmaline from the NYF pegmatites; example from the Třebíč massif. In International Symposium LERM 2003 (Nové Město na Moravě), Book of Abstracts, 55-56.
51. POUCHOU, J.L. & PICHOIR, F. (1985): "PAP" Φ(ρZ) procedure for improved quantitative microanalysis. In Microbeam Analysis (J.T. Armstrong, ed.). San Francisco Press, San Francisco, California (104-106).
52. POVONDRA, P. (1981): The crystal chemistry of tourmalines of the schorl-dravite series. Acta Univ. Carol., Geol. 1981, 223-264.
53. RODA, E., PESQUERA, A. & VELASCO, F. (1995): Tourmaline in granitic pegmatites and their country rocks, Fregeneda area, Salamanca, Spain. Can. Mineral. 33, 835-848.
54. RODA-ROBLES, E., PESQUERA, A., GIL P.P., TORRES-RUIZ, J. & FONTAN, F. (2004): Tourmaline from the rare-element Pinilla pegmatite, (Central Iberian Zone, Zamora, Spain): chemical variation and implications for pegmatitic evolution. Mineral. Petrol. 81, 249-263.
55. SELWAY, J.B., ČERNÝ, P., HAWTHORNE, F.C. & NOVÁK, M. (2000b): The Tanco pegmatite at Bernic Lake, Manitoba. XIV Internal tourmaline. Can. Mineral. 38, 877-891.
56. SELWAY, J.B., NOVÁK, M., ČERNÝ, P. & HAWTHORNE, F.C. (1999): Compositional evolution of tourmaline in lepidolite-subtype pegmatites. Eur. J. Mineral. 11, 569-584.
57. SELWAY, J.B., NOVÁK, M., ČERNÝ, P. & HAWTHORNE, F.C. (2000a): The Tanco pegmatite at Bernic Lake, Manitoba. XIII. Exocontact tourmaline. Can. Mineral. 38, 869-876.
58. SELWAY, J.B., SMEDS, S.-A., ČERNÝ, P. & HAWTHORNE, F.C. (2002): Compositional evolution of tourmaline in the petalite-subtype Nyköpingsgruvan pegmatites, Utö, Stockholm archipelago, Sweden. GFF 124, 93-102. (Pubitemid 39039808)
59. ŠKODA, R. & ČOPJAKOVÁ, R. (2005): Unusual Sn mineralization from the NYF pegmatite near Klučov, Třebí č Pluton, Moldanubicum. Geol. Výzk. Mor. Slez. v r. 2004, 93-97 (in Czech with English summary).
60. 6) minerals from REL-REE euxenite-subtype pegmatites of the Třebíč Pluton, Czech Republic; substitutions and fractionation trends. Lithos 95, 43-57.
61. ŠKODA, R., NOVÁK, M. & HOUZAR, S. (2006): Granitic NYF pegmatites of the Třebíč Pluton. Acta Mus. Moraviae, Sci. geol. 91, 129-176 (in Czech with English summary).
62. SLACK, J.F. (1996): Tourmaline associations with hydrothermal ore deposits. In Boron: Mineralogy, Petrology and Geochemistry (E.S. Grew & L.M. Anovitz, eds.). Rev. Mineral. 33, 559-644.
63. TINDLE, A.G., BREAKS, F.W. & SELWAY, J.B. (2002): Tourmaline in petalite-subtype granitic pegmatites: evidence of fractionation and contamination from the Pakeagama Lake and Separation Lake areas of northwestern Ontario, Canada. Can. Mineral. 40, 753-788.
64. TINDLE, A.G., SELWAY, J.B. & BREAKS, F.W. (2005): Liddicoatite and associated species from the McCombe spodumene-subtype rare-element granitic pegmatite, northwestern Ontario, Canada. Can. Mineral. 43, 769-793.
65. WEBBER, K.L., SIMMONS, W.B. & FALSTER, A.U. (1999): Biotite as tectonic discriminant for anorogenic and orogenic pegmatites. The Eugene E. Foord Memorial Symposium on NYF-type Pegmatites (Denver). Can. Mineral. 37, 839-841.
66. WOLF, M.B. & LONDON, D. (1997): Boron in granitic magmas: stability of tourmaline in equilibrium with biotite and cordierite. Contrib. Mineral. Petrol. 130, 12-30.
67. ŽÁČEK, V., FRÝDA, J., PETROV, A. & HYRŠL, J. (2000): Tourmalines of the povondraite - (oxy)dravite series from the cap rock of meta-evaporite in Alto Chapare, Cochambamba, Bolivia. J. Czech Geol. Soc. 45, 3-12.
68. ŽAK, J., HOLUB, F.V. & VERNER, K. (2005): Tectonic evolution of a continental magmatic arc from transpression in the upper crust to exhumation of mid-crustal orogenic root recorded by episodically emplaced plutons: the central Bohemian plutonic Complex (Bohemian Massif). Int. J. Earth Sci. (Geol Rundsch.), 94, 385-400.
69. ŽÁK, T. & JIRÁSKOVÁ, Y. (2006): CONFIT: Mössbauer spectra fitting program. Surf. Interface Anal. 38, 710-714.
70. ZHANG, Al CHENG, WANG, RU CHENG, JIANG, SHAO YONG, HU, HUAN & ZHANG, HUI (2008): Chemical and textural features of tourmaline from the spodumene-subtype Koktokay No. 3 pegmatite, Altai, northwestern China: a record of magmatic to hydrothermal evolution. Can. Mineral. 46, 41-58.