Mn-rich tourmaline from Austria: Structure, chemistry, optical spectra, and relations to synthetic solid solutions

American Mineralogist

Volumn 88, Issue 8-9, 2003, Pages 1369-1376

  Ertl, Andreas ^a   Hughes, John M ^b   Prowatke, Stefan ^c   Rossman, George R ^d   London, David ^e   Fritz, Eric A ^f  

^a UNIVERSITY OF VIENNA   (Austria)

^b MIAMI UNIVERSITY   (United States)

^c UNIVERSITY OF HEIDELBERG   (Germany)

^d CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^e UNIVERSITY OF OKLAHOMA   (United States)

^f NONE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; ALUMINUM COMPOUNDS; CHEMICAL ANALYSIS; COLOR; CRYSTAL STRUCTURE; GAMMA RAYS; IRON OXIDES; IRRADIATION; LIGHT ABSORPTION; LITHIUM; MANGANESE; MANGANESE OXIDE; OXIDE MINERALS; SILICATE MINERALS; SILICON;

BEARING SYSTEMS; BROWN COLOR; CRYSTAL STRUCTURE DETERMINATION; CRYSTAL STRUCTURE REFINEMENT; IRRADIATED CRYSTALS; NATURAL IRRADIATION; OPTICAL SPECTRA; POSITIVE CORRELATIONS;

MANGANESE METALLOGRAPHY;

CRYSTAL CHEMISTRY; CRYSTAL STRUCTURE; MANGANESE; OPTICAL PROPERTY; TOURMALINE;

AUSTRIA;

EID: 0141750359     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-2003-8-921     Document Type: Article

References (32)

1. Burns, P.C., MacDonald, D.J., and Hawthorne, F.C. (1994) The crystal chemistry of manganese-bearing elbaite. Canadian Mineralogist, 32, 31-41.
2. Duparc, L., Wunder, M., and Sabot, R. (1913) Die Mineralien der Pegmatite in der Umgehung von Antsirabé auf Madagascar. Zeitschrift für Kristallographic, 52, 294-300.
3. Dyar, M.D., Taylor, M.E., Lutz, T.M., Francis, C.A., Guidotti, C.V., and Wise, M. (1998) Inclusive chemical characterization of tourmaline: Mössbauer study of Fe valence and site occupancy. American Mineralogist, 83, 848-864.
4. Dyar, M.D., Wiedenbeck, M., Robertson, D., Cross, L.R., Delaney, J.S., Ferguson, K., Francis, C.A., Grew, E.S., Guidotti, C.V., Hervig, R.L., Hughes, J.M., Husler, J., Leeman, W., McGuire, A.V., Rhede, D., Rothe, H., Paul, R.L., Richards, I., and Yates, M. (2001) Reference Minerals for the Microanalysis of Light Elements. Geostandards Newsletter, 25, 441-163.
5. Ertl, A., Hughes, J.M., and Marler, B. (2001) Empirical formulae for the calculation of and X-O2 bond lengths in tourmaline and relations to tetrahedrally-coordinated boron. Neues Jahrbuch Mineralogie Monatshefte, 12, 548-557.
6. Foit, F.F., Jr. (1989) Crystal chemistry of alkali-deficient schorl and tourmaline structural relationships. American Mineralogist, 74, 422-431.
7. Foit, F.F., Jr. and Rosenberg, P.E. (1979) The structure of vanadium-bearing tourmaline and its implications regarding tourmaline solid solutions. American Mineralogist, 64, 788-798.
8. Grice, J.D. and Ercit, T.S. (1993) Ordering of Fe and Mg in the tourmaline crystal structure: The correct formula. Neues Jahrbuch Mineralogie Monatshefte, 165, 245-266.
9. Hawthorne, F.C. (1996) Structural mechanisms for light-element variations in tourmaline. Canadian Mineralogist, 34, 123-132.
10. Hawthorne, F.C. and Henry, D.J. (1999) Classification of the minerals of the tourmaline group. European Journal of Mineralogy, 11, 201-215.
11. Kalt, A., Schreyer, W., Ludwig, T., Prowatke, S., Bernhardt, H.-J., and Ertl, A. (2001) Complete solid solution between magnesian schorl and lithian excess-boron olenite in a pegmatite from Koralpe (eastern Alps, Austria). European Journal of Mineralogy, 13, 1191-1205.
12. King, P.L., Vennenmann, T.W., Holloway, J.R., Hervig, R.L., Lowenstern, J.B., and Forneris, J.F. (2002) Analytical techniques for volatiles: A case study using intermidiate (andesitic) glasses. American Mineralogist, 87, 1077-1089.
13. Kunitz, W. (1929) Die Mischungsreihen in der Turmalingruppe und die genetischen Bezichungen zwischen Turmalinen und Glimmern. Chemie der Erde, 4, 208-251.
14. London, D. (1999) Stability of tourmaline in peraluminous granite systems: the boron cycle from anatexis to hydrothermal aureoles. European Journal of Mineralogy, 11, 253-262.
15. London, D. and Manning, D.A.C. (1995) Compositional variation and significance of tourmaline from southwest England. Economic Geology, 90, 495-519.
16. th Annual Goldschmidt Conference Abstract 3369, Lunar Planetary Institute Contribution 1088, Lunar Planetary Institute, Houston (CD-ROM).
17. MacDonald, D.J. and Hawthorne, F.C. (1995) The crystal chemistry of Si ↔ Al substitution in tourmaline. Canadian Mineralogist, 33, 849-858.
18. 3+ interactions in tourmaline. Physics and Chemistry of Minerals, 14, 163-171.
19. Morgan, G.B. VI and London, D. (1999) Crystallization of the Little Three layered pegmatite-aplite dike, Ramona District, California. Contributions to Mineralogy and Petrology, 136, 310-330.
20. Novák, M. (2000) Compositional pathways of tourmaline evolution during primary (magmatic) crystallization in complex (Li) pegmatites of the Moldanubicum. Czech Republic. Memorie della Società Italiana di Science Naturali e del Museo Civico di Storia naturale di Milano, 30, 45-56.
21. Nuber, B. ad Schmetzer, K. (1984) Structural refinement of tsilaisite (manganese tourmaline). Neues Jahrbuch für Mineralogie. Monatshefte, 1984, 301-304.
22. Ottolini, L., Bottazzi, P., and Vannucci, R. (1993) Quantification of lithium, beryllium, and boron in silicates by secondary Ion Mass Spectrometry using conventional energy filtering. Analytical Chemistry, 65, 1960-1968.
23. 10B between tourmaline and aqueous vapor: A temperature- and pressure-dependent isotopic system. Chemical Geology, 101, 123-129.
24. Perkins, W.T., Pearce, N.J.G., and Westgate, J.A. (1997) The development of laser ablation ICP-MS and calibration strategies: examples from the analyses of trace elements in volcanic glass shards and sulfide minerals. Geostandards Newsletter, 21, 115-144.
25. Prowatke, S., Ertl, A., and Hughes, J.M. (2003) Tetrahedrally-coordinated Al in Mn-rich, Li- and Fe-bearing olenite from Eibenstein an der Thaya, Lower Austria: A chemical and structural investigation. Neues Jahrbuch Mineralogie Monatshefte, 2003, 385-395.
26. Reinitz, I.L. and Rossman, G.R. (1988) Role of natural radiation in tourmaline coloration. American Mineralogist, 73, 822-825.
27. Rossman, G.R. and Mattson, S.M. (1986) Yellow, Mn-rich elbaite with Mn-Ti intervalence charge transfer. American Mineralogist, 71, 599-602.
28. Schmetzer, K. and Bank, H. (1984) Crystal chemistry of tsilaisite (manganese tourmaline) from Zambia. Neues Jahrbuch für Mineralogie Monatshefte, 1984, 61-69.
29. Schreyer, W., Hughes, J.M., Bernhardt, H.-J., Kalt, A., Prowatke, S., and Ertl, A. (2002) Reexamination of olenite from the type locality: detection of boron in tetrahedral coordination. European Journal of Mineralogy, 14, 935-942.
30. Shigley, J.E., Kane, R.E., and Manson, D.V. (1986) A notable Mn-rich gem elbaite tourmaline and its relationship to "tsilaisite". American Mineralogist, 71, 1214-1216.
31. Tindle, A.G., Breaks, F.W., and Selway, J.B. (2002) Tourmaline in petalite-subtype granitic pegmatites: evidence of fractionation and contamination from the Pakeagama Lake and Separation Lake areas of northwestern Ontario, Canada. Canadian Mineralogist, 40, 753-788.
32. Wright, S.E., Foley, J.A., and Hughes, J.M. (2000) Optimization of site occupancies in minerals using quadratic programming. American Mineralogist, 85, 524-531.