A unique unit cell containing simultaneous doubly and triply copper(II) complexes bridging by 2,4-pyridine dicarboxylate: Synthesis, structural characterization and magnetic properties

Inorganic Chemistry Communications

Volumn 14, Issue 5, 2011, Pages 702-705

  Mautner, Franz A ^a   Albering, Jörg H ^b   Corbella, Montserrat ^c   Massoud, Salah S ^d  

^a GRAZ UNIVERSITY OF TECHNOLOGY   (Austria)

^b GRAZ UNIVERSITY OF TECHNOLOGY   (Austria)

^c UNIVERSITY OF BARCELONA   (Spain)

^d UNIVERSITY OF LOUISIANA AT LAFAYETTE   (United States)

Author keywords

Bridging carboxylate; Copper; Crystal structure; Magnetic properties; Polynuclear complexes

Indexed keywords

EID: 79954417999     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.02.011     Document Type: Article

References (73)

1. B.I. Chen, M. Eddaoudi, S.T. Hyde, M. O'Keeffe, and O.M. Yaghi Science 291 2001 1021
2. A.U. Czaja, N. Trukhan, and U. Müller Chem. Soc. Rev. 38 2009 1284
3. L.J. Murray, M. Dincǎ, and J.R. Long Chem. Soc. Rev. 38 2009 1294
4. S. Xiang, X. Wu, J. Zhang, R. Fu, S. Hu, and X. Zhang J. Am. Chem. Soc. 127 2005 16352
5. H.K. Chae, D.Y. Siberio-Perez, J. Kim, Y. Go, M. Eddaoudi, A.J. Matzger, M. O'Keeffe, and O.M. Yaghi Nature 427 2004 523
6. M. Eddaoudi, J. Kim, N. Rossi, D. Vodak, J. Wachter, O'Keeffe, and O.M. Yaghi Science 295 2002 469
7. W. Lin, L. Ma, and O.R. Evans Chem. Commun. 22 2000 2263
8. W. Lin, Z. Wang, and L. Ma J. Am. Chem. Soc. 121 1999 11249
9. C.N.R. Rao, A. Rangnathan, V.R. Pedireddi, and A.R. Raju Chem. Commun. 2000 39
10. M. Sanselme, J.M. Grenèche, M. Fiou-Cavllec, and G. Férey Chem. Commun. 2002 2172
11. V.V. Puvlishchuk, I.A. Koval, E. Goroshink, A.W. Addison, G.A. Albuda, and J. Reedijk Eur. J. Inorg. Chem. 2001 297
12. K.L. Gurunatha, and T.K. Maji Eur. J. Inorg. Chem. 2009 1592
13. J. Bi, L. Kong, Z. Huang, and J. Liu Inorg. Chem. 47 2008 4564
14. F.A. Mautner, R. Vicente, F.R. Louka, and S.S. Massoud Inorg. Chim. Acta 361 2008 1339
15. S.S. Massoud, K.T. Broussard, F.A. Mautner, R. Vicente, M.K. Saha, and I. Bernal Inorg. Chim. Acta 361 2008 123
16. S.S. Massoud, F.A. Mautner, R. Vicente, and B.M. Rodrigue Inorg. Chim. Acta 359 2006 3321
17. S.S. Massoud, F.A. Mautner, R. Vicente, and N.S. Hunter Inorg. Chim. Acta 359 2006 1489
18. J.-D. Lin, C.-C. Jia, Z.-H. Li, and S.-W. Du Inorg. Chem. Commun. 12 2009 558
19. G.-B. Che, C.-B. Liu, B. Liu, Q.-W. Wang, and Z.-L. Xu CrystEngComm. 10 2008 184
20. J. Yao, Z.-D. Lu, Y.-Z. Li, J.-G. Lin, X.-Y. Duan, S. Gao, Q.-J. Meng, and C.-S. Lu CrystEngComm. 10 2008 1379
21. J. Meng, X. Wang, E. Wang, Y. Li, C. Qin, and X. Xu Inorg. Chim. Acta 361 2008 2447
22. S.-W. Liang, M.-X. Li, M. Shao, and H.-J. Liu Inorg. Chem. Commun. 10 2007 1347
23. D. Zacher, J. Liu, K. Huber, and R.A. Fisher Chem. Commun. 2009 1031
24. J. Mroziński, A. Bieńko, P. Kopel, and V. Langer Inorg. Chim. Acta 361 2008 3723
25. L.-P. Zhang, J. Yang, J.-F. Ma, Z.-F. Jia, Y.-P. Xie, and G.-H. Wei CrystEngComm. 10 2008 1410
26. D.T. Tran, D. Chu, A.G. Oliver, and S.R.J. Oliver Inorg. Chem. Commun. 12 2009 351
27. M.A. Braveman, R.M. Supkowski, and R.L. LaDuca J. Solid State Chem. 180 2007 1852
28. J. Guo, T. Zhang, J. Zhang, Y. Liu, W. Yu, and R.W. Wu Struct. Chem. 2006 577
29. L.-J. Zhang, J.-Q. Xu, Z. Shi, W. Xu, and T.-G. Wang Dalton Trans. 2003 1148
30. L.-J. Zhang, J.-Q. Xu, Z. Shi, X.-L. Zhao, and T.-G. Wang J. Solid State Chem. 32 2003 32
31. R. Cao, D. Sun, Y. Liang, M. Hong, K. Tatsumi, and Q. Shi Inorg. Chem. 41 2002 2087
32. B. Moulton, and M.J. Zaworotko Chem. Rev. 101 2001 1620
33. De-Qing Chu, J.-Q. Xu, L.-M. Duan, T.-G. Wang, A.-Q. Tang, and L. Ye Eur. J. Inorg. Chem. 2001 1135
34. K.L. Gurunatha, and T.K. Maji Eur. J. Inorg. Chem. 2009 1592
35. S.-X. Cui, Y.-L. Zhao, J.-P. Zhang, Q. Liu, and Y. Zhang Polyhedron 28 2009 980
36. L. Chen, X.-M. Lin, Y. Ying, Q.-G. Zhan, Z.-H. Hong, J.-Y. Li, N.S. Weng, and Y.-P. Cai Inorg. Chem. Commun. 12 2009 761
37. S.S. Massoud, P.J. Deifik, P.K. Bankole, R. Lalancette, G. Yee, D. Tatum, I. Bernal, and F.A. Mautner Inorg. Chim. Acta 363 2010 1001
38. M. Gryz, W. Starosta, and J. Leciejewicz J. Coord. Chem. 58 2005 931
39. S.S. Massoud, F.R. Louka, L.T. Nguyen, M. Mikuriya, J.H. Albering, and F.A. Mautner Inorg. Chim. Acta 366 2011 394
40. L.-F. Chen, X.-Y. Cao, Z.-J. Li, J.-K. Cheng, Q.-P. Lin, and Y.-G. Yao Inorg. Chem. Commum. 11 2008 961
41. P. King, R. Clérac, C.E. Anson, and A.K. Powel Dalton Trans. 2004 852
42. P. King, R. Clérac, C.E. Anson, C. Coulon, and A.K. Powel Inorg. Chem. 42 2003 3492
43. J.-L. Tian, S.-P. Yan, D.-Z. Liao, Z.-H. Jiang, and P. Cheng Inorg. Chem. Commun. 6 2003 1025 1029
44. -1 per Cu atom): in H2O: 572 (sh), 657 (237); in MeOH: 571 (sh), 648 (283).
45. -1 per Cu atom)}: in H2O: 644 (104). Caution: Salts of perchlorate as well as their metal complexes are potentially explosive and should be handled with great care and in small quantities.
46. F.A Mautner, J.H. Albering, S.S. Massoud, results to be published.
47. Physical measurements. Infrared spectra were recorded on JASCO FT/IR-480 plus spectrometer as KBr pellets. Electronic spectra were recorded using an Agilent 8453 HP diode UV-VIS spectrophotometer. Elemental analyses were carried out by the Atlantic Microlaboratory, Norcross, Georgia USA. Magnetic measurements were carried out in the Unitat de Mesures Magnètiques (Universitat de Barcelona) on polycrystalline samples (20 mg) with a Quantum Design SQUID MPMS-XL susceptometer working in the 2-300 K range. The magnetic field was 0.1 T. The diamagnetic corrections were evaluated from Pascal's constants.
48. C.E. Xanthopoulos, M.P. Sigalas, G.A. Katsoulos, C.A. Tsipis, A. Terzis, M. Mentzafos, and A. Hountas Inorg. Chem. 32 1993 5433
49. E.G. Bakalbassis, J. Mrozinski, and C.A. Tsipis Inorg. Chem. 25 1986 3684
50. E.G. Bakalbassis, A.P. Bozopoulos, J. Mrozinski, P. Rentzeperis, and C.A. Tsipis Inorg. Chem. 27 1988 529
51. E.G. Bakalbassis, C.A. Tsipis, A. Bozopoulos, W. Dreissig, H. Hartl, J. Mrozinski, and P. Rentzeperis Inorg. Chim. Acta 185 1991 113
52. M. Verdaguer, J. Gouteron, S. Jeannin, Y. Jeannin, and O. Kahn Inorg. Chem. 23 1984 429
53. A.W. Addison, T.N. Rao, J. Reedijk, J. van Rijn, and C.G. Verschoor J. Chem. Soc. Dalton Trans. 1984 1349
54. (ii):
55. J.J. Borrás-Almenar, J.M. Clemente-Juan, E. Coronado, and B.S. Tsukerblat J. Comput. Chem. 22 2001 985 Inorg. Chem. 38 1999 6081
56. Program 66, Quantum Chemistry Program Exchange 1986 Indiana University Bloomington, IN
57. G.B. Deacon, and R.J. Phillips Coord. Chem. Rev. 33 1980 227
58. M. Melnik Coord. Chem. Rev. 36 1981 1
59. M. Kato, and Y. Muto Coord. Chem. Rev. 92 1988 45
60. C. Oldham G. Wilkinson, R.D. Gillard, J.A. McCleverty, Comprehensive Coordination Chemistry 1987 Pergamon Press Oxford 435 vol 2
61. K.K. Nanda, A.W. Addison, E. Sinn, and L.K. Thompson Inorg. Chem. 35 1996 5966
62. E.G. Bakalbassi, C.A. Tsipis, A. Bozopoulos, W. Dreissing, H. Harti, and J. Mrozinski Inorg. Chim. Acta 186 1991 113
63. R. Carling, K. Kopinga, O. Kahn, and M. Verdaguer Inorg. Chem. 25 1986 1786
64. E. Colacio, M. Ghazi, R. Kivekas, and J.M. Moreno Inorg. Chem. 39 2000 2882
65. C. Ruiz-Pérez, J. Sanchiz, M.H. Molina, F. Lloret, and M. Julve Inorg. Chem. 39 2000 1363
66. C. Ruiz-Pérez, M. Hernández-Molina, P. Lorenzo-Luis, F. Lloret, J. Cano, and M. Julve Inorg. Chem. 39 2000 3845
67. Y. Rodríguez-Martín, C. Ruiz-Pérez, J. Sanchiz, F. Lloret, and M. Julve Inorg. Chim. Acta 318 2001 159
68. D.K. Towle, S.K. Hoffmann, W.E. Hatfield, P. Singh, and P. Chaudhuri Inorg. Chem. 27 1988 394
69. E. Colacio, J.P. Costes, R. Kivekas, J.P. Laurent, and J. Ruiz Inorg. Chem. 29 1990 4240
70. E. Colacio, J.M. Domínguez-Vera, J.P. Costes, R. Kivekas, J.P. Laurent, J. Ruiz, and M. Sundberg Inorg. Chem. 31 1992 774
71. E. Colacio, J.M. Domínguez-Vera, M. Ghazi, R. Kivekas, M. Klinga, and J.M. Moreno Eur. J. Inorg. Chem. 1999 441 and references therein.
72. M. Murugesu, R. Clérac, B. Pilawa, A. Mandel, C.E. Anson, and A.K. Powell Inorg. Chim. Acta 337 2002 328
73. A. Rodríguez-Fortea, P. Alemany, S. Alvarez, and E. Ruiz Chem. Eur. J. 7 2001 627