Ferromagnetic interactions mediated by syn-anti carboxylate bridging in tetranuclear copper(II) compounds

Inorganica Chimica Acta

Volumn 337, Issue , 2002, Pages 328-336

  Murugesu, Muralee ^a   Clérac, Rodolphe ^b   Pilawa, Bernd ^a   Mandel, Alexander ^c   Anson, Christopher E ^a   Powell, Annie K ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

^b CNRS   (France)

^c UNIVERSITY OF EAST ANGLIA   (United Kingdom)

Author keywords

Antiferromagnetic interactions; Carboxylate bridging modes; Copper complexes; Ferromagnetic interactions

Indexed keywords

ANTIFERROELECTRICITY; ANTIFERROMAGNETISM; CARBOXYLATION; FERROMAGNETIC MATERIALS; FERROMAGNETISM; GROUND STATE; LIGANDS; PROPIONIC ACID; VOLATILE FATTY ACIDS;

ANTIFERRO-MAGNETIC INTERACTIONS; ANTIFERROMAGNETIC COUPLING; ANTIFERROMAGNETICS; BRIDGING MODE; COPPER COMPLEXES; FERRO-MAGNETIC INTERACTIONS; TETRANUCLEAR COMPOUNDS; TRIDENTATE LIGANDS;

COPPER COMPOUNDS;

ACETIC ACID; CARBOXYLIC ACID DERIVATIVE; COPPER COMPLEX; FERROMAGNETIC MATERIAL; OXYGEN; PROPIONIC ACID DERIVATIVE;

ARTICLE; CHEMICAL BOND; GEOMETRY; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; SYNTHESIS;

EID: 0037179979     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01083-6     Document Type: Article

References (37)

1. Bleaney B., Bowers K.D. Proc. R. Soc. London, A. 214:1952;451.
2. J. Lewis, F.E. Mabbs, L.K. Royston, W.R. Smail, J. Chem. Soc., A (1969) 291.
3. R.L. Martin, R.J. Watermann, J. Chem. Soc. (1957) 2545.
4. Costes P.J., Dahan F., Laurent J.P. Inorg. Chem. 24:1985;1018.
5. Costa-Filho A.J., Nascimento O.R., Ghivelder L., Calvo R. J. Phys. Chem. B. 105:2001;5039.
6. E. Colacio, J.M. Dominguez-Vera, M. Ghazi, R. Kivekäs, M. Klinga, J.M. Moreno, Eur. J. Inorg. Chem. (1999) 441.
7. Colacio E., Dominguez-Vera J.M., Kivekäs R., Moreno J.M., Romerosa A., Ruiz J. Inorg. Chim. Acta. 212:1993;115.
8. Colacio E., Costes J.P., Kivekäs R., Laurent J.P., Ruiz J. Inorg. Chem. 29:1990;4240.
9. H. Zhang, D. Fu, F. Ji, G. Wang, K. Yu, T. Yao, J. Chem. Soc., Dalton Trans. (1996) 3799.
10. Colacio E., Ghazi M., Kivekäs R., Moreno J.M. Inorg. Chem. 39:2000;2882.
11. Wang Q., Wu X., Lin P., Zhang W., Sheng T., Yu H., Chen L., Li J. Polyhedron. 18:1999;1411.
12. Ahlgren M., Turpeinen U., Hämäläinen R. Acta Crystallogr., B. 38:1982;429.
13. J. Rojo, J.M. Lehn, G. Baum, D. Fenske, O. Waldmann, P. Müller, Eur. J. Inorg. Chem. (1999) 517.
14. Z. Xu, L.K. Thompson, D.O. Miller, Chem. Commun. (2001) 1170.
15. Matthews C.J., Avery K., Xu Z., Thompson L.K., Zhao L., Miller D.O., Poirier K., Zaworotko M.J., Wilson C., Goeta A.E., Howard J.A.K. Inorg. Chem. 38:1999;5266.
16. Nanda K.K., Addison A.W., Sinn E., Thompson L.K. Inorg. Chem. 35:1996;5966.
17. Schultz D., Weyhermüller T., Wieghardt K., Butzlaff C., Trautwein A.X. Inorg. Chem. Acta. 247:1996;387.
18. Sen S., Saha M.K., Gupta T., Karmaker A.K., Kundu P., Mitra S., Hursthouse M.B., Malik K.M. J. Chem. Crystallogr. 28:1998;771.
19. M. Murugesu, M.Sc. thesis, University of East Anglia, UK, 1998.
20. Roman-Alpiste M.J., Martin-Ramos J.D., Castineiras-Campos A., Bugella-Altamirano E., Sicilia-Zafra A.G., Gonzalez-Perez J.M., Niclos-Gutierrez J. Polyhedron. 18:1999;3341.
21. Wang Q., Wu X., Zhang W., Sheng T., Lin P., Li J. Inorg. Chem. 38:1999;2223.
22. Whitlow S.H. Inorg. Chem. 12:1973;2286.
23. Boudreaux E.A., Mulay L.N., Theory and Applications of Molecular Paramagnetism. 1976;Wiley, New York.
24. G.M. Sheldrick, SHELXTL-NT 5.1, Bruker AXS Inc., Madison, WI, USA, 1997.
25. Ruiz-Perez C., Sanchiz J., Hernandez-Molina M., Lloret F., Julve M. Inorg. Chem. 39:2000;1363.
26. Towle D.K., Hoffmann S.K., Hatfield W.E., Singh P., Chaudhuri P. Inorg. Chem. 27:1988;394.
27. Colacio E., Dominguez-Vera J.M., Costes J.P., Kivekas R., Laurent J.P., Ruiz J., Sundberg M. Inorg. Chem. 31:1992;774.
28. Carlin R.L. Magnetochemistry. 1986;Springer, Berlin.
29. 4 rectangles present in the solid state.
30. Kambe K. Phys. Soc. Jpn. 5:1950;48.
31. Jotham R.W., Kettle S.F.A. Inorg. Chim. Acta. 4:1970;145.
32. Kolks G., Lippard S.J., Waszczak J.V., Lilienthal H.R. J. Am. Chem. Soc. 104:1983;717.
33. Berry K.J., Clark P.E., Murray K.S., Raston C.L., White A.H. Inorg. Chem. 22:1983;3920.
34. 4 rectangles present in the solid state.
35. Myers B.E., Berger L., Friedberg S. J. Appl. Phys. 40:1969;1149.
36. Marsh W.E., Patel K.C., Hatfield W.E., Hodgson D.J. Inorg. Chem. 22:1982;511.
37. B=+9 K and g=2.17. At lower temperature this model cannot be used in a satisfactory manner.