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0000268007
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Absolute rate constants for the self-termination of the isopropyl radical and for the decarbonylation of the 2-methylpropanoyl radical
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79952840430
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This was checked by separate measurements of temperature inside NMR tube
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This was checked by separate measurements of temperature inside NMR tube.
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31
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36048986067
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Interaction of monomer radicals with nitroxides: A new access to the radical-radical combination rate constants
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Lalevée, J.; Gigmes, D.; Bertin, D.; Allonas, X.; Fouassier, J.P. Interaction of monomer radicals with nitroxides: A new access to the radical-radical combination rate constants. Chem. Phys. Lett. 2007, 449, 231-235.
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32
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79952839792
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This value was given for the tert-butyl group. It was assumed no effect from the para nitro phenyl group
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This value was given for the tert-butyl group. It was assumed no effect from the para nitro phenyl group.
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33
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29744433926
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Reactivity of Phosphorus Centered Radicals
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It is known that topological rearrangements occur in RP leading that RP in the same or different spin states afford different products of reaction. Thus, although the geminate singlet and triplet RPs, and the diffusion RPs involves the same radical species and are locate on the same pathway, they might exhibit different topology leading to different occurrence of the intermolecular H-transfer reaction. An example of different reactivity of RP is provided
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It is known that topological rearrangements occur in RP leading that RP in the same or different spin states afford different products of reaction. Thus, although the geminate singlet and triplet RPs, and the diffusion RPs involves the same radical species and are locate on the same pathway, they might exhibit different topology leading to different occurrence of the intermolecular H-transfer reaction. An example of different reactivity of RP is provided in: Marque, S.; Tordo, P. Reactivity of Phosphorus Centered Radicals. Top. Curr. Chem. 2005, 250, 44-76.
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Marque, S.1
Tordo, P.2
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