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The LF at high conversion (ca. 70%), that is, long time, were lower than expected, that is, 61, and 18% for entries 1 and 3 in Table 3, respectively. The low LF observed for 20e (43% at 43% conversion) might be due to some instability of 20e under our experimental conditions.
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The LF at high conversion (ca. 70%), that is, long time, were lower than expected, that is, 61, and 18% for entries 1 and 3 in Table 3, respectively. The low LF observed for 20e (43% at 43% conversion) might be due to some instability of 20e under our experimental conditions.
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The efficiency of the ge as initiating alkyl radical when DPAIO-g was used for the NMP of MMA pointed out that intra-molecular radical reaction did not occur or to a negligible extend. Furthermore, the high amount of alkene generated during the thermal decomposition of 17g in the absence of scavenger confirmed the very low level of occurrence for the intra-molecular radical cyclization. In a paper in preparation, we describe the occurrence of H-transfer for THM-PO-g and showed that initiation of NMP of styrene occurred but with efficiency smaller than 1. Personal communication of the authors.
-
The efficiency of the ge as initiating alkyl radical when DPAIO-g was used for the NMP of MMA pointed out that intra-molecular radical reaction did not occur or to a negligible extend. Furthermore, the high amount of alkene generated during the thermal decomposition of 17g in the absence of scavenger confirmed the very low level of occurrence for the intra-molecular radical cyclization. In a paper in preparation, we describe the occurrence of H-transfer for THM-PO-g and showed that initiation of NMP of styrene occurred but with efficiency smaller than 1. Personal communication of the authors.
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74
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0037161420
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A. Goto, Y. Kwak, C. Yoshikawa, Y. Tsujii, Y. Sugiura, T. Fukuda, Macromolecules, 2002, 35, 3520.
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(2002)
Macromolecules
, vol.35
, pp. 3520
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Goto, A.1
Kwak, Y.2
Yoshikawa, C.3
Tsujii, Y.4
Sugiura, Y.5
Fukuda, T.6
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76
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-
55349130578
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-1), even at room temperature.
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-1), even at room temperature.
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-
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77
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55349130918
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Several papers dealing with the importance of the H-transfer reaction in the cases of TEMPO-, DPAIO-, SGl-, imidazoline, and imidazole nitroxides based alkoxyamines are in preparation.
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Several papers dealing with the importance of the H-transfer reaction in the cases of TEMPO-, DPAIO-, SGl-, imidazoline, and imidazole nitroxides based alkoxyamines are in preparation.
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-
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78
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55349102966
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Impurities observed between the vinylic protons are likely due to the degradation of the hydroxylamine, which is probably not stable under our conditions
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Impurities observed between the vinylic protons are likely due to the degradation of the hydroxylamine, which is probably not stable under our conditions.
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79
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55349146882
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Hydroxylamine may also play the role of inhibitor and quenched the polymerization
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Hydroxylamine may also play the role of inhibitor and quenched the polymerization.
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-
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80
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-
55349103349
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-
This reaction was questioned in ref.[79] and[80, However, preliminary results with less drastic conditions, but closer to the polymerization conditions, show that the occurrence of this reaction is very low and should not impede the polymerization
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[80]. However, preliminary results with less drastic conditions, but closer to the polymerization conditions, show that the occurrence of this reaction is very low and should not impede the polymerization.
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81
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33750083334
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P. B. Zetterlund, Y. Saka, R. McHale, T. Nakamura, F. Aldabbagh, M. Okubo, Polymer 2006, 47, 7900.
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(2006)
Polymer
, vol.47
, pp. 7900
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Zetterlund, P.B.1
Saka, Y.2
McHale, R.3
Nakamura, T.4
Aldabbagh, F.5
Okubo, M.6
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82
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34249814304
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R. McHale, F. Aldabbagh, P. B. Zetterlung, J. Polym. Chem., Part A: Polym. Chem. 2007, 45, 2194.
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(2007)
J. Polym. Chem., Part A: Polym. Chem
, vol.45
, pp. 2194
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McHale, R.1
Aldabbagh, F.2
Zetterlung, P.B.3
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