Chemistry of soluble β-diketiminatoalkaline-earth metal complexes with M-X Bonds (M = Mg, Ca, Sr; X = OH, Halides, H)

Accounts of Chemical Research

Volumn 44, Issue 3, 2011, Pages 157-170

  Sarish, Sankaranarayana Pillai ^a   Nembenna, Sharanappa ^a   Nagendran, Selvarajan ^b   Roesky, Herbert W ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

^b INDIAN INSTITUTE OF TECHNOLOGY DELHI   (India)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 79952841580     PISSN: 00014842     EISSN: 15204898     Source Type: Journal    
DOI: 10.1021/ar100103h     Document Type: Article

References (42)

1. Harder, S. From Limestone to Catalysis: Application of Calcium Compounds as Homogeneous Catalysts Chem. Rev. 2010, 110, 3852-3876
2. Westerhausen, M. Recent Developments in the Organic Chemistry of Calcium-An Element with Unlimited Possibilities in Organometallic Chemistry? Z. Anorg. Allg. Chem. 2009, 635, 13-32
3. Buchanan, W. D.; Allis, D. G.; Ruhlandt-Senge, K. Synthesis and Stabilization-Advances in Organoalkaline Earth Metal Chemistry Chem. Commun. 2010, 46, 4449-4465
4. Barrett, A. G. M.; Crimmin, M. R.; Hill, M. S.; Procopiou, P. A. Heterofunctionalization Catalysis with Organometallic Complexes of Calcium, Strontium, and Barium Proc. R. Soc.. 2010, 466, 927-963
5. Bourget-Merle, L.; Lappert, M. F.; Severn, J. R. The Chemistry of β-Diketiminatometal Complexes Chem. Rev. 2002, 102, 3031-3065
6. Cotton, F. A.; Wilkinson, E.; Murillo, C. A.; Bochmann, M. Advanced Inorganic Chemistry, 6 th ed.; John Wiley & Sons: New York, 1999; pp 1302 - 1304.
7. Sánchez-Barba, L. F.; Hughes, D. L.; Humphrey, S. M.; Bochmann, M. Ligand Transfer Reactions of Mixed-Metal Lanthanide/Magnesium Allyl Complexes with β-Diketimines: Synthesis, Structures, and Ring-Opening Polymerization Catalysis Organometallics 2006, 25, 1012-1020
8. Nembenna, S.; Singh, S.; Roesky, H. W.; Ott, H.; Stalke, D.; Noltemeyer, M. β-Diketiminate Ligand Stabilized Magnesium Hydroxide, Heterobimetallic, and Halide Complexes; Synthesis and X-ray Structural Studies Z. Anorg. Allg. Chem. 2010, DOI: 10.1002/zaac.201000348
9. Ruspic, C.; Nembenna, S.; Hofmeister, A.; Magull, J.; Harder, S.; Roesky, H. W. A Well-Defined Hydrocarbon-Soluble Calcium Hydroxide: Synthesis, Structure, and Reactivity J. Am. Chem. Soc. 2006, 128, 15000-15004 (Pubitemid 44851641)
10. Sarish, S.; Nembenna, S.; Nagendran, S.; Roesky, H. W.; Pal, A.; Herbst-Irmer, R.; Ringe, A.; Magull, J. A Reactivity Change of a Strontium Monohydroxide by Umpolung to an Acid Inorg. Chem. 2008, 47, 5971-5977
11. 2• toluene J. Fluorine Chem. 2002, 115, 143-147
12. 2]: The Application of Soluble Calcium Derivatives for Surface Coating Angew. Chem., Int. Ed. 2007, 46, 2512-2514 (Pubitemid 46978154)
13. Barrett, A. G. M.; Crimmin, M. R.; Hill, M. S.; Hitchcock, P. B.; Procopiou, P. A. Trifluoromethyl Coordination and C-F Bond Activation at Calcium Angew. Chem., Int. Ed. 2007, 46, 6339-6342 (Pubitemid 47329431)
14. 2L] Chem. Commun. 2009, 2390-2392
15. Smith, J. M.; Lachicotte, R. J.; Holland, P. L. Tuning Metal Coordination Number by Ancillary Ligand Steric Effects: Synthesis of a Three-Coordinate Iron(II) Complex Chem. Commun. 2001, 1542-1543 (Pubitemid 32812014)
16. Dove, A. P.; Gibson, V. C.; Hormnirun, P.; Marshall, E. L.; Segal, J. A.; White, A. J. P.; Williams, D. J. Low Coordinate Magnesium Chemistry Supported by a Bulky β-Diketiminate Ligand Dalton Trans. 2003, 3088-3097 (Pubitemid 41283491)
17. Ruspic, C.; Harder, S. Big Ligands for Stabilization of Small Functionalities in Calcium Chemistry Inorg. Chem. 2007, 46, 10426-10433
18. IBr Molecule in a Sandwich-Like Structure Organometallics 2002, 21, 2590-2592
19. Neculai, A.-M.; Cummins, C. C.; Neculai, D.; Roesky, H. W.; Bunkòczi, G.; Walfort, B.; Stalke, D. Elucidation of a Sc(I) Complex by DFT Calculations and Reactivity Studies Inorg. Chem. 2003, 42, 8803-8810
20. Prust, J.; Most, K.; Müller, I.; Alexopoulos, E.; Stasch, A.; Usón, I.; Roesky, H. W. Synthesis and Structures of β-Diketoiminate Complexes of Magnesium Z. Anorg. Allg. Chem. 2001, 627, 2032-2037
21. Bonyhady, S. J.; Jones, C.; Nembenna, S.; Stasch, A.; Edwards, A. J.; McIntyre, G. J. β -Diketiminate-Stabilized Magnesium(I) Dimers and Magnesium(II) Hydride Complexes: Synthesis, Characterization, Adduct Formation, and Reactivity Studies Chem.- Eur. J. 2010, 16, 938-955
22. El-Kaderi, H. M.; Heeg, M. J.; Winter, C. H. Complexes of the Heavier Alkaline Earth Metals Containing β-Diketiminato and Iodide Ligand Sets Polyhedron 2006, 25, 224-234
23. Sarish, S. P.; Jana, A.; Roesky, H. W.; Schulz, T.; John, M.; Stalke, D. Heavier Alkaline Earth Metal Borohydride Complexes Stabilized by β-Diketiminate Ligand Inorg. Chem. 2010, 49, 3816-3820
24. 2+ Chain Stabilized by Two Chelating β -Diketiminate Ligands Organometallics 2010, 29, 2901-2903
25. Green, S. P.; Jones, C.; Stasch, A. Stable Magnesium(I) Compounds with Mg-Mg Bonds Science 2007, 318, 1754-1757 (Pubitemid 350274380)
26. Sarish, S. P.; Nembenna, S.; Roesky, H. W.; Ott, H.; Pal, A.; Stalke, D.; Dutta, S.; Pati, S. K. Soluble Molecular Dimers of CaO and SrO Stabilized by a Lewis Acid Angew. Chem., Int. Ed. 2009, 48, 8740-8742
27. Harder, S.; Brettar, J. Rational Design of a Well-Defined Soluble Calcium Hydride Complex Angew. Chem., Int. Ed. 2006, 45, 3474-3478 (Pubitemid 44098960)
28. Green, S. P.; Jones, C.; Stasch, A. Stable Adducts of a Dimeric Magnesium(I) Compound Angew. Chem., Int. Ed. 2008, 47, 9079-9083
29. Jana, A.; Ghoshal, D.; Roesky, H. W.; Objartel, I.; Schwab, G.; Stalke, D. A Germanium(II) Hydride as an Effective Reagent for Hydrogermylation Reactions J. Am. Chem. Soc. 2009, 131, 1288-1293
30. 2 and Epoxides: Catalyst Synthesis and Unprecedented Polymerization Activity J. Am. Chem. Soc. 2001, 123, 8738-8749 (Pubitemid 32852674)
31. 2. A Comparative Study Inorg. Chem. 2002, 41, 2785-2794
32. Hao, H.; Cui, C.; Roesky, H. W.; Bai, G.; Schmidt, H.-G.; Noltemeyer, M. Syntheses and Structures of the First Examples of Zinc Compounds with Bridging Fluorine and Hydrogen Atoms Chem. Commun. 2001, 1118-1119 (Pubitemid 32553661)
33. Schulz, S.; Eisenmann, T.; Westphal, U.; Schmidt, S.; Flörke, U. Synthesis and Characterization of β-Diketiminate Zinc Complexes Z. Anorg. Allg. Chem. 2009, 635, 216-220
34. Prust, J.; Stasch, A.; Zheng, W.; Roesky, H. W.; Alexopoulos, E.; Usón, I.; Böhler, D.; Schuchardt, T. Synthesis and Structural Characterization of Monomeric Three-Coordinated β -Diketoiminate Organozinc Derivatives Organometallics 2001, 20, 3825-3828 (Pubitemid 35349023)
35. tBu, N-2,6-diisopropylphenyl)imine BDI*H Dalton Trans. 2009, 9237-9245
36. Varonka, M. S.; Warren, T. H. S-Nitrosothiol and Nitric Oxide Reactivity at β-Diketiminato Zinc Thiolates Inorg. Chim. Acta 2007, 360, 317-328
37. Prust, J.; Hohmeister, H.; Stasch, A.; Roesky, H. W.; Magull, J.; Alexopoulos, E.; Usón, I.; Schmidt, H.-G.; Noltemeyer, M. Synthesis and Structural Characterization of β-Diketoiminate Complexes Containing Three-Coordinate Zinc and Copper Atoms Eur. J. Inorg. Chem. 2002, 2156-2162
38. Bonello, O.; Jones, C.; Stasch, A.; Woodul, W. D. Group 2 and 12 Metal Gallyl Complexes Containing Unsupported Ga-M Covalent Bonds (M = Mg, Ca, Sr, Ba, Zn, Cd) Organometallics 2010, 29, 4914-4922
39. II Iodine Derivatives Eur. J. Inorg. Chem. 2001, 1613-1616 (Pubitemid 32525350)
40. Resa, I.; Carmona, E.; Gutierrez-Puebla, E.; Monge, A. Decamethyldizincocene, a Stable Compound of Zn(I) with a Zn-Zn Bond Science 2004, 305, 1136-1138 (Pubitemid 39100322)
41. 2CH]): Synthesis, Structure and Computations J. Am. Chem. Soc. 2005, 127, 11944-11945 (Pubitemid 41233711)
42. Spielmann, J.; Piesik, D.; Wittkamp, B.; Jansen, G.; Harder, S. Convenient Synthesis and Crystal Structure of a Monomeric Zinc Hydride Complex with a Three-Coordinate Metal Center Chem. Commun. 2009, 3455-3456