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53249115651
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11
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0037467050
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2-, have been determined. See for example: M. Y. Redko, R. H. Huang, J. E. Jackson, J. F. Harrison, J. L. Dye, J. Am. Chem. Soc. 2003, 125, 2259-2263.
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2-, have been determined. See for example: M. Y. Redko, R. H. Huang, J. E. Jackson, J. F. Harrison, J. L. Dye, J. Am. Chem. Soc. 2003, 125, 2259-2263.
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34748813719
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See for example: a
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See for example: a) A. Velazquez, I. Fernandez, G. Frenking, G. Merino, Organometallics 2007, 26, 4731-4736;
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18
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56249138060
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In contrast, colorless THF solutions of compound 1 slowly decompose at room temperature, depositing magnesium metal.
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In contrast, colorless THF solutions of compound 1 slowly decompose at room temperature, depositing magnesium metal.
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19
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56249138763
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3. C. Reichardt, Solvents and Solvent Effects in Organic Chemistry, 3rd ed., Wiley-VCH, Weinheim, 2003.
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3. C. Reichardt, Solvents and Solvent Effects in Organic Chemistry, 3rd ed., Wiley-VCH, Weinheim, 2003.
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20
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56249086254
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As determined from a survey of the Cambridge Crystallographic Database, August
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As determined from a survey of the Cambridge Crystallographic Database, August, 2008.
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21
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56249102244
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During the course of this study, a polymorph of 2 was crystallized and crystallographically characterized (see the Supporting Information). Its Mg-Mg distance was measured at 2.8624(15) Å.
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During the course of this study, a polymorph of 2 was crystallized and crystallographically characterized (see the Supporting Information). Its Mg-Mg distance was measured at 2.8624(15) Å.
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22
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56249120768
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2] (L = THF, dioxane, DMAP, or 4-tBuPy). It is believed that the presence of these co-crystallized contaminants has a significant, though not substantial, effect on the Mg-Mg bond lengths observed for 3-6. See the Supporting Information for a full discussion on this point.
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2] (L = THF, dioxane, DMAP, or 4-tBuPy). It is believed that the presence of these co-crystallized contaminants has a significant, though not substantial, effect on the Mg-Mg bond lengths observed for 3-6. See the Supporting Information for a full discussion on this point.
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a) J. Emsley, The Elements, 2nd ed., Clarendon, Oxford, 1995;
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The effect of the steric bulk of β-diketiminate ligands upon the planarity of their metallacyclic complexes has been noted previously: P. B. Hitchcock, M. F. Lappert, D.-S. Liu, J. Chem. Soc. Chem. Commun. 1994, 1699-1700
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The effect of the steric bulk of β-diketiminate ligands upon the planarity of their metallacyclic complexes has been noted previously: P. B. Hitchcock, M. F. Lappert, D.-S. Liu, J. Chem. Soc. Chem. Commun. 1994, 1699-1700.
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33
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0037148807
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Anionic examples have been structurally characterized. See for example
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Anionic examples have been structurally characterized. See for example: D. J. Gallagher, K. W. Henderson, A. R. Kennedy, C. T. O'Hara, R. E. Mulvey, R. B. Rowlings, Chem. Commun. 2002, 376-377.
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34
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0008544550
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2] (R = amide, alkyl, etc.) have been previously prepared, though not structurally characterized. See for example: E. C. Ashby, A. B. Goel, Inorg. Chem. 1978, 17, 1862-1866.
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2] (R = amide, alkyl, etc.) have been previously prepared, though not structurally characterized. See for example: E. C. Ashby, A. B. Goel, Inorg. Chem. 1978, 17, 1862-1866.
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