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Volumn 47, Issue 47, 2008, Pages 9079-9083

Stable adducts of a dimeric magnesium(I) compound

Author keywords

Low oxidation states; Magnesium; Metal hydrides; Metal metal bonding; Structure elucidation

Indexed keywords

HYDRIDES; HYDROGEN; LIGHT METALS; MAGNESIUM; STRUCTURAL METALS;

EID: 56249147796     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200803960     Document Type: Article
Times cited : (213)

References (34)
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    • 2-, have been determined. See for example: M. Y. Redko, R. H. Huang, J. E. Jackson, J. F. Harrison, J. L. Dye, J. Am. Chem. Soc. 2003, 125, 2259-2263.
    • 2-, have been determined. See for example: M. Y. Redko, R. H. Huang, J. E. Jackson, J. F. Harrison, J. L. Dye, J. Am. Chem. Soc. 2003, 125, 2259-2263.
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    • In contrast, colorless THF solutions of compound 1 slowly decompose at room temperature, depositing magnesium metal.
    • In contrast, colorless THF solutions of compound 1 slowly decompose at room temperature, depositing magnesium metal.
  • 19
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    • 3. C. Reichardt, Solvents and Solvent Effects in Organic Chemistry, 3rd ed., Wiley-VCH, Weinheim, 2003.
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    • As determined from a survey of the Cambridge Crystallographic Database, August
    • As determined from a survey of the Cambridge Crystallographic Database, August, 2008.
    • (2008)
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    • During the course of this study, a polymorph of 2 was crystallized and crystallographically characterized (see the Supporting Information). Its Mg-Mg distance was measured at 2.8624(15) Å.
    • During the course of this study, a polymorph of 2 was crystallized and crystallographically characterized (see the Supporting Information). Its Mg-Mg distance was measured at 2.8624(15) Å.
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    • 2] (L = THF, dioxane, DMAP, or 4-tBuPy). It is believed that the presence of these co-crystallized contaminants has a significant, though not substantial, effect on the Mg-Mg bond lengths observed for 3-6. See the Supporting Information for a full discussion on this point.
    • 2] (L = THF, dioxane, DMAP, or 4-tBuPy). It is believed that the presence of these co-crystallized contaminants has a significant, though not substantial, effect on the Mg-Mg bond lengths observed for 3-6. See the Supporting Information for a full discussion on this point.
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    • The effect of the steric bulk of β-diketiminate ligands upon the planarity of their metallacyclic complexes has been noted previously: P. B. Hitchcock, M. F. Lappert, D.-S. Liu, J. Chem. Soc. Chem. Commun. 1994, 1699-1700
    • The effect of the steric bulk of β-diketiminate ligands upon the planarity of their metallacyclic complexes has been noted previously: P. B. Hitchcock, M. F. Lappert, D.-S. Liu, J. Chem. Soc. Chem. Commun. 1994, 1699-1700.
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    • 2] (R = amide, alkyl, etc.) have been previously prepared, though not structurally characterized. See for example: E. C. Ashby, A. B. Goel, Inorg. Chem. 1978, 17, 1862-1866.
    • 2] (R = amide, alkyl, etc.) have been previously prepared, though not structurally characterized. See for example: E. C. Ashby, A. B. Goel, Inorg. Chem. 1978, 17, 1862-1866.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.