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[(dipp)NacNacH] has been proved to be a good ligand suitable for main group metals and has led to several interesting results. (a) First monomeric three-coordinated β-diketoiminate magnesium compound was synthesized: Gibson, V. C.; Segal, J. A.; White, A. J. P.; Williams, D. J. J. Am. Chem. Soc. 2000, 122, 7120-7121.
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First monomeric aluminum(I) compound with β-diketoiminate ligand was synthesized: Cui, C.; Roesky, H. W.; Schmidt, H.-G.; Noltemeyer, M.; Hao, H.; Cimpoesu, F. Angew. Chem. 2000, 112, 4444-4446
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