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Volumn 44, Issue 6, 2011, Pages 1570-1584

Entanglement dynamics in miscible polyisoprene/poly(p-tert-butylstyrene) blends

Author keywords

[No Author keywords available]

Indexed keywords

ANGULAR FREQUENCIES; CIS-POLYISOPRENE; COMPLEX MODULUS; CONSTRAINT RELEASE; DIELECTRIC DATA; ENTANGLEMENT DYNAMICS; EQUILIBRATION TIME; GLOBAL MOTION; HIGH-T; KUHN SEGMENT; LOSS MODULI; MISCIBLE BLEND; MIXING RULES; MODEL CALCULATIONS; MOLECULAR PICTURES; POWER-LAW BEHAVIOR; RHEO-OPTICAL; STORAGE MODULI;

EID: 79952753960     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma102596b     Document Type: Article
Times cited : (25)

References (65)
  • 39
    • 34547723170 scopus 로고    scopus 로고
    • Chain Dimensions and Entanglement Spacings
    • Mark J.E. In, 2 nd ed.;, Ed.; Springer: New York,; Chapter 25
    • Fetters, L. J.; Lohse, D. J.; Colby, R. H. Chain Dimensions and Entanglement Spacings. In Physical Properties of Polymers Handbook, 2 nd ed.; Mark, J. E., Ed.; Springer: New York, 2007; Chapter 25, pp 445 - 452.
    • (2007) Physical Properties of Polymers Handbook , pp. 445-452
    • Fetters, L.J.1    Lohse, D.J.2    Colby, R.H.3
  • 47
    • 79952764488 scopus 로고    scopus 로고
    • Within the context of the tube model, the PI relaxation in the blends at high T occurs in the fixed entanglement mesh formed by the slow PtBS chains as well as by the PI chains themselves
    • Within the context of the tube model, the PI relaxation in the blends at high T occurs in the fixed entanglement mesh formed by the slow PtBS chains as well as by the PI chains themselves.
  • 50
    • 79952772058 scopus 로고    scopus 로고
    • note
    • PtBS.
  • 63
    • 79952763035 scopus 로고    scopus 로고
    • We also modified the model (eqs 12 and 13) by incorporating a minor contribution from the segmental (glassy) relaxation. The resulting model prediction remained very close to that shown in Figure 9 (solid curves).
    • We also modified the model (eqs 12 and 13) by incorporating a minor contribution from the segmental (glassy) relaxation. The resulting model prediction remained very close to that shown in Figure 9 (solid curves).
  • 64
    • 79952761750 scopus 로고    scopus 로고
    • We also attempted the rheo-optical analysis by incorporating the segmental (glassy) contribution in eq 9. The resulting component moduli were hardly different from those shown in Figure 10, parts b and c (symbols).
    • We also attempted the rheo-optical analysis by incorporating the segmental (glassy) contribution in eq 9. The resulting component moduli were hardly different from those shown in Figure 10, parts b and c (symbols).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.