The isotropic remnant of the CO2 near-fully depolarized Raman 23 overtone

Journal of Chemical Physics

Volumn 134, Issue 10, 2011, Pages

  Chrysos, M ^a   Verzhbitskiy, I A ^a   Rachet, F ^a   Kouzov, A P ^b  

^a UNIVERSITÉ D'ANGERS   (France)

^b ST PETERSBURG STATE UNIVERSITY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

ANISOTROPY;

AB INITIO PREDICTION; ANISOTROPIC SPECTRA; ISOTROPIC SPECTRA; POLARIZABILITIES; RAMAN LINES;

CARBON DIOXIDE;

EID: 79952656787     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3557820     Document Type: Article

References (42)

1. S. Califano, Vibrational states (Wiley, New York, 1976).
2. B. P. Stoicheff, Can. J. Phys. 35, 730 (1957). 10.1139/p57-079
3. B. P. Stoicheff, Can. J. Phys. 36, 218 (1958). 10.1139/p58-026
4. B. P. Stoicheff, in Advances in Spectroscopy, edited by, H. W. Thompson, (Wiley-Interscience, New York, 1959), Vol. 1, pp. 91-174.
5. A. Weber, in The Raman Effect, edited by, A. Anderson, (Marcel Dekker, New York, 1973), Vol. 2, pp. 543-757.
6. H. Finsterhlzl, H. W. Klckner, K. Srinivasan, H. W. Schrtter, and J. Brandmüller, Indian J. Pure Appl. Phys. 16, 370 (1978). 10.1366/000370278774331161
7. H. W. Klckner, H. Finsterhlzl, K. Srinivasan, and H. W. Schrtter, Appl. Spectrosc. 32, 401 (1978). 10.1366/000370278774331161
8. H. Finsterhlzl, Ber. Bunsenges. Phys. Chem. 86, 797 (1982). 10.1002/bbpc.19820860907
9. P. Wienecke, H. Finsterhlzl, H. W. Schrtter, and J. Brandmüller, Appl. Spectrosc. 40, 70 (1986). 10.1366/0003702864815411
10. G. Tejeda, B. Maté, and S. Montero, J. Chem. Phys. 103, 568 (1995). 10.1063/1.470091
11. F. Rachet, M. Chrysos, C. Guillot-Nol, and Y. Le Duff, Phys. Rev. Lett. 84, 2120 (2000). 10.1103/PhysRevLett.84.2120
12. F. Rachet, Y. Le Duff, C. Guillot-Nol, and M. Chrysos, Phys. Rev. A 61, 062501 (2000). 10.1103/PhysRevA.61.062501
13. M. Chrysos, S. Dixneuf, and F. Rachet, Phys. Rev. A 80, 054701 (2009). 10.1103/PhysRevA.80.054701
14. I. A. Verzhbitskiy, M. Chrysos, F. Rachet, and A. P. Kouzov, Phys. Rev. A 81, 012702 (2010); 10.1103/PhysRevA.81.012702
15. M. Chrysos and I. A. Verzhbitskiy, Phys. Rev. A 81, 042705 (2010); 10.1103/PhysRevA.81.042705
16. I. A. Verzhbitskiy, M. Chrysos, and A. P. Kouzov, Phys. Rev. A 82, 052701 (2010). 10.1103/PhysRevA.82.052701
17. T. Bancewicz and S. Kielich, J. Chem. Phys. 75, 107 (1981). 10.1063/1.441808
18. Useful in the understanding of the symmetry concepts treated in the present or in the preceding paper (Ref.) was the analysis reported by T. Bancewicz and S. Kielich (Ref.), about the collision-induced mechanisms in Raman scattering for nontotally symmetric vibrations. 10.1063/1.441808
19. M. F. Crawford, H. L. Welsh, and J. L. Locke, Phys. Rev. 75, 1607 (1949). 10.1103/PhysRev.75.1607
20. L. Frommhold, Adv. Chem. Phys. 46, 1 (1981). 10.1002/SERIES2007
21. L. Frommhold, Collision-induced Absorption in Gases (Cambridge University Press, Cambridge, England, 1993).
22. Collision- and Interaction-Induced Spectroscopy, edited by, G. C. Tabisz, and, M. N. Neuman, (Kluwer, Dordrecht, 1995).
23. J. P. McTague and G. Birnbaum, Phys. Rev. Lett. 21, 661 (1968). 10.1103/PhysRevLett.21.661
24. J. C. Lewis and J. Van Kranendonk, Phys. Rev. Lett. 24, 802 (1970). 10.1103/PhysRevLett.24.802
25. A. Borysow and L. Frommhold, Adv. Chem. Phys. 75, 439 (1989). 10.1002/SERIES2007
26. L. Ulivi, N. Meinander, and F. Barocchi, Phys. Rev. Lett. 75, 3094 (1995). 10.1103/PhysRevLett.75.3094
27. M. Zoppi, L. Ulivi, M. Santoro, M. Moraldi, and F. Barrochi, Phys. Rev. A 53, R1935 (1996). 10.1103/PhysRevA.53.R1935
28. Y. Le Duff, Phys. Rev. Lett. 90, 193001 (2003). 10.1103/PhysRevLett.90. 193001
29. Y. Le Duff, J. Chem. Phys. 119, 1893 (2003). 10.1063/1.1594183
30. M. Chrysos, I. A. Verzhbitskiy, F. Rachet, and A. P. Kouzov, J. Chem. Phys. 134, 044318 (2011). 10.1063/1.3535599
31. P. Atkins and J. de Paula, Atkins' Physical Chemistry, 8th ed. (Oxford University Press, UK, 2006). According to a general symmetry rule cited therein, p. 464, only totally symmetrical vibrations give rise to polarized lines in which the incident polarization is largely preserved and vibrations that are not totally symmetrical give rise to depolarized lines.
32. Proof: M0iso/(215M0ani)= -Sisod/-Sanid= -(S-76S)d/-Sd= -Sd/-Sd-76 =int-1-76.
33. D. A. Long, The Raman Effect. A Unified Treatment of the Theory of Raman Scattering by Molecules (Wiley, Chichester, UK, 2002).
34. T. D. Kolomiitsova and D. N. Shchepkin in Advances in Spectroscopy, edited by, R. J. H. Clark, and R. E. Hester (Wiley, Chichester, 1995), Vol. 23.
35. A. Haskopoulos and G. Maroulis, Chem. Phys. Lett. 417, 235 (2006). 10.1016/j.cplett.2005.10.023 (Pubitemid 41817548)
36. T. D. Kolomiitsova, A. V. Lyaptsev, and D. N. Shchepkin, Opt. and Spectrosc. 88, 648 (2000). 10.1134/1.626856
37. G. Maroulis, Chem. Phys. 291, 81 (2003). 10.1016/S0301-0104(03)00186-1
38. 2 0.754(4) a.u.
39. A. Chedin, J. Mol. Spectrosc. 76, 430 (1979). 10.1016/0022-2852(79)90236- 4
40. R. G. Gordon, J. Chem. Phys. 39, 2788 (1963). 10.1063/1.1734108
41. 2. Given the conversion factor of (Ref.), we obtain |0002||0000|=5.52(91)10-3a03 and thus 0002||00002=30(10)10-6 a06.
42. It has also been pointed out by Tejeda that the accuracy of second derivatives very much depends on each particular case, ranging from 10 to 100 (their words) (Ref., Introduction section).