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The scattering plane is the plane containing the incident light beam and the line from the center of the scattering system to the observer.
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The scattering plane is the plane containing the incident light beam and the line from the center of the scattering system to the observer.
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Note that according to Hunt's Eq. (19) [7], and upon use of the relationship γXXXX=3γXXYY, the isotropic invariant for nitrogen reads γb=115(3γZZZZ+12γXXZZ+8γXXXX), which is identical to the one given by Maroulis for this molecule [17]. However, in the case of SF6, the respective expressions given by the two authors differ from each other, namely γa=310(3γZZZZ+γXXZZ) [7] and γa= 35(γZZZZ+2γXXZZ) [16], but they both reduce to γa=γZZZZ in the atom limit (γXXZZ=γZZZZ3).
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Note that according to Hunt's Eq. (19) [7], and upon use of the relationship γ XXXX = 3 γ XXYY, the isotropic invariant for nitrogen reads γ b = 1 15 (3 γ ZZZZ + 12 γ XXZZ + 8 γ XXXX), which is identical to the one given by Maroulis for this molecule [17]. However, in the case of SF 6, the respective expressions given by the two authors differ from each other, namely γ a = 3 10 (3 γ ZZZZ + γ XXZZ) [7] and γ a = 3 5 (γ ZZZZ + 2 γ XXZZ) [16], but they both reduce to γ a = γ ZZZZ in the atom limit (γ XXZZ = γ ZZZZ 3).
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This is to be contrasted to standard rototranslational or vibrational CIS experiments with heavy gases, such as our recent work on Kr-Xe [, JCPSA6 0021-9606 10.1063/1.3200929
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This is to be contrasted to standard rototranslational or vibrational CIS experiments with heavy gases, such as our recent work on Kr-Xe [S. Dixneuf, M. Chrysos, and F. Rachet, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.3200929 131, 074304 (2009)]. There, pressures as low as a few atmospheres had been used to record CIS in the low-frequency range and had permitted the observation of a pronounced rotovibrational structure by bound and predissociating Kr-Xe dimers.
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-1/atm.
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Such a treatment could be envisioned only if a "numerical experiment" were carried out through molecular dynamics simulations to get a complete view of the motion of the particles and of the way a-b pairs scatter light in the presence of the surrounding particles.
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Such a treatment could be envisioned only if a "numerical experiment" were carried out through molecular dynamics simulations to get a complete view of the motion of the particles and of the way a - b pairs scatter light in the presence of the surrounding particles.
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0000360421
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While anisotropic intermolecular potential models have been developed for SF6-Rg [see, for instance, JCPSA6 0021-9606 10.1063/1.457781
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While anisotropic intermolecular potential models have been developed for SF 6 -Rg [see, for instance, S. M. El-Sheikh, G. C. Tabisz, and R. T. Pack, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.457781 92, 4234 (1990)], there is no anisotropic potential model available for SF 6 - N 2, even though the anisotropy of the interaction energy in the latter system is expected to be much greater than it is for the former systems. The development of an elaborated SF 6 - N 2 potential energy surface would be welcome.
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