Are asymmetric stretch Raman spectra by centrosymmetric molecules depolarized?: The 23 overtone of CO2

Journal of Chemical Physics

Volumn 134, Issue 4, 2011, Pages

  Chrysos, M ^a   Verzhbitskiy, I A ^a   Rachet, F ^a   Kouzov, A P ^b  

^a UNIVERSITÉ D'ANGERS   (France)

^b ST PETERSBURG STATE UNIVERSITY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

BINARY ALLOYS; CARBON DIOXIDE; LIGHT SCATTERING; MOLECULES; PHYSICAL CHEMISTRY; POTASSIUM ALLOYS; STRETCHING; URANIUM ALLOYS;

ANISOTROPIC SPECTRA; CENTROSYMMETRIC MOLECULES; DEPOLARIZATION RATIO; INTERMODE COUPLINGS; LIGHT SCATTERING MEASUREMENT; MECHANICAL ANHARMONICITY; STRETCH VIBRATIONS; STRETCHING VIBRATIONS;

VIBRATION ANALYSIS;

EID: 79551599972     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3535599     Document Type: Article

References (41)

1. D. A. Long, The Raman Effect. A Unified Treatment of the Theory of Raman Scattering by Molecules (John Wiley and Sons, Chichester, UK, 2002).
2. In both cases, precautions must be taken to ensure that the emitted radiation is completely unpolarized.
3. B. P. Stoicheff, in Advances in Spectroscopy, edited by, H. W. Thompson, (Wiley, New York, 1959), Vol. 1, pp. 91-174.
4. A. Weber, in The Raman Effect, edited by, A. Anderson, (Marcel Dekker, New York, 1973), Vol. 2, pp. 543-757.
5. H. W. Klckner, H. Finsterhlzl, K. Srinivasan, H.W. Schrtter, Appl. Spectrosc. 32, 401 (1978); 10.1366/000370278774331161
6. P. Wienecke, H. Finsterhlzl, H. W. Schrtter, and J. Brandmller, Appl. Spectrosc. 40, 70 (1986). 10.1366/0003702864815411
7. G. Tejeda, B. Maté, and S. Montero, J. Chem. Phys. 103, 568 (1995). 10.1063/1.470091
8. P. Atkins and J. de Paula, Atkins' Physical Chemistry, 8th ed. (Oxford University Press, UK, 2006), p. 464.
9. A totally symmetric vibration is a normal mode with all characters equal to one in the character table. This table is associated with the point group to which the molecule belongs.
10. Strictly, a line is classified as polarized if 67; if 0, the line is fully polarized. A line is classified as depolarized if =67.
11. L. Frommhold, Adv. Chem. Phys. 46, 1 (1981). 10.1002/SERIES2007
12. Collision- and Interaction-Induced Spectroscopy, edited by, G. C. Tabisz, and, M. N. Neuman, (Kluwer, Dordrecht, 1995).
13. F. Rachet, Y. Le Duff, C. Guillot-Nol, and M. Chrysos, Phys. Rev. A 61, 062501 (2000). 10.1103/PhysRevA.61.062501
14. F. Rachet, M. Chrysos, C. Guillot-Nol, and Y. Le Duff, Phys. Rev. Lett. 84, 2120 (2000); 10.1103/PhysRevLett.84.2120
15. Y. Le Duff, Phys. Rev. Lett. 90, 193001 (2003); 10.1103/PhysRevLett.90. 193001
16. J. Chem. Phys. 119, 1893 (2003); 10.1063/1.1594183
17. M. Chrysos, A. P. Kouzov, N. I. Egorova, and F. Rachet, Phys. Rev. Lett. 100, 133007 (2008); 10.1103/PhysRevLett.100.133007 (Pubitemid 351503192)
18. S. Dixneuf, M. Chrysos, and F. Rachet, J. Chem. Phys. 131, 074304 (2009). 10.1063/1.3200929
19. I. A. Verzhbitskiy, M. Chrysos, F. Rachet, and A. P. Kouzov, Phys. Rev. A 81, 012702 (2010). 10.1103/PhysRevA.81.012702
20. M. Chrysos and I. A. Verzhbitskiy, Phys. Rev. A 81, 042705 (2010). 10.1103/PhysRevA.81.042705
21. I. A. Verzhbitskiy, M. Chrysos, and A. P. Kouzov, Phys. Rev. A 82, 052701 (2010). 10.1103/PhysRevA.82.052701
22. T. Bancewicz and S. Kielich, J. Chem. Phys. 75, 107 (1981). 10.1063/1.441808
23. 2 overtone at its maximum (Refs.).
24. Y. Le Duff, A. Gharbi, and T. Othman, Phys. Rev. A 28, 2714 (1983). 10.1103/PhysRevA.28.2714
25. 2.
26. 2 in solution can be found in G. S. Devendorf, J. Phys. Chem. A 104, 11025 (2000); 10.1021/jp001802j (Pubitemid 32033027)
27. see also the seminal work by K. S. Schweizer and D. Chandler, J. Chem. Phys. 76, 2296 (1982). 10.1063/1.443302
28. R. R. Rudder and D. R. Bach, J. Opt. Soc. Am. 58, 1260 (1968). 10.1364/JOSA.58.001260
29. H. Finsterhlzl, Ber. Bunsenges. Phys. Chem. 86, 797 (1982).
30. 3 overtone., (unpublished).
31. G. Maroulis, Chem. Phys. 291, 81 (2003). 10.1016/S0301-0104(03)00186-1
32. A. Haskopoulos and G. Maroulis, Chem. Phys. Lett. 417, 235 (2006). 10.1016/j.cplett.2005.10.023 (Pubitemid 41817548)
33. L. S. Rothman, Appl. Opt. 25, 1795 (1986). 10.1364/AO.25.001795
34. 17O (0.08), generate bands that are centered at 4639.5 and 4655.2 cm -1, respectively (Ref.). Not only the signatures by these isotopomers were too feeble to be seen in the spectrum, but also their positions were too far away from the center of the recorded band (4673 cm -1) to have an effect.
35. 1.
36. M. A. Buldakov, V. N. Cherepanov, B. V. Korolev, and I. I. Matrosov, J. Mol. Spectrosc. 217, 1 (2003). 10.1016/S0022-2852(02)00012-7
37. G. Maroulis, J. Chem. Phys. 118, 2673 (2003). 10.1063/1.1535443
38. T. D. Kolomiitsova and D. N. Shchepkin, in Advances in Spectroscopy, edited by R. J. H. Clark and R. E. Hester (Wiley, Chichester, 1995), Vol. 23.
39. T. D. Kolomiitsova, A. V. Lyaptsev, and D. N. Shchepkin, Opt. Spectrosc. 88, 648 (2000). 10.1134/1.626856
40. A. Chedin, J. Mol. Spectrosc. 76, 430 (1979). 10.1016/0022-2852(79)90236- 4
41. R. G. Gordon, J. Chem. Phys. 39, 2788 (1963). 10.1063/1.1734108