A new family of 1D exchange biased heterometal single-molecule magnets: Observation of pronounced quantum tunneling steps in the hysteresis loops of quasi-linear {Mn2Ni3} clusters

Journal of the American Chemical Society

Volumn 133, Issue 10, 2011, Pages 3433-3443

  Das, Animesh ^a   Gieb, Klaus ^b   Krupskaya, Yulia ^c   Demeshko, Serhiy ^a   Dechert, Sebastian ^a   Klingeler, Rüdiger ^c   Kataev, Vladislav ^c   Büchner, Bernd ^c   Müller, Paul ^b   Meyer, Franc ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

^b UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^c IFW DRESDEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AC SUSCEPTIBILITY; ANTIFERROMAGNETICS; DC FIELD; FERROMAGNETIC EXCHANGE INTERACTION; FREQUENCY-DEPENDENT; HETEROMETALLICS; HIGH FIELD EPR; INTERMOLECULAR CONTACTS; INTERMOLECULAR INTERACTIONS; INTRAMOLECULAR HYDROGEN BOND; LOW TEMPERATURES; MAGNETIZATION DATA; OCTAHEDRAL COORDINATION; OUT OF PHASE; QUANTUM TUNNELING; QUANTUM TUNNELLING; QUASI-LINEAR; SCAN RATES; SINGLE-MOLECULE MAGNET; SLOW RELAXATIONS; SPIN REVERSAL; TEMPERATURE DEPENDENT; ZERO-CROSSINGS;

ANTIFERROMAGNETISM; COMPLEXATION; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRON TUNNELING; ETHANOL; FERROMAGNETIC MATERIALS; FERROMAGNETISM; HYDROGEN BONDS; HYSTERESIS; HYSTERESIS LOOPS; MAGNETIC FIELDS; MAGNETIC SUSCEPTIBILITY; MAGNETIZATION REVERSAL; MAGNETS; MANGANESE; METAL IONS; METALLIC COMPOUNDS; MOLECULAR STRUCTURE;

SINGLE CRYSTALS;

2 [3 (2 HYDROXYPHENYL) 1H PYRAZOL 1 YL] ETHANOL; ALCOHOL; FERROMAGNETIC MATERIAL; MANGANESE; METAL ION; NICKEL; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; HYDROGEN BOND; HYSTERESIS; MAGNET; QUANTUM CHEMISTRY; SPECTROSCOPY; SYNTHESIS; TEMPERATURE;

EID: 79952585199     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja108740c     Document Type: Article

References (78)

1. Christou, G.; Gatteschi, D.; Hendrickson, D. N.; Sessoli, R. MRS Bull. 2000, 25, 66-71
2. Chudnovsky, E. M. Science 1996, 274, 938-939
3. Gatteschi, D.; Sessoli, R. Angew. Chem. 2003, 115, 278-309
4. Affronte, M. J. Mater. Chem. 2009, 19, 1731-1737
5. Ardavan, A.; Blundell, S. J. J. Mater. Chem. 2009, 19, 1754-1760
6. Lehmann, J.; Gaita-Ariño, A.; Coronado, E.; Loss, D. J. Mater. Chem. 2009, 19, 1672-1677
7. Camarero, J.; Coronado, E. J. Mater. Chem. 2009, 19, 1687-1684
8. Bogani, L.; Wernsdorfer, W. Nat. Mater. 2008, 7, 179-186
9. Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 365, 141-143
10. Sessoli, R.; Tsai, H. L.; Schake, A. R.; Wang, S. Y.; Vincent, J. B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1993, 115, 1804-1816
11. Bagai, R.; Christou, G. Chem. Soc. Rev. 2009, 38, 1011-1026
12. Miyasaka, H.; Clérac, R.; Wernsdorfer, W.; Lecren, L.; Bonhomme, C.; Sugiura, K.-I.; Yamashita, M. Angew. Chem. 2004, 116, 2861-2865
13. Sanudo, E. C.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. Inorg. Chem. 2004, 43, 4137-4144
14. Taguchi, T.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. Inorg. Chem. 2010, 49, 199-208
15. Sun, Z.; Grant, C. M.; Castro, S. L.; Hendrickson, D. N.; Christou, G. Chem. Commun. 1998, 721-722
16. Gatteschi, D.; Sessoli, R.; Cornia, A. Chem. Commun. 2000, 725-732
17. Accorsi, S.; Barra, A.-L.; Caneschi, A.; Chastanet, G.; Cornia, A.; Fabretti, A. C.; Gatteschi, D.; Mortalo, C.; Olivieri, E.; Parenti, F.; Rosa, P.; Sessoli, R.; Sorace, L.; Wernsdorfer, W.; Zobbi, L. J. Am. Chem. Soc. 2006, 128, 4742-4755
18. Boudalis, A. K.; Sanakis, Y.; Clemente-Juan, J. M.; Donnadieu, B.; Nastopoulos, V.; Mari, A.; Coppel, Y.; Tuchagues, J.-P.; Perlepes, S. P. Chem.-Eur. J. 2008, 14, 2514-2526
19. Ako, A. M.; Mereacre, V.; Lan, Y.; Wernsdorfer, W.; Clérac, R.; Anson, C. E.; Powell, A. K. Inorg. Chem. 2010, 49, 1-3
20. Moubaraki, B.; Murray, K. S.; Hudson, T. A.; Robson, R. Eur. J. Inorg. Chem. 2008, 4525-4529
21. Murray, K. S. Aust. J. Chem. 2009, 62, 1081-1101
22. Murrie, M. Chem. Soc. Rev. 2010, 39, 1986-1995
23. Andres, H.; Basler, R.; Blake, A. J.; Cadiou, C.; Chaboussant, G.; Grant, C. M.; Güdel, H.-U.; Murrie, M.; Parsons, S.; Paulsen, C.; Semadini, F.; Villar, V.; Wernsdorfer, W.; Winpenny, R. E. P. Chem.-Eur. J. 2002, 8, 4867-4876
24. Ochsenbein, S. T.; Murrie, M.; Rusanow, E.; Stoeckli-Evans, H.; Sekine, C.; Güdel, H.-U. Inorg. Chem. 2002, 41, 5133-5140
25. Bell, A.; Aromi, G.; Teat, S. J.; Wernsdorfer, W.; Winpenny, R. E. P. Chem. Commun. 2005, 2808-2810
26. Aromi, G.; Parsons, S.; Wernsdorfer, W.; Brechin, E. K.; McInnes, E. J. L. Chem. Commun. 2005, 5038-5040
27. Milios, C. J.; Vinslava, A.; Wernsdorfer, W.; Moggach, S.; Parsons, S.; Perlepes, S. P.; Christou, G.; Brechin, E. K. J. Am. Chem. Soc. 2007, 129, 2754-2755
28. Cremades, E.; Cano, J.; Ruiz, E.; Rajaraman, G.; Milios, C. J.; Brechin, E. K. Inorg. Chem. 2009, 48, 8012-8019
29. Inglis, R.; Jones, L. F.; Milios, C. J.; Datta, S.; Collins, A.; Parsons, S.; Wernsdorfer, W.; Hill, S.; Perlepes, S. P.; Piligkos, S.; Brechin, E. K. Dalton Trans. 2009, 3403-3412
30. Gatteschi, D.; Sessolis, R.; Villain, J. Molecular Nanomagnets; Oxford University Press: New York, 2006.
31. Cirera, J.; Ruiz, E.; Alvarez, S.; Neese, F.; Kortus, J. Chem.-Eur. J. 2009, 15, 4078-4087
32. Oshio, H.; Nakano, M. Chem.-Eur. J. 2005, 11, 5178-5185
33. Waldmann, O. Inorg. Chem. 2007, 46, 10035-10037
34. Ruiz, E.; Cirera, J.; Cano, J.; Alvarez, S.; Loose, C.; Kortus, J. Chem. Commun. 2008, 52-54
35. Hill, S.; Datta, S.; Liu, J.; Inglis, R.; Milios, C. J.; Feng, P. L.; Henderson, J. J.; del Barco, E.; Brechin, E. K.; Hendrickson, D. N. Dalton Trans. 2010, 39, 4693-4707
36. Wernsdorfer, W.; Aliaga Alcalde, N.; Hendrickson, D. N.; Christou, G. Nature 2002, 416, 406-409
37. Hill, S.; Edwards, R. S.; Aliaga-Alcade, N.; Christou, G. Science 2003, 302, 1015-1018
38. Tiron, R.; Wernsdorfer, W.; Foguet-Albiol, D.; Aliaga-Alcade, N.; Christou, G. Phys. Rev. Lett. 2003, 91 (227203) 1-4
39. Yamaguchi, A.; Kusumi, N.; Ishimoto, H.; Mitamura, H.; Goto, T.; Mori, N.; Nakano, M.; Awaga, K.; Yoo, J.; Hendrickson, D. N.; Christou, G. J. Phys. Soc. Jpn. 2002, 71, 414-417
40. Affronte, M.; Lasjaunias, J. C.; Wernsdorfer, W.; Sessoli, R.; Gatteschi, D.; Heath, S. L.; Fort, A.; Rettori, A. Phys. Rev. B 2002, 66, 064408/1-064408/7
41. Asada, H.; Ozeki, M.; Fujiwara, M.; Matsushita, T. Chem. Lett. 1999, 525-526
42. Dey, M.; Rao, C. P.; Saarenketo, P. K.; Rissanen, K. Inorg. Chem. Commun. 2002, 5, 924-928
43. Wittick, L. M.; Murray, K. S.; Moubaraki, B.; Batten, S. R.; Spiccia, L.; Berry, K. J. Dalton Trans. 2004, 1003-1011
44. Boskovic, C.; Bircher, R.; Tregenna-Piggott, W. L. P.; Güdel, U. H.; Paulsen, C.; Wernsdorfer, W.; Baara, -L. A.; Khatsko, E.; Neels, A.; Stoeckli-Evans, H. J. Am. Chem. Soc. 2003, 125, 14046-14058
45. Miyasaka, H.; Yamashita, M. Dalton Trans. 2007, 399-406
46. Oshio, H.; Nihei, M.; Yoshida, A.; Nojiri, H.; Nakano, M.; Yamaguchi, A.; Karaki, Y.; Ishimoto, H. Chem.-Eur. J. 2005, 11, 843-848
47. Oshio, H.; Nihei, M.; Koizumi, S.; Shiga, T.; Nojiri, H.; Nakano, M.; Shirakawa, N.; Akatsu, M. J. Am. Chem. Soc. 2005, 127, 4568-4569
48. Kachi-Terajima, C.; Miyasaka, H.; Saitoh, A.; Shirakawa, N.; Yamashita, M.; Clérac, R. Inorg. Chem. 2007, 46, 5861-5872
49. Li, D.; Parkin, S.; Wang, G.; Yee, T. G.; Cle' rac, R.; Wernsdorfer, W.; Holmes, M. S. J. Am. Chem. Soc. 2006, 128, 4214-4215
50. Glaser, T.; Heidemeier, M.; Weyhermüller, T.; Hoffmann, R.-D.; Rupp, H.; Müller, P. Angew. Chem., Int. Ed. 2006, 45, 6033-6037
51. Feng, L. P.; Beedle, C. C.; Wernsdorfer, W.; Koo, C.; Nakano, M.; Hill, S.; Hendrickson, N. D. Inorg. Chem. 2007, 46, 8126-8128
52. Feng, L. P.; Beedle, C. C.; Koo, C.; Wernsdorfer, W.; Nakano, M.; Hill, S.; Hendrickson, N. D. Inorg. Chem. 2008, 47, 3188-3204
53. Glaser, T.; Heidemeier, M.; Krickemeyer, E.; Bögge, H.; Stammler, A.; Fröhlich, R.; Bill, E.; Schnack, J. Inorg. Chem. 2007, 48, 607-620
54. Winpenny, R. E. P. Dalton Trans. 2002, 1-10
55. Aromi, G.; Brechin, E. K. Struct. Bonding (Berlin) 2006, 122, 1-67
56. Tasiopoulos, A. J.; Perlepes, S. P. Dalton Trans. 2008, 5537-5555
57. Tanase, S.; Aromi, G.; Bouwman, E.; Kooijman, H.; Spek, A. L.; Reedijk, J. Chem. Commun. 2005, 3147
58. Viciano-Chumillas, M.; Tanase, S.; Aromi, G.; Smits, J. M. M.; de Gelder, R.; Solans, X.; Bouwman, E.; Reedijk, J. Eur. J. Inorg. Chem. 2007, 2635-2640
59. Viciano-Chumillas, M.; de Ruiter, G.; Tanase, S.; Smits, J. M. M.; de Gelder, R.; Mutikainen, I.; Turpeinen, U.; de Jongh, L. J.; Reedijk, J. Dalton Trans. 2010, 39, 4991-4998
60. Klingele, J.; Dechert, S.; Meyer, F. Coord. Chem. Rev. 2009, 253, 2698-2741
61. Chaudhuri, P.; Kataev, V.; Büchner, B.; Klauss, H.-H.; Kersting, B.; Meyer, F. Coord. Chem. Rev. 2009, 253, 2261-2285
62. Pleier, A.-K; Glas, H; Grosche, M.; Sirsch, P.; Thiel, W. R. Synthesis 2001, 55-62
63. Liu, W.; Thorp, H. H. Inorg. Chem. 1993, 32, 4102-4105
64. 2 is likely.
65. Geim, A. K.; Dubonos, S. V.; Lok, J. G. S.; Grigorieva, I. V.; Maan, J. C.; Hansen, L. T.; Lindelof, P. E. Appl. Phys. Lett. 1997, 71, 2379-2381
66. Abragam, A.; Bleaney, B. Electron Paramagnetic Resonance of Transition Ions; Oxford University Press: London, 1970.
67. Gatteschi, D.; Sessoli, R.; Villain, J. Molecular Nanomagnets; Oxford University Press: Oxford, 2006.
68. Bencini, A.; Gatteschi, D. EPR of Exchange Coupled Systems; Springer: New York, 1990.
69. Stoll, S.; Schweiger, A. J. Magn. Reson. 2006, 178, 42-55
70. Macrae, C. F.; Bruno, I. J.; Chisholm, J. A.; Edgington, P. R.; McCabe, P.; Pidcock, E.; Rodriguez-Monge, L.; Taylor, R.; van de Streek, J.; Wood, P. A. J. Appl. Crystallogr. 2008, 41, 466-470
71. Spek, A. L. J. Appl. Crystallogr. 2003, 36, 7-13
72. Janiak, C. J. Chem. Soc., Dalton Trans. 2000, 3885-3896
73. III SMMs, see for example: Lecren, L.; Roubeau, O.; Coulon, C.; Li., Y.-G.; Le Goff, X. F.; Wernsdorfer, W.; Miyasaka, H.; Clérac, R. J. Am. Chem. Soc. 2005, 127, 17353-17363
74. Jeon, I.-R.; Ababei, R.; Lecren, L.; Li, Y.-G.; Wernsdorfer, W.; Roubeau, O.; Mathonière, C.; Clérac, R. Dalton Trans. 2010, 39, 4744-4746
75. Haryono, M.; Kalisz, M.; Sibille, R.; Lescouëzec, R.; Fave, C.; Trippe-Allard, G.; Li, Y.; Seuleiman, M.; Rousselière, H.; Balkhy, A. M.; Lacroix, J.-C.; Journaux, Y. Dalton Trans. 2010, 39, 4751-4756
76. Golze, C.; Alfonsov, A.; Klingeler, R.; Büchner, B.; Kataev, V.; Mennerich, C.; Klauss, H.-H.; Goiran, M.; Broto, J.-M.; Rakoto, H.; Demeshko, S.; Leibeling, G.; Meyer, F. Phys. Rev. B 2006, 73, 224403/1-224403/8
77. Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112-122
78. X-RED; Stoe & Cie GmbH: Darmstadt, Germany, 2002.