Deprotonation of β-diketiminate in sterically demanding β-(diketiminato)-lanthanide complexes: Influence of lanthanide metals

European Journal of Inorganic Chemistry

Volumn , Issue 9, 2011, Pages 1448-1453

  Jiao, Rui ^a   Xue, Mingqiang ^a   Shen, Xiaodong ^a   Zhang, Yong ^a   Yao, Yingming ^a   Shen, Qi ^a,b  

^a SOOCHOW UNIVERSITY   (China)

^b SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

Deprotonation; Diketiminato ligand; Lanthanide complexes; Metalation; N ligands; Steric hindrance

Indexed keywords

CHELATION; CHLORINE COMPOUNDS; ERBIUM COMPOUNDS; METAL IONS; RARE EARTH ELEMENTS; SYNTHESIS (CHEMICAL); YTTERBIUM COMPOUNDS;

CENTRAL METALS; DIKETIMINATES; DIKETIMINATO LIGAND; LANTHANIDES COMPLEXES; METALATIONS; METHYL GROUP; N LIGANDS; N-LIGANDS; STERIC HINDRANCES; STERICALLY DEMANDING;

LIGANDS;

EID: 79952577398     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201000759     Document Type: Article

References (28)

1. a) L. Bourget-Merle, M. F. Lappert, J. R. Severn, Chem. Rev. 2002, 102, 3031-3065;
2. b) W. E. Piers, D. J. H. Emslie, Coord. Chem. Rev. 2002, 131, 233-234;
3. c) V. C. Gibson, K. Spitzmesser, Chem. Rev. 2003, 103, 283-315;
4. d) L. M. Mirica, X. Ottenwaelder, T. D. P. Stack, Chem. Rev. 2004, 104, 1013-1046;
5. e) G. W. Coates, D. R. Moore, Angew. Chem. 2004, 116, 6784;
6. Angew. Chem. Int. Ed. 2004, 43, 6618-6639.
7. a) A. G. Avent, A. V. Khvostov, P. B. Hitchcock, M. F. Lappert, Chem. Commun. 2002, 1410-1411;
8. b) O. Eisenstein, P. B. Hitchcock, A. V. Khvostov, M. F. Lappert, L. Maron, L. Perrin, A. V. Protchenko, J. Am. Chem. Soc. 2003, 125, 10790-10791;
9. c) A. G. Avent, P. B. Hitchcock, A. V. Khvostov, M. F. Lappert, A. V. Protchenko, Dalton Trans. 2004, 2272-2280.
10. a) Y. Ding, H. Hao, H. W. Roesky, M. Noltemeyer, H. G. Schmidt, Organometallics 2001, 20, 4806-4811;
11. b) A. M. Neculai, H. W. Roesky, D. Neculai, J. Magull, Organometallics 2001, 20, 5501-5503;
12. c) S. Harder, Angew. Chem. 2003, 115, 3553;
13. Angew. Chem. Int. Ed. 2003, 42, 3430-3434;
14. d) P. G. Hayes, W. E. Piers, L. W. M. Lee, L. K. Knight, M. Parvez, M. R. J. Elsegood, W. Clegg, Organometallics 2001, 20, 2533-2544;
15. e) F. Bazuli, J. C. Huffman, D. J. Mindiola, Inorg. Chem. 2003, 42, 8003-8010;
16. f) P. B. Hitchcock, M. F. Lappert, A. V. Protchenko, Chem. Commun. 2005, 951-953.
17. R. Jiao, X. D. Shen, M. Q. Xue, Y. Zhang, Y. M. Yao, Q. Shen, Chem. Commun. 2010, 46, 4118-4120.
18. a) M. Q. Xue, R. Jiao, Y. Zhang, Y. M. Yao, Q. Shen, Eur. J. Inorg. Chem. 2009, 4110-4118;
19. b) R. Jiao, M. Q. Xue, X. D. Shen, Y. Zhang, Y. M. Yao, Q. Shen, Eur. J. Inorg. Chem. 2010, 2523-2529.
20. A. G. Avent, P. B. Hitchcock, A. V. Khvostov, M. F. Lappert, A. V. Protchenko, Dalton Trans. 2003, 1070-1075.
21. a) H. Liang, Q. Shen, J. Guan, Y. Lin, J. Organomet. Chem. 1994, 474, 113-116;
22. b) H. Liang, J. Guan, Y. Lin, Q. Shen, Youji Huaxue 1994, 14, 380-382;
23. c) M. Niemeyer, S.-O. Hauber, Z. Anorg. Allg. Chem. 1999, 625, 137-140;
24. d) M. N. Bochkarev, Chem. Rev. 2002, 102, 2089-2118.
25. G. B. Deacon, Q. Shen, J. Organomet. Chem. 1996, 511, 1-17.
26. J. Feldman, S. J. Mclain, A. Parthasarathy, W. J. Marshall, J. C. Calabrese, S. D. Arthur, Organometallics 1997, 16, 1514-1516.
27. M. D. Taylor, C. P. Carter, J. Inorg. Nucl. Chem. 1962, 24, 387-391.
28. J. L. Atwood, W. E. Hunter, A. L. Wayda, W. J. Evans, Inorg. Chem. 1981, 20, 4115-4119.