Reversible submergence of nanoparticles into ultrathin block copolymer films

Soft Matter

Volumn 7, Issue 6, 2011, Pages 2538-2542

  Iyer, K Swaminathan ^a,b   Zdyrko, Bogdan ^a   Malynych, Sergiy ^c   Chumanov, George ^c   Luzinov, Igor ^a  

^a AMRL   (United States)

^b UNIVERSITY OF WESTERN AUSTRALIA   (Australia)

^c CLEMSON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

2-VINYLPYRIDINE; BLOCK COPOLYMER FILMS; DIFFERENT SOLVENTS; ORGANIC/INORGANIC NANO-COMPOSITE; SILVER NANOPARTICLES; THERMAL TREATMENT; THERMAL-ANNEALING; ULTRA-THIN;

ANNEALING; BLOCK COPOLYMERS; COPOLYMERIZATION; NANOCOMPOSITE FILMS; NANOCOMPOSITES; NANOPARTICLES; ORGANIC POLYMERS; PLASTIC FILMS; POLYMER FILMS; POLYMERIC FILMS; SOLVENTS; STYRENE; ULTRATHIN FILMS; VAPORS;

SILVER;

EID: 79952372464     PISSN: 1744683X     EISSN: 17446848     Source Type: Journal    
DOI: 10.1039/c0sm01156h     Document Type: Article

References (46)

1. W. Fritzsche H. Porwol A. Wiegand S. Bornmann J. M. Kohler In-situ formation of Ag-containing nanoparticles in thin polymer films Nanostruct. Mater. 1998 10 1 89 97 (Pubitemid 128402189)
2. S. Porel S. Singh S. S. Harsha D. N. Rao T. P. Radhakrishnan Nanoparticle-embedded polymer: in situ synthesis, free-standing films with highly monodisperse silver nanoparticles and optical limiting Chem. Mater. 2004 17 1 9 12 (Pubitemid 40096100)
3. A. C. Balazs T. Emrick T. P. Russell Nanoparticle polymer composites: where two small worlds meet Science 2006 314 5802 1107 1110 (Pubitemid 44789033)
4. E. Ploshnik A. Salant U. Banin R. Shenhar Hierarchical surface patterns of nanorods obtained by co-assembly with block copolymers in ultrathin films Adv. Mater. 2010 22 25 2774 2779
5. J. Bang U. Jeong D. Y. Ryu T. P. Russell C. J. Hawker Block copolymer nanolithography: translation of molecular level control to nanoscale patterns Adv. Mater. 2009 21 47 4769 4792
6. B. Zhao W. J. Brittain W. S. Zhou S. Z. D. Cheng Nanopattern formation from tethered PS-b-PMMA brushes upon treatment with selective solvents J. Am. Chem. Soc. 2000 122 10 2407 2408 (Pubitemid 30164668)
7. K. S. Iyer I. Luzinov Surface morphology of mechanically heterogeneous ultrathin polymer films Langmuir 2003 19 1 118 124
8. I. Tokarev R. Krenek Y. Burkov D. Schmeisser A. Sidorenko S. Minko M. Stamm Microphase separation in thin films of poly(styrene-block-4-vinylpyridine) copolymer-2-(4′-hydroxybenzeneazo)benzoic acid assembly Macromolecules 2005 38 2 507 516 (Pubitemid 40184325)
9. I. Luzinov V. V. Tsukruk Ultrathin triblock copolymer films on tailored polymer brushes Macromolecules 2002 35 15 5963 5973 (Pubitemid 34822509)
10. J. Y. Cheng C. A. Ross V. Z. H. Chan E. L. Thomas R. G. H. Lammertink G. J. Vancso Formation of a cobalt magnetic dot array via block copolymer lithography Adv. Mater. 2001 13 15 1174 1178 (Pubitemid 32798077)
11. V. Z. H. Chan J. Hoffman V. Y. Lee H. Latrou A. Avgeropoulos N. Hadjichristidis R. D. Miller E. L. Thomas Ordered bicontinuous nanoporous and nanorelief ceramic films from self assembling polymer precursors Science 1999 286 5445 1716 1719
12. R. B. Thompson V. V. Ginzburg M. W. Matsen A. C. Balazs Predicting the mesophases of copolymer-nanoparticle composites Science 2001 292 5526 2469 2472 (Pubitemid 32601655)
13. A. Haryono W. H. Binder Controlled arrangement of nanoparticle arrays in block-copolymer domains Small 2006 2 5 600 611
14. J. J. Chiu B. J. Kim G. R. Yi J. Bang E. J. Kramer D. J. Pine Distribution of nanoparticles in lamellar domains of block copolymers Macromolecules 2007 40 9 3361 3365 (Pubitemid 46750639)
15. Q. F. Li J. B. He E. Glogowski X. F. Li J. Wang T. Emrick T. P. Russell Responsive assemblies: gold nanoparticles with mixed ligands in microphase separated block copolymers Adv. Mater. 2008 20 8 1462 1466
16. C. Xu K. Ohno V. Ladmiral D. E. Milkie J. M. Kikkawa R. J. Composto Simultaneous block copolymer and magnetic nanoparticle assembly in nanocomposite films Macromolecules 2009 42 4 1219 1228
17. Y. Lin A. Boker J. B. He K. Sill H. Q. Xiang C. Abetz X. F. Li J. Wang T. Emrick S. Long Q. Wang A. Balazs T. P. Russell Self-directed self-assembly of nanoparticle/copolymer mixtures Nature 2005 434 7029 55 59 (Pubitemid 40349381)
18. J. B. He R. Tangirala T. Emrick T. P. Russell A. Boker X. F. Li J. Wang Self-assembly of nanoparticle-copolymer mixtures: a kinetic point of view Adv. Mater. 2007 19 3 381 385 (Pubitemid 46925428)
19. Q. L. Zhang S. Gupta T. Emrick T. P. Russell Surface-functionalized CdSe nanorods for assembly in diblock copolymer templates J. Am. Chem. Soc. 2006 128 12 3898 3899
20. J. G. Son W. K. Bae H. M. Kang P. F. Nealey K. Char Placement control of nanomaterial arrays on the surface-reconstructed block copolymer thin films ACS Nano 2009 3 12 3927 3934
21. S. W. Hong J. Wang Z. Q. Lin Evolution of ordered block copolymer serpentines into a macroscopic, hierarchically ordered web Angew. Chem., Int. Ed. 2009 48 44 8356 8360
22. M. Byun N. B. Bowden Z. Q. Lin Hierarchically organized structures engineered from controlled evaporative self-assembly Nano Lett. 2010 10 8 3111 3117
23. S. I. Yoo J. H. Kwon B. H. Sohn Single layers of diblock copolymer micelles for the fabrication of arrays of nanoparticles J. Mater. Chem. 2007 17 29 2969 2975 (Pubitemid 47118846)
24. K. S. Iyer, J. Moreland, I. Luzinov, S. Malynych and G. Chumanov, Block Copolymer Nanocomposite Films Containing Silver Nanoparticles, in Film Formation: Process and Morphology, ed., T. Provder,, ACS Symposium Series, Washington, DC, 2006, vol. 224, pp. 149-166
25. L. H. Sperling, Polymeric Multicomponent Materials, Wiley-Interscience, New York, 1997, p. 397
26. S. Malynych G. Chumanov Light-induced coherent interactions between silver nanoparticles in two-dimensional arrays J. Am. Chem. Soc. 2003 125 10 2896 2898 (Pubitemid 36512513)
27. M. A. Cohen Stuart W. T. S. Huck J. Genzer M. Muller C. Ober M. Stamm G. B. Sukhorukov I. Szleifer V. V. Tsukruk M. Urban F. Winnik S. Zauscher I. Luzinov S. Minko Emerging applications of stimuli-responsive polymer materials Nat. Mater. 2010 9 2 101 113
28. S. Malynych I. Luzinov G. Chumanov Poly(vinyl pyridine) as a universal surface modifier for immobilization of nanoparticles J. Phys. Chem. B 2002 106 6 1280 1285 (Pubitemid 35276089)
29. T. P. Russell Surface-responsive materials Science 2002 297 5583 964 967 (Pubitemid 34856021)
30. G. Chumanov K. Sokolov T. M. Cotton Unusual extinction spectra of nanometer-sized silver particles arranged in two-dimensional arrays J. Phys. Chem. 1996 100 13 5166 5168 (Pubitemid 126790476)
31. G. Coulon T. P. Russell V. R. Deline P. F. Green Surface-induced orientation of symmetric, diblock copolymers - a secondary ion mass-spectrometry study Macromolecules 1989 22 6 2581 2589
32. M. S. Kunz K. R. Shull A. J. Kellock Colloidal gold dispersions in polymeric matrices J. Colloid Interface Sci. 1993 156 1 240 249
33. B. Wei P. A. Gurr A. O. Gozen A. Blencowe D. H. Solomon G. G. Qiao R. J. Spontak J. Genzer Autophobicity-driven surface segregation and patterning of core-shell microgel nanoparticles Nano Lett. 2008 8 9 3010 3016
34. G. J. Fleer, M. A. Cohen Stuart; J. M. H. M. Scheutjens, T. Cosgrove and B. Vincent, Polymers at Interfaces, Chapman & Hall, London, 1993, p. 496
35. T. P. Russell G. Coulon V. R. Deline D. C. Miller Characteristics of the surface-induced orientation for symmetric diblock PS/PMMA copolymers Macromolecules 1989 22 12 4600 4606
36. K. Ramaratnam V. Tsyalkovsky V. Klep I. Luzinov Ultrahydrophobic textile surface via decorating fibers with monolayer of reactive nanoparticles and non-fluorinated polymer Chem. Commun. 2007 4510 4512 (Pubitemid 350045938)
37. B. Zhao W. J. Brittain Polymer brushes: surface-immobilized macromolecules Prog. Polym. Sci. 2000 25 5 677 710
38. I. Luzinov S. Minko V. V. Tsukruk Responsive brush layers: from tailored gradients to reversibly assembled nanoparticles Soft Matter 2008 4 4 714 725 (Pubitemid 351434076)
39. B. Zhao W. J. Brittain Synthesis, characterization, and properties of tethered polystyrene-b-polyacrylate brushes on flat silicate substrates Macromolecules 2000 33 23 8813 8820 (Pubitemid 32069941)
40. J. Draper I. Luzinov S. Minko I. Tokarev M. Stamm Mixed polymer brushes by sequential polymer addition: anchoring layer effect Langmuir 2004 20 10 4064 4075
41. O. Hoy B. Zdyrko R. Lupitskyy R. Sheparovych D. Aulich J. Wang E. Bittrich K. J. Eichhorn P. Uhlmann K. Hinrichs M. Müller M. Stamm S. Minko I. Luzinov Synthetic hydrophilic materials with tunable strength and a range of hydrophobic interactions Adv. Funct. Mater. 2010 20 2240 2247
42. S. Forster M. Zisenis E. Wenz M. Antonietti Micellization of strongly segregated block copolymers J. Chem. Phys. 1996 104 24 9956 9970 (Pubitemid 126715594)
43. A. P. Gast Structure, interactions, and dynamics in tethered chain systems Langmuir 1996 12 17 4060 4067 (Pubitemid 126567895)
44. L. H. Sperling, Introduction to Physical Polymer Science, Wiley-Interscience Hoboken, New Jersey, 4th edn, 2006, p. 845
45. D. D. Evanoff G. Chumanov Size-controlled synthesis of nanoparticles. 1. "Silver-only" aqueous suspensions via hydrogen reduction J. Phys. Chem. B 2004 108 37 13948 13956
46. J. Brandrup, E. H. Immergut and E. A. Grulke, Polymer Handbook, John Wiley & Sons, Inc, New York, 4th edn, 1999, VI/193 VI/275