Kinetics of hydroformylation of 1-octene in ionic liquid-organic biphasic media using rhodium sulfoxantphos catalyst

Chemical Engineering Science

Volumn 66, Issue 8, 2011, Pages 1631-1639

  Deshpande, R M ^a   Kelkar, A A ^a   Sharma, A ^b   Julcour Lebigue, C ^b   Delmas, H ^b  

^a NATIONAL CHEMICAL LABORATORY   (India)

^b UNIVERSITÉ DE TOULOUSE   (France)

Author keywords

Biphasic catalysis; Butylpyridinium tetrafluoroborate; Kinetics; Parameter identification; Reaction engineering; Solubility

Indexed keywords

1-OCTENE; BIPHASIC CATALYSIS; BIPHASIC HYDROFORMYLATION; CATALYTIC COMPLEXES; COMPLEX BEHAVIOR; DATA FITTINGS; FIRST-ORDER DEPENDENCE; FRACTIONAL ORDER; HIGH PRESSURE; HIGH SELECTIVITY; INITIAL RATE; KINETIC MODELING; LINEAR ALDEHYDES; MATRIX APPROACH; ORGANIC BIPHASIC MEDIA; PARAMETER IDENTIFICATION; PROCESS PARAMETERS; RATE MODELS; REACTION ENGINEERING; SOLUBILITY MEASUREMENT; TETRAFLUOROBORATES; THERMOGRAVIMETRY ANALYSIS;

ALDEHYDES; CARBON MONOXIDE; CATALYSIS; CATALYSTS; GAS FUEL ANALYSIS; HYDROFORMYLATION; HYDROXYLATION; IONIC LIQUIDS; IONS; MATHEMATICAL MODELS; PARAMETER ESTIMATION; RHODIUM; SOLUBILITY; THERMOGRAVIMETRIC ANALYSIS;

REACTION KINETICS;

EID: 79952244858     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2010.12.040     Document Type: Article

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