Silylene-mediated polarity reversal of dienoates: Additions of dienoates to aldehydes at the δ-position to form trans-dioxasilacyclononenes

Journal of the American Chemical Society

Volumn 133, Issue 3, 2011, Pages 406-408

  Ventocilla, Christian C ^a,b   Woerpel, K A ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b NEW YORK UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHIRAL AUXILIARIES; FUNCTIONALIZATIONS; NUCLEOPHILIC CENTERS; POLARITY REVERSAL; PURE MATERIALS; SILYLENES; STEREOSPECIFICITY; TRANSITION STATE; UNSATURATED CARBONYL COMPOUNDS;

ALDEHYDES; STEREOCHEMISTRY; UNSATURATED COMPOUNDS;

CARBONYLATION;

ALDEHYDE DERIVATIVE; CARBONYL DERIVATIVE; CYCLOALKENE; CYCLONONENE; DIENIMIDE; DIENOATE; DIENOL ETHER; EPOXIDE; OXASILACYCLOPENTENE; SILANE DERIVATIVE; SILYLENE; TRANS DIOXASILACYCLONONENE; UNCLASSIFIED DRUG; VINYL OXASILACYCLOPENTENE;

ARTICLE; CHEMICAL STRUCTURE; CHIRALITY; NUCLEOPHILICITY; STEREOISOMERISM; STEREOSPECIFICITY;

ALDEHYDES; ORGANOSILICON COMPOUNDS; STEREOISOMERISM;

EID: 79851499673     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja109631z     Document Type: Article

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