Polymer-immobilized palladium supported on TiO2 (Pd-PVB-TiO 2) as highly active and reusable catalyst for hydrogen generation from the hydrolysis of unstirred ammonia-borane solution

International Journal of Hydrogen Energy

Volumn 36, Issue 2, 2011, Pages 1448-1455

  Rakap, Murat ^a,b,c   Kalu, Egwu Eric ^a   Özkar, Saim ^b  

^a FAMU FSU COLLEGE OF ENGINEERING   (United States)

^b MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

^c YUZUNCU YIL UNIVERSITY   (Turkey)

Author keywords

Ammonia borane; Hydrogen generation; Hydrolysis; Palladium; Polymer immobilized; Titanium dioxide

Indexed keywords

GENERATION RATE; HYDROGEN GENERATION; HYDROGEN GENERATIONS; KINETIC DATA; LOW CONCENTRATIONS; PALLADIUM CATALYST; REUSABLE CATALYSTS; SEM; SOLID MATERIAL; SUBSTRATE CONCENTRATIONS; TIO; XRD;

ACTIVATION ENERGY; AMMONIA; HYDROGEN PRODUCTION; HYDROLYSIS; OXIDES; POLYMERS; TITANIUM; TITANIUM DIOXIDE;

CATALYST SUPPORTS;

EID: 79551502227     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.10.097     Document Type: Article

References (39)

1. F.H. Stephens, V. Pons, and R.T. Baker Ammonia-borane: the hydrogen source par excellence? Dalton Trans 2007 2613 2626
2. S. Satyapal, C. Read, G. Ordaz, and G. Thomas 2006 Annual DOE hydrogen program Merit Review: hydrogen storage 2006 U.S. Department of Energy Washington, D.C. http://www.hydrogen.energy.gov/pdfs/review06/2-storage- satyapal.pdf
3. B. Peng, and J. Chen Ammonia-borane as an efficient and lightweight hydrogen storage medium Energy Environ Sci 1 2008 479 483
4. T. Umegaki, J.M. Yan, X.B. Zhang, H. Shioyama, N. Kuriyama, and Q. Xu Boron- and nitrogen based chemical hydrogen storage materials Int J Hydrogen Energy 34 2008 2303 2311
5. T. Umegaki, J.M. Yan, X.B. Zhang, H. Shioyama, N. Kuriyama, and Q. Xu Preparation and catalysis of poly(N-vinyl-2-pyrrolidone) (PVP) stabilized nickel catalyst for hydrolytic dehydrogenation of ammonia-borane Int J Hydrogen Energy 34 2009 3816 3822
6. K.S. Eom, M. Kim, R.H. Kim, D.H. Nam, and H.S. Kwon Characterization of hydrogen generation for fuel cells via borane hydrolysis using an electroless-deposited Co-P/Ni foam catalyst J Power Sources 195 2010 2830 2834
7. J.M. Yan, X.B. Zhang, S. Han, H. Shioyama, and Q. Xu Magnetically recyclable Fe-Ni alloy catalyzed dehydrogenation of ammonia-borane in aqueous solution under ambient atmosphere J Power Sources 194 2009 478 481
8. W. Grochala, and P.P. Edwards Thermal decomposition of the non-interstitial hydrides for the storage and production of hydrogen Chem Rev 104 2004 1283 1316
9. P.V. Ramachandran, and P.D. Gagare Preparation of ammonia-borane in high yield and purity, methanolysis, and regeneration Inorg Chem 46 2007 7810 7817
10. Q. Xu, and M. Chandra Catalytic activities of non-noble metals for hydrogen generation from aqueous ammonia-borane at room temperature J Power Sources 163 2006 364 370
11. M. Chandra, and Q. Xu Room temperature hydrogen generation from aqueous ammonia-borane using noble metal nano-clusters as highly active catalysts J Power Sources 168 2007 135 142
12. M. Chandra, and Q. Xu Dissociation and hydrolysis of ammonia-borane with solid acids and carbon dioxide: an efficient hydrogen generation system J Power Sources 159 2006 855 860
13. N. Mohajeri, A. T-Raissi, and O. Adebiyi Hydrolytic cleavage of ammonia-borane complex for hydrogen production J Power Sources 167 2007 482 485
14. F. Cheng, H. Ma, Y. Li, and J. Chen Ni1-xPtx (x = 0-0.12) hollow spheres as catalysts for hydrogen generation from ammonia-borane Inorg Chem 46 2007 788 794
15. S. Basu, A. Brockman, P. Gagore, Y. Zheng, P.V. Ramachandran, and W.N. Delgass Chemical kinetics of Ru-catalyzed ammonia-borane hydrolysis J Power Sources 188 2009 238 243
16. 3 in air Inorg Chem 46 2007 7522 7527
17. 2O core shell catalysts for hydrogen generation from ammonia-borane Phys Chem Chem Phys 10 2008 5870 5874
18. 2nanosphere-catalyzed hydrolytic dehydrogenation of ammonia-borane for chemical hydrogen storage J Power Sources 191 2009 209 216
19. C.F. Yao, L. Zhuang, Y.L. Cao, X.P. Hi, and H.X. Yang Hydrogen release from hydrolysis of borazane on Pt- nd Ni-based alloy catalysts Int J Hydrogen Energy 33 2008 2462 2467
20. J.M. Yan, X.B. Zhang, S. Han, H. Shioyama, and Q. Xu Iron nanoparticle-catalyzed hydrolytic dehydrogenation of ammonia-borane for chemical hydrogen storage Angew Chem Int Ed Engl 47 2008 2287 2289
21. Ö Metin, and S. Özkar Hydrogen generation from the hydrolysis of ammonia-borane and sodium borohydride using water-soluble polymer-stabilized cobalt(0) nanoclusters catalyst Energy Fuels 23 2009 3517 3526
22. Ö Metin, S. ahin,. Özkar, and S. Özkar Water-soluble poly(4-styrenesulfonic acid-co-maleic acid) stabilized ruthenium(0) and palladium(0) nanoclusters as highly active catalysts in hydrogen generation from the hydrolysis of ammonia-borane Int J Hydrogen Energy 34 2009 6304 6313
23. J.M. Yan, X.B. Zhang, H. Shioyama, and Q. Xu Room temperature hydrolytic dehydrogenation of ammonia-borane catalyzed by Co nanoparticles J Power Sources 195 2010 1091 1094
24. J.M. Yan, X.B. Zhang, S. Han, H. Shioyama, and Q. Xu Synthesis of longtime water/air-stable Ni nanoparticles and their high catalytic activity for hydrolysis of ammonia-borane for hydrogen generation Inorg Chem 48 2009 7389 7393
25. X. Yang, F. Cheng, J. Liang, Z. Tao, and J. Chen PtxNi1-x nanoparticles as catalysts for hydrogen generation from hydrolysis of ammonia-borane Int J Hydrogen Energy 34 2009 8785 8791
26. M. Zahmakran, F. Durap, and S. Özkar Zeolite confined copper(0) nanoclusters as cost-effective and reusable catalyst in hydrogen generation from the hydrolysis of ammonia-borane Int J Hydrogen Energy 35 2010 187 197
27. M. Rakap, and S. Özkar Zeolite confined palladium(0) nanoclusters as effective and reusable catalyst for hydrogen generation from the hydrolysis of ammonia-borane Int J Hydrogen Energy 35 2010 1305 1312
28. M. Rakap, and S. Özkar Hydrogen generation from the hydrolysis of ammonia-borane using intrazeolite cobalt(0) nanoclusters catalyst Int J Hydrogen Energy 35 2010 3341 3346
29. D.G. Tong, X.L. Zeng, W. Chu, D. Wang, and P. Wu Magnetically recyclable hollow Co-B nanospindles as catalyst for hydrogen generation from ammonia-borane J Mater Sci Lett 45 2010 2862 2867
30. N. Patel, R. Fernandes, G. Guella, and A. Miotello Nanoparticle-assembled Co-B thin film for the hydrolysis of ammonia-borane: a highly active catalyst for hydrogen production Appl Catal B 95 2010 137 143
31. 2 by electroless deposition. Int J Hydrogen Energy, in press. doi:10.1016/j.ijhydene.2010.09.027.
32. H.L. Jiang, T. Umegaki, T. Akita, X.B. Zhang, M. Haruta, and Q. Xu Bimetallic Au-Ni nanoparticles embedded in SiO2 nanospheres: synergetic catalysis in hydrolytic dehydrogenation of ammonia-borane Chem Eur J 16 2010 3132 3137
33. D. Foxx, and E.E. Kalu Amperometric biosensor based on thermally activated polymer-stabilized metal nanoparticles Electrochem Commun 9 2007 584 590
34. A.S. Kuruganti, K.S. Chen, and E.E. Kalu Tapping mode atomic force microscopy analysis of a novel catalyzation technique on nonconducting substrates Electrochem Solid State Lett 2 1999 27 29
35. H.B. Dai, L.L. Gao, Y. Liang, X.D. Kang, and P. Wang Promoted hydrogen generation from ammonia-borane aqueous solution using cobalt-molybdenum-boron/ nickel foam catalyst J Power Sources 195 2010 307 312
36. 2 catalysts by different preparation methods J Electron Spectrosc Relat Phenom 173 2009 88 95
37. S.B. Kalidindi, M. Indirani, and B.R. Jagirdar First row transition metal ion-assisted ammonia-borane hydrolysis for hydrogen generation Inorg Chem 47 2008 7424 7429
38. 3 by an electroplated Co-P catalyst Int J Hydrogen Energy 35 2010 181 186
39. C.A. Jaska, T.J. Clark, S.B. Clendenning, D. Groeza, A. Turak, and Z.H. Lu Poisoning of heterogeneous, late transition metal dehydrocoupling catalysts by boranes and other group 13 hydrides J Am Chem Soc 127 2005 5116 5124