Chalcogenidobis(ene-1,2-dithiolate)molybdenum(iv) complexes (chalcogenide e = O, S, Se): Probing MoE and ene-1,2-dithiolate substituent effects on geometric and electronic structure

Dalton Transactions

Volumn 40, Issue 5, 2011, Pages 1119-1131

  Sugimoto, Hideki ^a   Tano, Hiroyuki ^b   Suyama, Koichiro ^b   Kobayashi, Tomoya ^b   Miyake, Hiroyuki ^b   Itoh, Shinobu ^a   Mtei, Regina P ^c   Kirk, Martin L ^c  

^a OSAKA UNIVERSITY   (Japan)

^b Osaka Prefecture University   (Japan)

^c UNIVERSITY OF NEW MEXICO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOND DISTANCE; CHALOCOGENIDE; CT BANDS; DITHIOLATES; DITHIOLENE; ELECTROCHEMICAL STUDIES; ELECTRON DONATION; ELECTRONIC ABSORPTION; ELECTRONWITHDRAWING; GEOMETRIC STRUCTURE; ISOSTRUCTURAL; LIGAND EFFECT; LIGAND-FIELD; LOW ENERGIES; MOLYBDENUM COMPLEX; NEW SERIES; RESONANCE RAMAN SPECTROSCOPY; SAKURAI; SPECTROSCOPIC PROPERTY; SQUARE-PYRAMIDAL GEOMETRY; SUBSTITUENT EFFECT; SYSTEMATIC INVESTIGATIONS; VIBRATIONAL FREQUENCIES; X-RAY CRYSTALLOGRAPHIC ANALYSIS;

ABSORPTION SPECTROSCOPY; ALKYLATION; CARBOXYLATION; DENSITY FUNCTIONAL THEORY; ELECTRONIC PROPERTIES; ELECTRONIC STRUCTURE; GEOMETRY; LIGANDS; MAGNETIC FIELDS; MOLYBDENUM; NUCLEAR MAGNETIC RESONANCE; RAMAN SPECTROSCOPY; RESONANCE;

MOLYBDENUM COMPOUNDS;

CHALCOGEN; MOLYBDENUM; SELENIUM;

ARTICLE; CHEMISTRY; ELECTRON; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

CHALCOGENS; ELECTRONS; MAGNETIC RESONANCE SPECTROSCOPY; MOLYBDENUM; SELENIUM; SPECTROSCOPY, FOURIER TRANSFORM INFRARED;

EID: 78751504559     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c0dt00871k     Document Type: Article

References (49)

1. W. A. Nugent and J. M. Mayer, Metal-Ligand Mutiple Bonds, John Wiley, New York, 1988
2. C. Limberg Angew. Chem. Int. Ed. 2009 48 2270
3. R. Hille Chem. Rev. 1996 96 2757
4. J. M. Tunney, L. McMaster and C. D. Garner, In Comprehensive Coordination Chemistry II; ed., J. A. McCleverty, and, J. M. Meyer, 2004, vol. 8, 459
5. S. J. N. Burgmayer Prog. Inorg. Chem. 2004 52 491
6. C. G. Young, In Encyclopedia of Inorganic Chemistry 2; ed, R. B. King, 2005, vol. 5, 3321
7. K. Okamoto K. Matsumoto R. Hille B. T. Eger E. F. Pai T. Nishino Proc. Natl. Acad. Sci. U. S. A. 2004 101 7931
8. C. J. Doonan N. D. Rubie K. Peariso H. H. Harris S. Z. Knottenbelt G. N. George C. G. Young M. L. Kirk J. Am. Chem. Soc. 2008 130 55
9. H. C. A. Raaijimakers M. J. Romao J. Biol. Inorg. Chem. 2006 11 1261
10. N. Wagener A. J. Pierik A. Ibdah R. Hille H. Dobbek Proc. Natl. Acad. Sci. U. S. A. 2009 106 11055
11. R. H. Holm Coord. Chem. Rev. 1990 100 183
12. C. G. Young, In Biomimetic Oxidations Catalyzed by Transition Metal Complexes; ed., B. Meunier, 2000, 415
13. C. G. Young, In Comprehensive Coordination Chemistry II; ed., J. A. McCleverty, and, J. M. Meyer, 2004, vol. 4, 415
14. J. H. Enemark J. L. A. Cooney J. -J. Wang R. H. Holm Chem. Rev. 2004 104 1175
15. H. Sugimoto H. Tsukube Chem. Soc. Rev. 2008 37 2609
16. F. A. Cotton G. Schmid Inorg. Chem. 1997 36 2267
17. A. R. Johnson W. M. Davis C. Christopher C. C. Cummins S. Serron S. P. Nolan D. G. Musaev K. Morokuma J. Am. Chem. Soc. 1998 120 2071
18. C. G. Young A. G. Wedd Chem. Commun. 1997 1251
19. C. G. Young S. A. Roberts R. B. Ortega J. H. Enemark J. Am. Chem. Soc. 1987 109 2938
20. C. G. Young R. W. Gable J. P. Hill G. N. George Eur. J. Inorg. Chem. 2001 2227
21. C. J. Doonan D. J. Nielsen P. D. Smith J. M. White G. N. George C. G. Young J. Am. Chem. Soc. 2006 128 305
22. S. C. Drew J. P. Hill I. Lane G. R. Hansen R. W. Gable C. G. Young Inorg. Chem. 2007 46 2373
23. L. J. Laughlin A. A. Eagle G. N. George E. R. T. Tiekink C. G. Young Inorg. Chem. 2007 46 939
24. H. Sugimoto M. Harihara M. Shiro K. Sugimoto K. Tanaka H. Miyake H. Tsukube Inorg. Chem. 2005 44 6386
25. H. Sugimoto T. Sakurai H. Miyake K. Tanaka H. Tsukube Inorg. Chem. 2005 44 6927
26. H. Tano R. Tajima H. Miyake S. Itoh H. Sugimoto Inorg. Chem. 2008 47 7465
27. P. J. Ellis T. Conrads R. Hille P. Kuhn Structure 2001 9 125
28. B. S. Lim R. H. Holm J. Am. Chem. Soc. 2001 123 1920
29. D. Coucouvanis A. Hadjikyriacou A. Toupadakis S. M. Koo O. Ileperuma M. Draganjac A. Salifoglou Inorg. Chem. 1991 30 754
30. G. N. Schrauzer V. P. Mayweg W. Heinrich J. Am. Chem. Soc. 1966 88 8174
31. H. Sugimoto S. Tatemoto K. Suyama H. Miyake R. P. Mtei S. Itoh M. L. Kirk Inorg. Chem. 2010 49 5368
32. M. C. Burla M. Camalli B. Carrozzini G. L. Cascarano C. Giacovazzo G. Polidori R. Spagna J. Appl. Crystallogr. 2003 36 1103
33. P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, R. de Gelder, R. Israel and J. M. M. Smits, The DIRDIF-99 program system, Technical Report of the Crystallography Laboratory, University of Nijmegen: The Netherlands: 1999
34. Crystal Structure Analysis Package, Rigaku and Rigaku/MSC, The Woodlands, TX, USA: 2000-2006
35. Gaussian 03, R. C. G., Inc., Pittsburgh, PA, 2003, Inc (full reference is given in Supplementary Information)
36. S. I. Gorelsky, AOMix: Program for Molecular Orbital Analysis, York University, Toronto, 1997 http://www.sh-chem.net/
37. S. I. Gorelsky A. P. B. Lever J. Organomet. Chem. 2001 635 187 196
38. N. M. O'Boyle A. L. Tenderholt K. M. Langner J. Comput. Chem. 2008 29 839 845
39. S. O'Neal J. W. Kolis J. Am. Chem. Soc. 1988 110 1971
40. D. Coucouvais M. J. Draganjac J. Am. Chem. Soc. 1982 104 6820
41. S. Groysman R. H. Holm Inorg. Chem. 2007 46 4090
42. H. Sugimoto K. Suyama K. Sugimoto H. Miyake I. Takahashi S. Hirota S. Itoh Inorg. Chem. 2008 47 10150
43. B. S. Lim J. P. Donahue R. H. Holm Inorg. Chem. 2000 39 263
44. P. Atkins, T. Orerton, J. Rourke, M. Weller and F. Armstrong, Inorganic Chemistry, Fourth Edition Oxford University Express, New York, 2006
45. V. J. Murphy G. Parkin J. Am. Chem. Soc. 1995 117 3522
46. P. Subramanian S. Burgmayer S. Richards V. Szalai T. G. Spiro Inorg. Chem. 1990 29 3849
47. F. E. Inscore R. McNaughton B. L. Westcott M. E. Helton R. Jones I. K. Dhawan J. H. Enemark M. L. Kirk Inorg. Chem. 1999 38 1401
48. R. L. McNaughton B. S. Lim S. Z. Knottenbelt R. H. Holm M. L. Kirk J. Am. Chem. Soc. 2008 130 4628
49. K. G. Matz R. P. Mtei B. Leung S. J. N. Burgmayer M. L. Kirk J. Am. Chem. Soc. 2010 132 7830