Mechanism and direct kinetic study of the polychlorinated dibenzo-p-dioxin and dibenzofuran formations from the radical/radical cross-condensation of 2,4-dichlorophenoxy with 2-chlorophenoxy and 2,4,6-trichlorophenoxy

Environmental Science and Technology

Volumn 45, Issue 2, 2011, Pages 643-650

  Xu, Fei ^a   Yu, Wanni ^a   Zhou, Qin ^a   Gao, Rui ^a   Sun, Xiaoyan ^a   Zhang, Qingzhu ^a   Wang, Wenxing ^a  

^a SHANDONG UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CANONICAL VARIATIONAL TRANSITION-STATE THEORIES; CHLOROPHENOXY; ELEMENTARY REACTION; EXPERIMENTAL KINETICS; FORMATION MECHANISM; GASPHASE; KINETIC CALCULATIONS; KINETIC PROPERTIES; KINETIC STUDY; PCDD/F FORMATION; PCDD/FS; POLYCHLORINATED DIBENZO-P-DIOXIN AND DIBENZOFURAN; POLYCHLORINATED DIBENZO-P-DIOXINS AND DIBENZOFURANS; PREEXPONENTIAL FACTOR; SELF-CONDENSATION; SMALL-CURVATURE TUNNELING; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE; THEORETICAL RESULT;

ACTIVATION ENERGY; CONDENSATION; DENSITY FUNCTIONAL THEORY;

RATE CONSTANTS;

2 CHLOROPHENOXY RADICAL; 2,4 DICHLOROPHENOXY RADICAL; 2,4,6 TRICHLOROPHENOXY RADICAL; POLYCHLORINATED DIBENZODIOXIN; POLYCHLORINATED DIBENZOFURAN; RADICAL; UNCLASSIFIED DRUG;

ACTIVATION ENERGY; CONDENSATION; CURVATURE; PCDD; PCDF; RADICAL; REACTION KINETICS;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CROSS CONDENSATION; DENSITY FUNCTIONAL THEORY; EXPERIMENTAL STUDY; KINETICS; TEMPERATURE;

AIR POLLUTANTS; BENZOFURANS; FREE RADICALS; HYDROCARBONS, CHLORINATED; INCINERATION; KINETICS; TETRACHLORODIBENZODIOXIN;

EID: 78651410156     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es102660j     Document Type: Article

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