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Synthesis of [Cd(2, 4′-bpdc)H2O]n (1). A mixture of 2, 4′-biphenyldicarboxylic acid (0.0250 g; 0.1 mmol), Cd(Ac)2 (0.0250 g; 0.11 mmol), and H2O (12 mL) was heated to 180 °C for 5 days in a 20 mL Teflon-lined stainless-steel autoclave and was then cooled to room temperature at 10 °Ch-1 to obtain colorless block single crystals of 1 (yield: 58% based on Cd) Anal. Calcd for C14H10OCd (%): C, 45.33; H, 2.70. Found: C, 45.27; H, 2.73. IR frequencies (K Br, cm-1): 3463, 3275, 1578, 1467, 1396, 1241, 1092, 958, 895, 853, 789, 658, 621, 543.
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Single crystal X-ray diffraction data collections for 1 was performed on a Bruker Apex II CCD diffractometer operating at 50 kV and 30 mA using Mo Ka radiation (λ = 0.71073 Å) at 296 K. Data collection and reduction were performed using the SMART and SAINT software 14. A multi-scan absorption correction was applied using the SADABS program 14. The two structures were solved by direct methods and refined by full-matrix least squares on F2 using the SHELXTL program package 15. Hydrogen atoms were located from difference Fourier maps and a riding model. Selected bond lengths and angles are given in Table S1. Crystallographic data for complex 1: PrC7H9N2O8, FW = 421.42, Monoclinic, Space group P21/c with a = 13.1277(6) Å, b = 6.591(3) Å, c = 12.8486(6) Å. V = 1104.75(9) Å3 Z = 4, F(000) = 792, GOF = 1.027, R1 = 0.0171, wR2 = 0.0388 [I > 2σ(I)].
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