Luminescence of meso-pyrimidinylcorroles: Relationship with substitution pattern and heavy atom effects

Photochemical and Photobiological Sciences

Volumn 10, Issue 1, 2011, Pages 143-150

  Nastasi, Francesco ^a   Campagna, Sebastiano ^a   Ngo, Thien H ^b   Dehaen, Wim ^b   Maes, Wouter ^b,c   Kruk, Mikalai ^d  

^a UNIVERSITY OF MESSINA   (Italy)

^b UNIVERSITY OF LEUVEN   (Belgium)

^c HASSELT UNIVERSITY   (Belgium)

^d B I STEPANOV INSTITUTE OF PHYSICS   (Belarus)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 78650758287     PISSN: 1474905X     EISSN: 14749092     Source Type: Journal    
DOI: 10.1039/c0pp00282h     Document Type: Article

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40. -1). As the emission quantum yield of 9 is 0.013, more than 98% of the excited state deactivates by radiationless decay, and more than 80% of the radiationless decay is due to intersystem crossing. With this figure, the triplet π-π* state is produced with an efficiency of about 80% from the singlet state. Additional indirect evidence of the high efficiency of triplet state population and enhancement upon introducing of halide atoms into aryl substituents can be derived from comparison of our results with literature data, where it was found that triphenylcorrole triplet state quantum yield is only 0.51, while pentafluorophenylcorrole has triplet state quantum yield as high as 0.71 (see ref.
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