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These unfavorable photophysical properties result from the proximity (in energy) of the lowest-lying MLCT and metal-centered (MC) states, with the latter governing the excited-state decay dynamics by thermally activated surface crossing. This topic has been clarified and is reported in detail in several reviews.
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The electronic interaction between the chromophores has to be weak, otherwise a single (delocalized) excited state is populated and equilibration between states, the key point of the strategy (see later), is meaningless.
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The 5-chloro group is deactivated as it is meta to both nitrogens of the pyrimidine; V. Farina, V. Krishnamurthy, W. J. Scott, The Stille Reaction, Wiley, New York, 1998.
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0242510798
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A boronic acid group on a ruthenium complex has been coupled with 9-bromoanthracene although the newly formed complex was not isolated in pure form: see ref [8c].
-
-
-
-
41
-
-
0242595551
-
-
note
-
2+ ion, which under the same experimental conditions has a lifetime of 250 ps. This increase is partly because of the use of the extended π* orbital, as described in ref. [5d].
-
-
-
-
42
-
-
0242595552
-
-
note
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-1 in 1 and 2, respectively.
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