Measuring diffusivity in supercooled liquid nanoscale films using inert gas permeation. I. Kinetic model and scaling methods

Journal of Chemical Physics

Volumn 133, Issue 17, 2010, Pages

  Smith, R Scott ^a   Matthiesen, Jesper ^a   Kay, Bruce D ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMORPHOUS OVERLAYERS; DESORPTION SPECTRA; DESORPTION TIME; DIFFUSION MODEL; DIFFUSIVITIES; GLASS TRANSITION TEMPERATURE; KINETIC MODELS; MODEL SIMULATION; NANOSCALE FILMS; NUMERICAL SIMULATION; OVERLAYERS; SCALING METHOD; SCALING RELATIONSHIPS; SIMULATION RESULT; SUPERCOOLED LIQUIDS; TEMPERATURE RAMP; UNIVERSAL SCALING; DESORPTION PEAKS; EXPERIMENTAL CONDITIONS; EXPERIMENTAL TECHNIQUES; IDEAL MODEL; LOW TEMPERATURES; PEAK TEMPERATURES; TEMPERATURE REGIMES;

COMPUTER SIMULATION; CRYOGENIC LIQUIDS; DIFFUSION; GLASS TRANSITION; INERT GASES; METHANOL; SUPERCOOLING; TEMPERATURE PROGRAMMED DESORPTION; GAS PERMEABLE MEMBRANES; KRYPTON; PROBES; XENON;

GAS PERMEABLE MEMBRANES; SUPERCOOLING;

GLASS; INERT GAS; METHANOL; NANOMATERIAL;

ARTICLE; CHEMICAL MODEL; CHEMISTRY; COLD; COMPUTER SIMULATION; DIFFUSION; KINETICS; SURFACE PROPERTY; TRANSITION TEMPERATURE;

COLD TEMPERATURE; COMPUTER SIMULATION; DIFFUSION; GLASS; KINETICS; METHANOL; MODELS, CHEMICAL; NANOSTRUCTURES; NOBLE GASES; SURFACE PROPERTIES; TRANSITION TEMPERATURE;

EID: 78650670442     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3497654     Document Type: Article

References (25)

1. P. G. Debenedetti, Metastable Liquids: Concepts and Principles (Princeton University Press, Princeton, NJ, 1996).
2. C. A. Angell, Science SCIEAS 0036-8075 267, 1924 (1995). 10.1126/science.267.5206.1924
3. J. H. Crowe, J. F. Carpenter, and L. M. Crowe, Annu. Rev. Physiol. ARPHAD 0066-4278 60, 73 (1998). 10.1146/annurev.physiol.60.1.73 (Pubitemid 28157865)
4. F. H. Stillinger, Science SCIEAS 0036-8075 267, 1935 (1995). 10.1126/science.267.5206.1935
5. M. D. Ediger, Annu. Rev. Phys. Chem. ARPLAP 0066-426X 51, 99 (2000). 10.1146/annurev.physchem.51.1.99
6. P. G. Debenedetti and F. H. Stillinger, Nature (London) NATUAS 0028-0836 410, 259 (2001). 10.1038/35065704 (Pubitemid 32218700)
7. P. G. Debenedetti, J. Phys.: Condens. Matter JCOMEL 0953-8984 15, R1669 (2003). 10.1088/0953-8984/15/45/R01
8. P. G. Debenedetti and H. E. Stanley, Phys. Today PHTOAD 0031-9228 56 (6), 40 (2003). 10.1063/1.1595053
9. A. Cavagna, Phys. Rep. PRPLCM 0370-1573 476, 51 (2009). 10.1016/j.physrep.2009.03.003
10. J. Matthiesen, R. S. Smith, and B. D. Kay, Phys. Rev. Lett. PRLTAO 0031-9007 103, 245902 (2009). 10.1103/PhysRevLett.103.245902
11. D. L. Wise and G. Houghton, Chem. Eng. Sci. CESCAC 0009-2509 23, 1211 (1968). 10.1016/0009-2509(68)89029-3
12. R. S. Smith, J. Matthiesen, and B. D. Kay, J. Chem. Phys. JCPSA6 0021-9606 132, 124502 (2010). 10.1063/1.3361664
13. J. Matthiesen, R. S. Smith, and B. D. Kay, J. Chem. Phys. JCPSA6 0021-9606 133, 174505 (2010).
14. R. S. Smith, T. Zubkov, and B. D. Kay, J. Chem. Phys. JCPSA6 0021-9606 124, 114710 (2006). 10.1063/1.2177658
15. T. Zubkov, R. S. Smith, T. R. Engstrom, and B. D. Kay, J. Chem. Phys. JCPSA6 0021-9606 127, 184707 (2007). 10.1063/1.2790432 (Pubitemid 350115940)
16. B. Lang, Surf. Sci. SUSCAS 0039-6028 53, 317 (1975). 10.1016/0039- 6028(75)90132-6
17. M. Enachescu, D. Schleef, D. F. Ogletree, and M. Salmeron, Phys. Rev. B PLRBAQ 0556-2805 60, 16913 (1999). 10.1103/PhysRevB.60.16913
18. H. Ueta, M. Saida, C. Nakai, Y. Yamada, M. Sasaki, and S. Yamamoto, Surf. Sci. SUSCAS 0039-6028 560, 183 (2004). 10.1016/j.susc.2004.04.039
19. G. A. Kimmel, J. Matthiesen, M. Baer, C. J. Mundy, N. G. Petrik, R. S. Smith, Z. Dohnalek, and B. D. Kay, J. Am. Chem. Soc. JACSAT 0002-7863 131, 12838 (2009). 10.1021/ja904708f
20. K. P. Stevenson, G. A. Kimmel, Z. Dohnalek, R. S. Smith, and B. D. Kay, Science SCIEAS 0036-8075 283, 1505 (1999). 10.1126/science.283.5407.1505 (Pubitemid 29133354)
21. T. Zubkov, R. S. Smith, T. R. Engstrom, and B. D. Kay, J. Chem. Phys. JCPSA6 0021-9606 127, 184708 (2007). 10.1063/1.2790433 (Pubitemid 350115941)
22. R. S. Smith, T. Zubkov, Z. Dohnalek, and B. D. Kay, J. Phys. Chem. B JPCBFK 1089-5647 113, 4000 (2009). 10.1021/jp804902p
23. J. L. Daschbach, G. K. Schenter, P. Ayotte, R. S. Smith, and B. D. Kay, Phys. Rev. Lett. PRLTAO 0031-9007 92, 198306 (2004). 10.1103/PhysRevLett.92. 198306
24. R. Getz, A Primer of Diffusion Problems (Wiley, New York, 1988).
25. J. Crank, Mathematics of Diffusion, 2nd ed. (Oxford University Press, Bristol, 1975).