Supporting multiple organometallic catalysts on poly(norbornene) for cyanide addition to α,β-unsaturated imides

Journal of Molecular Catalysis A: Chemical

Volumn 334, Issue 1-2, 2011, Pages 1-7

  Madhavan, Nandita ^a   Sommer, William ^a   Weck, Marcus ^a,b  

^a GEORGIA INSTITUTE OF TECHNOLOGY   (United States)

^b NEW YORK UNIVERSITY   (United States)

Author keywords

Aluminum; Bimetallic mechanism; ROMP; Salen; Supported catalysis

Indexed keywords

BIMETALLIC MECHANISM; CASCADE REACTIONS; CATALYST SYSTEM; CATALYTIC SYSTEM; NORBORNENES; ONE POT; ORGANOMETALLIC CATALYSTS; POLYMER BACKBONES; PROOF OF CONCEPT; ROMP; SALEN; SUPPORTED CATALYSIS; UNSATURATED IMIDES;

ALUMINUM; AMINES; CATALYSIS; CYANIDES; ENANTIOSELECTIVITY; ORGANOMETALLICS;

CATALYST SUPPORTS;

EID: 78650514876     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2010.10.023     Document Type: Article

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17. The insolubility of the catalyst made it extremely difficult to characterize it by NMR spectroscopy or Mass spectrometry.
18. Trimethyl silyl cyanide and hydrogen cyanide are extremely toxic and should be handled carefully in a well-ventilated fume hood.
19. The kinetics for the cyanide addition catalyzed by 1 was studied using NMR spectroscopy. Data shown in the supplemental information.